• Bulletin of the Korean Chemical Society
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• v.25 no.5
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• pp.699-703
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• 2004

Solvolyses of isopropylsulfonyl chloride (IPSC) in water, D_2O,\;CH_3OD$, and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25, 35 and 45$^{\circ}C$. The Grunwald-Winstein plot of first-order rate constants for the solvolytic reaction of IPSC with $Y_{Cl}$ (based on 2-adamantyl chloride) shows marked dispersions into three separate lines for three aqueous mixtures with a small slope (m < 0.30). The extended Grunwald-Winstein plots for the solvolysis of IPSC show better correlation. The kinetic solvent isotope effects determined in water and methanol are in consistent with the proposed mechanism of the general base catalyzed and/or $S_AN/S_N2$ reaction mechanism for IPSC solvolyses based on mass law and stoichiometric solvation effect studies.

• Korean Journal of Applied Biomechanics
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• v.31 no.4
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• pp.297-307
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• 2021

Objective: The aim of this study was to analyze kinetic variables between thermotherapy and dynamic warm-up during drop-landing. Method: Twenty male healthy subjects (Age: 21.85 ± 1.90 years, Height: 1.81 ± 0.06 cm, Weight: 68.5 ± 7.06 kg) underwent three treatments applied on the thermotherapy of femoral muscles and a dynamic warm-up. The thermotherapy was performed for 15 minutes while sitting in a chair using an electric heating pad equipped with a temperature control device. Dynamic warm-up performed 14 exercise, a non-treatment was sitting in a chair for 15 minutes. Core temperature measurements of all subjects were performed before landing at a height of 50 cm. During drop-landing, core temperature, joint angle, moment, work of the sagittal plane was collected and analyzed. All analyses were performed with SPSS 21.0 and for repeated measured ANOVA and Post-hoc was Bonferroni. Results: Results indicated that Thermotherapy was increased temperature than other treatments (p = .000). During drop-landing, hip joint of dynamic warm-up was slower for angular velocity (p < .005), and left ankle joint was fastest than other treatments (p = .004). Maximum joint moment of dynamic warm-up was smaller for three joints (hip extension: p = .000; knee flexion/extension: p = .001/.000; ankle plantarflexion: p = .000). Negative work of dynamic warm-up was smaller than other treatments (p = .000). Conclusion: In conclusion, the thermotherapy in the local area doesn't affect the eccentric contraction of the thigh. The dynamic warm-up treatment minimized the joint moment and negative work of the lower joint during an eccentric contraction, it was confirmed that more active movement was performed than other treatment methods.

• The Journal of the Korea Contents Association
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• v.17 no.1
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• pp.465-474
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• 2017

This study aimed to identify the trends of related research as a basic study for the development of creative convergent formative education program of natural structure concept. This study sought to identify research trends present in previous studies. The nature structure of the preliminary research was limited to the three concepts: (i) fractal ; (ii) kinetic and (iii) biomimicry. In this study, the trends of domestic research in the last 10 years related to the concept of natural structure were analyzed using academic research information service. It was found that, to date, little research has been conducted on the three concepts across education fields. In relation to the fractal concept, previous research has focused on mathematics. This preliminary study sought to review the abovementioned three concepts or the development of a modeling education program. It should be significant, if an education program adopted unlimited modeling principles to understand the innate features of the nature structure. However, very few education programs have adopted the three concepts of the nature structure. Future studies would seek to review international research trends based on the three concepts of the nature structure and combine the results on international research trends with the results on domestic research trends found in this study.

• Journal of the Korean Chemical Society
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• v.43 no.6
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• pp.699-706
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• 1999

The purpose of this study was to investigate high school students' conceptions and conceptual types on molecular kinetic theory of gases. Data was collected by a series of semi-structured and in-depth interviews, and has been analyzed. This study showed that the students came to science classes with various prior conceptions of many disciplinary topics. Their conceptual types of their prior knowledge were distinguished as superficial terms-speaking, partial sense-making, and causal sense-making by the degrees of organization and elaboration of conceptual networks. These conceptual types had influence on the ways students understand and think of science, a stability of their conceptions, a tendency to distinguish school science from everyday science, and building a meaning of concept in contexts. It was referred that the students didn't have proper understanding on the nature of scientific knowledge and had been limited their participations as active learners. Therefore, in order for students to experience conceptual change, they must have opportunities of manifesting their own thinking, taking part in discussions, and promoting their motivations and metacognition of knowing and learning science.

• Korean Journal of Applied Biomechanics
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• v.21 no.3
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• pp.317-325
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• 2011

The purpose of this study was to investigate the contributions of body joints to the kinetic energy of the clubhead in the golf swing. Three dimensional swing analysis was conducted on the seven KPGA golfers. The subjects were asked to swing with 45 inches of driver. The work done by body joints were computed by utilizing the inverse dynamics method. The order of work done by the body joints was lumbar > left hip > right shoulder > left wrist > right wrist > right hip at the first phase. At the second phase, the order of work done by the body joints was trunk > left elbow > right wrist > right shoulder > left wrist > right wrist. At the third phase, the order of work done by body joints was lumbar > right shoulder > left shoulder > left elbow > right wrist > right elbow. The sum of the work done by the body joints was lumbar > shoulder > wrist on the average. The kinetic energy of the club head was 430.11${\pm}$24.35 J and the subject's swing efficiency was shown as 31.82${\pm}$4.86% on the average. The contributions of body joints to the kinetic energy of the clubhead was the order of lumbar > upper right shoulder > left elbow > right wrist during the down swing.

• Horticultural Science & Technology
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• v.34 no.6
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• pp.940-958
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• 2016

The objective of this study was to analyze the kinematic and kinetic characteristics of two horticultural activities: seed sowing and planting plant. Thirty-one male university students (aged $26.2{\pm}2.0years$) participated in this study. Kinematic factors (movement times, peak velocity, joint angles, and grasp patterns) were assessed using a three-dimensional motion analysis system while the subjects performed the horticultural activities. Kinetic factors (muscle activation of eight upper-limb muscles: the anterior deltoid, serratus anterior, upper trapezius, infraspinatus, latissimus dorsi, biceps brachii, brachioradialis, and flexor carpi radialis) were assessed using surface electromyography. The acts of seed sowing and planting plant were comprised of five tasks which included six types of phases: reaching, grasping, back transporting, forward transporting, watering, and releasing. The movement times, peak velocity, joint angles, and grasp patterns were significantly different across the tasks involved in the horticultural activities. All eight muscles of the upper limbs were utilized during the horticultural activities, and the muscle activation of the serratus anterior was the highest compared to that of the other muscles tested. The kinematic and kinetic characteristics of these horticultural activities showed similar characteristics to reaching and grasping rehabilitation training and daily living activities. The present study provides reference data for common horticultural activities using a kinematic and kinetic analysis.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3293-3297
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• 2012

The solvolysis rate constants of 5-nitro-2-furoyl chloride (5-$NO_2(C_4H_2O)$-2-COCl, 1) in 27 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and YCl solvent ionizing scale, with sensitivity values of $1.20{\pm}0.05$ and $0.37{\pm}0.02$ for l and m, respectively. The activation enthalpies (${\Delta}H^{\neq}$) were 5.63 to $13.0kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -25.9 to $-43.4cal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effect (SKIE, $k_{MeOH}/k_{MeOD}$) of 2.65 was also in accord with the $S_N2$ mechanism and was possibly assisted using a general-base catalysis. The product selectivity (S) for solvolysis of 1 in alcohol/water mixtures was 1.2 to 11, which is also consistent with the proposed bimolecular reaction mechanism.

• Journal of Microbiology and Biotechnology
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• v.20 no.9
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• pp.1283-1287
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• 2010

In eukaryotes, eRF3 participates in translation termination and belongs to the superfamily of GTPases. In this work, the dissociation constants for nucleosides bound to Euplotes octocarinatus eRF3 in the presence and absence of eRF1a were determined using fluorescence spectra methods. Furthermore, a GTP hydrolyzing assay of eRF3 was carried out using an HPLC method, and the kinetic parameters for GTP hydrolysis by eRF3 were determined. Consistent with data from humans, the results showed that eRF1a promoted the binding of GTP to eRF3 and the GTP hydrolyzing activity of eRF3. However, in contrast to the lack of GTP binding in the absence of eRF1 in human eRF3, the E. octocarinatus eRF3 was able to bind GTP by itself. The nucleotide binding affinity of the E. octocarinatus eRF3 also differed from the human data. A structure model and amino acid sequence alignment of potential G domains indicated that these differences may be due to valine 317 and glutamate 452 displacing the conserved glycine and lysine involved in GTP binding.

• Bulletin of the Korean Chemical Society
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• v.28 no.7
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• pp.1217-1220
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• 2007

• Bulletin of the Korean Chemical Society
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• v.27 no.6
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• pp.941-943
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• 2006