• Journal of the Korean Chemical Society
• /
• v.48 no.5
• /
• pp.461-466
• /
• 2004

Kinetics for the nucleophiles have been studied under high vacuum and high pressures in various temperatures. Pseudo-first order rate constants, second order rate constants, thermodynamic parameters and Hammett ${\rho}$-values are determined. The values of ${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq}\;and\;{\Delta}S^{\neq}$are all negative. The Hammett r-values are negative for the nucleophile (${\rho}$x) over the pressure range studied. The results of kinetic studies for pressure and nucleophilet show that these reactions proceed in typical $S_N2$ reaction mechanism and change of mechanism.

• Korean Journal of Applied Biomechanics
• /
• v.24 no.3
• /
• pp.229-238
• /
• 2014

This study comparatively analyzed the speed and segment coordination characteristics of Taekwondo hand techniques, while different attention focusing strategies were utilized. Ten elite Taekwondo poomsae athletes participated, and three different strategies (no focus, target focus, body focus) were utilized in random order. The hand velocity and upper body segment coordination characteristics were analyzed, with the following results. First, the maximum magnitudes of the hand velocity differed between the focus conditions for the Araenaereomakgi and Momtongjireugi techniques. Second, the angular velocity and kinetic energy transfer patterns of the segments differed between the focus conditions, and in the case of the body focus condition, the movement was more correct according to the theory. Third, the shoulder and elbow joint coordination patterns differed between the focus conditions, with more efficient movement shown with the body focus condition. In conclusion, we confirmed the potential of effectively using an attention focusing strategy in a taekwondo teaching situation. However, the effect on the movement coordination and results of the movement could be changed by a difference in the cue provided or the type of the task. In addition, depending on the task, the attention focusing strategy could affect the efficiency of the movement. Therefore, coaches and masters of Taekwondo will have to constitute determine the appropriate attention focusing cues based on the task.

• Journal of Korean Elementary Science Education
• /
• v.22 no.1
• /
• pp.15-28
• /
• 2003

The purpose of this study was to explore the relationships between the concept of heat and that of temperature for elementary students. Eight multiple choice type questions with explanation of reasons for selection were developed based on previous researches and the analysis of science curriculum for elementary students. The students of 9, 10, 11 years(n=292) were selected from two elementary schools in Taegu City. The responses of students' multiple choice and their explanations were analysed in each items χ² test used for the relationships between types of heat and temperature conceptions Half of elementary student could discriminate the two terms of heat and temperature, majority of them thought that heat is likely to be hot and temperature is the quantity of heat, which is not based on scientific conception. Elementary students thinkings about heat could be classified with material type of heat and molecular kinematics type. Material type of heat were more popular than with molecular kinematics type, although the latter is increased. Majority of students answered correctly in qualitative questions of mixing of hot and cold water, but about only one third of them answers in quantitative questions. Subtraction of cold temperature from hot temperature was the most popular explanation, even though one-quarter of students summed up the two temperature in quantitative situation of mixing hot and cold waters. Those who thought heat as the molecular kinetic responded more correctly in most difficult questions than those who as the material. Therefore, we concluded that the types of heat conceptions affected the concept formation of temperature.

• Wind and Structures
• /
• v.22 no.6
• /
• pp.663-684
• /
• 2016

Conical vortices generated at the corner regions of large-span flat roofs have been investigated by using the Particle Image Velocimetry (PIV) technique. Mean and instantaneous vector fields for velocity, vorticity, and streamlines were measured at three visual planes and for two different flow angles of $15^{\circ}$. The results indicated that conical vortices occur when the wind is not perpendicular to the front edge. The location of the leading edge corresponding to the negative peak vorticity and maximum turbulent kinetic energy was found at the center of the conical vortex. The wind pressure reaches the maximum near the leading edge roof corner, and a triangle of severe suctions zone appears downstream. The mean pressure in uniform flow is greater than that under turbulent flow condition, while a significant increase in the fluctuating wind pressure occurs in turbulent streams. From its emergence to stability, the shape of the vortex cross-section is nearly elliptical, with increasing area. The angle that forms between the vortex axis and the leading edge is much smaller in turbulent streams. The detailed flow structures and characteristics obtained through FLUENT simulation are in agreement with the experimental results. The three dimensional (3-D) structure of the conical vortices is clearly observed from the comprehensive arrangement of several visual planes, and the inner link was established between the vortex evolution process, vortex core position and pressure distribution.

• Korean Journal of Applied Biomechanics
• /
• v.24 no.4
• /
• pp.339-347
• /
• 2014

The purpose of this study was to investigate joint torques of lower body segments on professional golfers. Three dimensional swing analysis was conducted on the seven subjects. Each subject was asked to swing with 45 inches of Callaway driver, where two force plates (9286AA, Kistler, Switzerland) were built, with his normal speed and tempo. The resultant joint moments of the lower extremities were computed using the kinematic variables of the segments, anthropometric measures and the ground reaction force data by inverse dynamics method. Based on the results of this study, the following conclusions were drawn; It was found that the left ankle joint torque at 3rd phase was increased toward extension on the X-axis and abduction on the Y-axis. The left knee joint torque was alternated from flexion to extension direction in order to lower down the body weight at the beginning of the downswing. The lumbar joint torque was alternated from flexion to extension in order to speed up the upper body rotation which could increase the club head speed ultimately.

• Korean Journal of Applied Biomechanics
• /
• v.23 no.3
• /
• pp.245-252
• /
• 2013

The purpose of this study was to analyze the effect that various loads have on the lower limb biomechanics. The following variables were measured and analyzed; performance time for each phase, lower limb moments and joint angles, and ground reaction forces. The kinematic and kinetic data was recorded by 2 force platforms and a motion capture system while 12 healthy adults in their twenties stepped down three steps under loads of 0%, 10%, 20% BW. Results are as follows. First, the different loading conditions did not seem to significantly affect the performance times and the joint angles. Second, the largest ground reaction forces were observed at the 1 step at the 10% BW condition. Finally, at the 0% BW loading condition the right hip extension moment was the smallest and the left hip flexion moment was the largest. The results show that there are not any significant changes in the biomechanics of the lower limbs under loading conditions up to 20% BW. Further investigations including more loading conditions with more weights and more additional steps analyzed are needed.

• Bulletin of the Korean Chemical Society
• /
• v.11 no.4
• /
• pp.318-323
• /
• 1990

The bis(malonato)diaquochromate(III) ion, $Cr(C_3H_2O_4)_2^-$ in acidic solution hydrolyzes to give $Cr(C_3H_2O_4)^{+}.$ This reaction is catalyzed by ferric ion and the rate law for this cation catalyzed-aquation in a $HClO_4/NaClO_4$ medium, $I = 1.00 M, is-d[Cr(C_3H_2O_4)_2^-]/dt = ({\kappa}_1[Fe^{3+}] + {\kappa}_2[H^+])[Cr(C_3H_2O_4)_2^-]$ where ${\kappa}_1(25^{\circ}C) = 4.72×10^{-5} M^{-1}sec^{-1} ({\Delta}H^{\neq} = 22.5 Kcal/mol, {\Delta}S^{\neq} = - 2.58 eu) and {\kappa}_2(25^{\circ}C) = 4.75{\times}10^{-5} M^{-1}sec^{-1} ({\Delta}H^{\neq} = 21.2 Kcal/mol, {\Delta}S^{\neq} = - 7.13 eu).$ Rapid preequilibrium association of basic Cr-bound oxygen with $Fe^{3+},$ followed by rate-determining ring opening, is proposed to account for the ${\kappa}_1,$ hydrolysis pathway.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.20 no.5
• /
• pp.71-80
• /
• 2012

To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

• Journal of the Korean Chemical Society
• /
• v.28 no.3
• /
• pp.155-162
• /
• 1984

Kinetic studies for the nucleophilic substitution reactions of para-substituted benzyl bromides and benzyl iodide with anilines were carried out in MeOH-MeCN mixtures at 35.0$^{\circ}$C. Hammett $ {\rho}_N,\;{\rho}_C$, Bronsted $ {\beta}$ and solvatochromic correlation coefficient a, s values were determined in order to clarify the transition state variations caused by changing nucleophiles, substituents, leaving group and solvents. The results of solvatochromic equation showed that ${\pi}^{ast}$effect was a dominant factor for the reaction systems studied. It was shown that the reaction proceeds via the dissociative $S_N$2 mechanism using the potential energy surface model approach. The potential energy surface model approach however failed to account for the transition state variation due to leaving group changes. The quatum mechanical approach showed that kinetic results were consistent with proposed dissociative $S_N$2 mechanism.

• Journal of the Korean Chemical Society
• /
• v.29 no.1
• /
• pp.15-22
• /
• 1985

Kinetic studies of nucleophilic substitution reaction of substituted benzoyl cyanides and benzoyl chlorides with pyridines were conducted at 25$^{\circ}C$ in pure acetone solvent. Results showed that (ⅰ) magnitudes of $_{\rho}_S$, $_{\rho}_N$ and ${\beta}$ associated with a change of substituent in the nucleophile indicate relatively advanced bond-formation in the transition state, (ⅱ) the potential energy surface model is able to predict the reaction mechanism, but it is unable to predict the transition state variation to a more product-like transition state, where bond-formation is much more progressed than bond breaking, upon changing the leaving group to that with better leaving ability (ⅲ) the quantum mechanical model predicted the product-like transition state and slightly better leaving ability of CN- as compared with Cl-.