• Journal of the Korean institute of surface engineering
• /
• v.24 no.3
• /
• pp.119-124
• /
• 1991

Recently, the trend of research in hard coating is concentrate on developing the process of ionization rate under low operating pressure, to get the thin film with high adhesion and dense microstructures. In this study ionization rate enhancement type PVD process using permanent magnet is developed, which enhances the ionization rate by confining the plasma suppressing the wall loss of electron. By the result to investigate the characteristic of glow discharge, the ionization rate of this process is enhanced about twice as high as that of triod BARE process (about 26%), and more dense TiN microstructures are obtained in this process. Cylindrical ion energy analyzer is made and attached in front of a quadrupole mass filter for the analysis of the energy distribution of reactive gas and activated gas ions from the plasma zone. To analyze the operation mechanism of ion energy analyzer, computer simulation is performed by calculation the electric field environment using finite element method. By these analyses of ion energy distribution of outcoming ions from the plasma zone, it is found that magnetic field enhances ion kinetic energy as well as ionization rate. The other results of this study is that the foundation of feed-back system is constructed, which automatically control the partial pressure of reactive gas. In can be possible by recording the data of mass spectrum and ion energy analysis using A-D converter.

• Journal of the Korean Chemical Society
• /
• v.20 no.5
• /
• pp.333-339
• /
• 1976

The rates of solvolysis for 2-thenoyl chloride have been measured in aqueous acetone and aqueous ethanol at various temperatures ranging from 20 to $40^{circ}C$. The activation parameters and the Grundwald-Winstein's slope are determined by the analysis of solvolysis rates. The results indicated that the reaction rates of solvolysis are considerably slower than those of the reaction for benzoyl chloride due to the electron donating effect of thiophene nucleus. The results also showed that the reaction proceeds with the $S_N1$ mechanism in water-rich solvents whereas the $S_N2$ character increases with the decrease of water content, and overall reaction is subject to entropy control.

• Journal of Advanced Marine Engineering and Technology
• /
• v.32 no.4
• /
• pp.498-505
• /
• 2008

Many researches have been studied on in-cylinder flow as one of dominant effects for an engine combustion. The combustion phenomena of reciprocating engine is one of the most important processes affecting performance and emissions. One effective way to improve the engine combustion is to control the motion of the charge inside a cylinder by means of optimum induction system design. It is believed that the tumble and swirl motion generated during intake breaks down into small-scale turbulence in the compression stroke of the cycle. However, the exact nature of their relationship is not well known. To know this relationship definitely, this paper describes analytical results of the tumble motion, swirl motion, turbulence intensity, turbulence inside the cylinder of marine engine. 3-D computation has been performed by using STAR-CD solver and es-ice.

• Journal of Magnetics
• /
• v.12 no.3
• /
• pp.103-107
• /
• 2007

Magnetic field induced structural transition has been systematically investigated for $La_{1-x}Ba_xMnO_3$ with the fine control of carrier doping $(0.15{\leq}x{\leq}0.20)$. Application of a magnetic field results in the suppression of the rhombohedral-orthorhombic transition temperature $(T_s)$ and the increase of insulator-metal transition temperature $(T_{MI})$. Near x = 0.17, where $T_S$ is similar to $T_{MI}$ at zero magnetic field, we found that the $T_S$ smoothly decreased with magnetic field even though it intersected the $T_{MI}$ near 3 T. Also, the magnetostructural phase diagram obtained from the temperature sweep and from the magnetic field sweep is not significantly modified. By comparing the magnetostructural transition in $La_{1-x}Sr_xMnO_3$, we have suggested that the large disorder originated from ionic size differences between La and Ba may weaken the sensitivity of the kinetic energy of $e_g$ electrons on the degree of lattice distortion in $La_{1-x}Ba_xMnO_3$.

• Journal of ILASS-Korea
• /
• v.17 no.1
• /
• pp.14-19
• /
• 2012

The present study conducts experimental investigation on spreading and deposition characteristics of a $4.3{\mu}l$ de-ionized (DI) water droplet impacting upon aluminum (Al 6061) flat and textured surfaces. The micro-textured surface consisted the micro-hole arrays (hole diameter: $125{\mu}m$, hole depth: $125{\mu}m$) fabricated by the conventional micro-computer numerical control (${\mu}$-CNC) milling machine process. We examined the surface effect of texture area fraction ${\varphi}_s$ ranging from 0 to 0.57 and impact velocity of droplet ranging from 0.40 m/s to 1.45 m/s on spreading and deposition characteristics from captured images. We used a high-speed camera to capture sequential images for investigate spreading characteristics and the image sensor to capture image of final equilibrium deposition droplet for analyze spreading diameter and contact angle. We found that the deposition droplet on textured surfaces have different wetting states. When the impact velocity is low, the non-wetting state partially exists, whereas over 0.64 m/s of impact velocity, totally wetting state is more prominent due to the increase kinetic energy of impinging droplet.

• Corrosion Science and Technology
• /
• v.16 no.2
• /
• pp.59-63
• /
• 2017

Chelating solutions can be damaged by strong acids during oil production. To design effective corrosion inhibitors and other alternatives for corrosion control, it is important to understand not only the behavior of the system under operating condition but also the kinetics of electrochemical reactions during the corrosion process. In this study, the electrochemical behaviors of P-110 steel in aqueous fluids based on ethylenediaminetetraacetic acid (EDTA) compounds under various temperatures and hydrodynamic regime conditions were assessed. Electrochemical measurements were conducted using rotating disc electrodes manufactured. Electrolytes were prepared using aqueous compounds of EDTA like diammonium salt, disodium salt, and tetrasodium salt. Potentiodynamic polarization, electrochemical impedance, and mass loss tests were performed in order to assess the corrosion kinetic in electrolytes. Hydrodynamic effects were observed only in the cathodic polarization curve. This proves that hydrodynamic regime plays an important role in the corrosion of steel mainly in disodium and diammonium EDTA solutions. Two cathodic reactions controlled the corrosion process. However, oxygen level and pH of the electrolyte played the most important role in metal corrosion. Corrosion rates in those fluids were decreased drastically when oxygen concentration was reduced.

• Journal of Electrical Engineering and Technology
• /
• v.13 no.1
• /
• pp.60-67
• /
• 2018

The presence of induction motor loads in a power system may cause the phenomenon of delayed voltage recovery after the occurrence of a severe fault. A high proportion of induction motor loads in the power system can be a significant influence on the voltage stability of the system. This problem referred to as FIDVR(Fault Induced Delayed Voltage Recovery) is commonly caused by stall of small HVAC unit(Heating, Ventilation, and Air Conditioner) after transmission or distribution system failure. This delayed voltage recovery arises from the dynamic characteristics associated with the kinetic energy of the induction motor load. This paper proposes the UVLS (Under Voltage Load Shedding) control strategy for dealing with FIDVR. UVLS based schemes prevent voltage instability by shedding the load and can help avoid major economic losses due to wide-ranging cascading outages. This paper review recent topic about under voltage load shedding and compare decentralized load shedding scheme with conventional load shedding scheme. The load shedding strategy is applied to an actual system in order to verify the proposed FIDVR mitigation solution. Simulations demonstrate the effectiveness of the proposed method in resolving the problem of delayed voltage recovery in the Korean Power System.

• Journal of the Korean Society of Safety
• /
• v.8 no.4
• /
• pp.175-182
• /
• 1993

Volatilization of toxic heavy metals, especially, metal chlorides at elevated temperatures in oxidation conditions was observed using a thermogravimetric furnace since such metal chlorides used to be a cause for the disease of industrial workers by their toxicity and high volatile extent. Most of tested metal chloride compounds were evaporated or decomposed into gas phase at elevated temperatures ranged from 200~90$0^{\circ}C$, while CrCl$_3$ and NiC1$_2$became stable with converting into oxide forms. A kinetic model for evaporation/condensation could predict maximum evaporation flux and the calculated values were compared with real evaporation flux. The ratio of two fluxes could be explained as the fraction of impinging gas molecules to the condensing surface( $\alpha$ ) and obtained in the range of 10$^{-3}$ ~10$^{-9}$ for the experimented toxic heavy metal chlorides. This ratio might be used to define the volatile extent or toxicity of such toxic metal compounds. The schemes to avoid volatilization of toxic heavy metals Into the atmosphere were suggested as follows ; 1 ) controlling the compositions of metals and Chlorine produced substances( such as PVC ) in the treated materials using a reverse estimation from regulatory limit and characteristics of a processing facility, 2) Installation of wet type devices such as a scrubber for condensing the metal compounds.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.22 no.7
• /
• pp.63-69
• /
• 2014

Domestic automobile companies have adopted drum type brake system for commercial vehicles. However recently those companies have been applying disc-brake system to solve vehicle control-instability and inefficient heat discharge performance of conventional drum brake system for a medium commercial vehicle. Because the kinetic energy of a running commercial vehicle is relatively high, the brake system should discharge lots of heat energy while braking. A ventilated type brake disc has been used to increase heat discharge performance of a brake system. The vent structure of a disc highly affects cooling efficiency. This paper compares thermal characteristics of three types of vent structure in JASO C421 braking condition. It is found that the slant bend type disc has the lowest temperature and thermal stress distributions in the braking condition.

• International Journal of Automotive Technology
• /
• v.6 no.5
• /
• pp.453-460
• /
• 2005

The tumble or swirl flow is used to promote mixing of air and fuel in the cylinder and to enlarge turbulent intensity in the end of the compression stroke. Since the in-cylinder flow is a kind of transient state with rapid flow variation, which is non-steady state flow, the tumble or swirl flow has not been analyzed sufficiently whether they are applicable to combustion theoretically. In the investigation of intake turbulent characteristics using PIV method, typical flow characteristics were figured out by SCV configurations. An engine installed SCV had higher vorticity and turbulent strength by fluctuation and turbulent kinetic energy than a baseline engine, especially near the cylinder wall and lower part of the cylinder. Above all, the engine with SCV 8 was superior to the others in aspect of vorticity and turbulent strength. For energy dissipation, a baseline engine had much higher energy loss than the engine installed SCV because flow impinged on the cylinder wall. Consequently, as swirl flow was added to existing tumble flow, it was found that fluctuation increased and flow energy was conserved effectively through the experiment.