• Nuclear Engineering and Technology
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• v.52 no.2
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• pp.279-286
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• 2020

In this article, we develop a reactive distillation (RD) column configuration for the production of hydrogen. This RD column is in the HI decomposition section of the sulphur - iodine (SI) thermochemical cycle, in which HI decomposition and H₂ separation take place simultaneously. The section plays a major role in high hydrogen production efficiency (that depends on reaction conversion and separation efficiency) of the SI cycle. In the column simulation, the rigorous thermodynamic phase equilibrium and reaction kinetic model are used. The tuning parameters involved in phase equilibrium model are dependent on interactive components and system temperature. For kinetic model, parameter values are adopted from the Aspen flowsheet simulator. Interestingly, there is no side reaction (e.g., solvation reaction, electrolyte decomposition and polyiodide formation) considered aiming to make the proposed model simple that leads to a challenging prediction. The process parameters are determined on the basis of optimal hydrogen production as reflux ratio = 0.87, total number of stages = 19 and feeding point at 8th stage. With this, the column operates at a reasonably low pressure (i.e., 8 bar) and produces hydrogen in the distillate with a desired composition (H₂ = 9.18 mol%, H₂O = 88.27 mol% and HI = 2.54 mol%). Finally, the results are compared with other model simulations. It is observed that the proposed scheme leads to consume a reasonably low energy requirement of 327 MJ/kmol of H₂.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.517-520
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• 2006

The Korean peninsula has a number of coastal sites where the rhythmic rising and lowering of water surface due to tides results in strong tidal current. The kinetic energy of these currents can be efficiently exploited by use of tidal current turbines. The pilot tidal current power plant is to be constructed at the Uldolmok narrow channel between J info and Haenam, Our ins next Year, and extensive coastal engineer ing research works have been carried out. This paper describes and analyzes some observation results of field test about the efficiency of Helical turbine for tidal current power plant. The efficiency of turbine, which is diameter 2.2m and height 2.5m, is evaluated meximum RPM, torque, and current velocity. The tested turbines had the maximum efficiencies of the bounds of 25 to 35% in the current velocity range between 1.4 and 2.6 m/s. This result shows that the pilot tidal current power plant needs three helical turbines with diameter 3.0m and height 3.6m to produce electric power 500kW.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.311-324
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• 2018

Herein,the Neodymium ion ($Nd^{3+}$) doped CoAl-LDH have been successfully prepared via co-precipitation method and was used as a precursor of Nd-doped CoAl-mixed metal oxides (MMO). The photocatalytic activity of doped LDH and MMO was investigated in the degradation of an azo dye, C.I. Acid Red 14, under visible light irradiation. DRS and PL analysis demonstrated decreasing in the band gap energy and recombination of photo-induced charge carriers of Nd-doped LDH and MMO compared with the pristine CoAL-LDH. Due to significant difference in photocatalytic performance. A power law empirical kinetic model was obtained for predicting the photocatalytic degradation efficiency.

• Journal of Industrial Technology
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• v.25 no.B
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• pp.81-87
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• 2005

This project addresses the product identification and design application of corrugated products for kinetic architectural applications. Initially, an architectural approach to product identification was carried out with the end goal of demonstrating application design principles of numerous novel architectural examples from the forest products industry. A design and prototyping stage followed demonstrating such application design principles and functional analysis on various novel architectural examples. The results of coupling product identification with proven application advantages will be of potential value not only to architecture but also to other designers in the arts and sciences. The general motivation for the research arises out of a growing interest corrugated and paper products to be ideally suited for various architectural applications for their unparallel environmental benefits. Applications in architecture that use fewer resources and that adapt efficiently to complex and changing conditions are particularly relevant for an industry (architecture) that is increasingly aware of its environmental responsibilities. Corrugated and paper products are highly under-utilized by the building industry as design choice material for both interior and exterior applications. An increased awareness of the benefits of corrugated and paper products coupled with a process of designing for the total use and reuse will prove to be a valuable means by which issues of energy efficiency and environmental quality of buildings could be enhanced to be more efficient, affordable, and therefore reach a broader audience of users.

• Bulletin of the Korean Chemical Society
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• v.34 no.8
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• pp.2358-2366
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• 2013

Iron oxide (ferrihydrite, hematite, and magnetite) coated silica gels were prepared using a low-cost, easily-scalable and straightforward method as the adsorbent material for arsenic removal application. Adsorption of the anionic form of arsenic oxyacids, arsenite ($AsO^{2-}$) and arsenate ($AsO{_4}^{3-}$), onto hematite coated silica gel was fitted against non-linear 3-parameter-model Sips isotherm and 2-parameter-model Langmuir and Freundlich isotherm. Adsorption kinetics of arsenic could be well described by pseudo-second-order kinetic model and value of adsorption energy derived from non-linear Dubinin-Radushkevich isotherm suggests chemical adsorption. Although arsenic adsorption process was not affected by the presence of sulfate, chloride, and nitrate anions, as expected, bicarbonate and silicate gave moderate negative effects while the presence of phosphate anions significantly inhibited adsorption process of both arsenite and arsenate. When the actual efficiency to remove arsenic was tested against 1 L of artificial arsenic-contaminated groundwater (0.6 mg/L) in the presence competing anions, the reasonable amount (20 g) of hematite coated silica gel could reduce arsenic concentration to below the WHO permissible safety limit of drinking water of $10{\mu}g/L$ without adjusting pH and temperature, which would be highly advantageous for practical field application.

• Applied Chemistry for Engineering
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• v.32 no.6
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• pp.706-710
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• 2021

In the current research, thermal and catalytic thermogravimetric (TG) analysis of polyethylene terephthalate (PET) over natural zeolite (NZ), olivine, bentonite, HZSM-5, and HAl-MCM-41 were investigated using a TG analyzer and model-free kinetic analysis. Catalytic TG analysis of PET was carried out at multi-heating rates, 10, 20, 30, and 40 ℃/min, under nitrogen atmosphere. Apparent activation energy (Ea) values for the thermal and catalytic pyrolysis of PET were calculated using Flynn-Wall-Ozawa method. Although natural catalysts, NZ, olivine, and bentonite, could not lead the higher PET decomposition efficiency than synthetic zeolites, HZSM-5 and HAl-MCM-41, maximum decomposition temperatures on the differential TG (DTG) curves for the catalytic pyrolysis of PET, 436 ℃ over olivine, 435 ℃ over bentonite, and 434 ℃ over NZ, at 10 ℃/min, were definitely lower than non-catalytic pyrolysis. Calculated Ea values for the catalytic pyrolysis of PET over natural catalysts, 177 kJ/mol over olivine, 168 kJ/mol over bentonite, and 171 kJ/mol over NZ, were also not lower than those over synthetic zeolites, however, those were also much lower than the thermal decomposition, suggesting their feasibility as the proper and cost-effective catalysts on the pyrolysis of PET.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.223-226
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• 2004

In this paper, removal of diesel hydrocarbons (C$_{10}$-C$_{22}$) for dry and moist soil was investigated so that microwave-enhanced soil vapor extraction(SVE) reduced soil treatment time and raised remediation efficiency. Kinetic constants of diesel hydrocarbons with microwave energy were 7 times on dry soil and 1580 times on moist soil as much as those of SVE process without microwave energy. The diesel removals were 67.7～78.4% for $C_{10}$ and $C_{12}$, and 0～18.5% for $C_{14}$～C$_{22}$ for dry and moist soil with SVE process only. On the other hand, dry soil with microwave-enhanced SVE process showed 89.3～99.4% removal for $C_{10}$ and $C_{12}$ and 35.6～67.0% for hydrocarbons over $C_{14}$. All hydrocarbons(C$_{10}$～C$_{22}$) studied were significantly removed (93.6～99.8%) for moist soil with microwave-enhanced SVE process. Almost all diesel hydrocarbons were usually considered as semi-volatile compounds(SVOCs). Microwave-enhanced SVE process might have a great potential for remediation of soils contaminated with SVOCs.OCs.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.3
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• pp.181-189
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• 2000

The aerodynamic characteristics of large transport vehicle has become more and more important in recent vehicle design to improve driving performance in high speed cruising and raise the product valve with regard to a comfortable driving condition. Hence, detailed knowledge of the flow field around truck coner vane is essential to improve fuel efficiency and reduce the dirt contamination on vehicle body surface. In this study, three-dimensional flow characteristics around corner vane attached to truck cabin were computed for the steady, incompressible, and high speed viscous flow, adopting the RNG k-$\varepsilon$ turbulence model. In order to investigate the influence of configuration and structure of corner vane, computations were carried out for four cases at a high Reynolds number, Re=4.1$\times$106 (based on the cabin height). The global flow patterns, drag coefficient and the distributions such as velocity magnitude, turbulent kinetic energy around the corner vane, were examined. As a result of this study, we could identify the flow characteristics around corner vane for the variation of corner vane length and width. Also, suggest the improved structure to reduce the dirt contamination in cabin side.

• Composites Research
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• v.18 no.6
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• pp.48-53
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• 2005

In this study, to improve the ballistic efficiency of very brilliant alumina-silica armor material, forming press and sintering temperature were changed. After physical/mechanical measurement, we measured ballistic properties about KE(Kinetic Energy, L/D=10.7, tungsten heavy alloy) and HEAT(High Explosive Anti-Tank, K215) projectiles and analyzed them. As a result, in $1235^{\circ}C$, it appeared the highest ballistic efficiency about HEAT and it improved $22\%$ ballistic efficiency, better than invented alumina-silica armor material before.

• Journal of Power System Engineering
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• v.17 no.2
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• pp.103-107
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• 2013

The structure of a variable liquid column oscillator(a VLCO) is analogous to that of the tuned liquid column damper used to suppress oscillatory motion in large structures like tall buildings and cargo ships. The VLCO is a system absorbing high kinetic energy of accelerated motions of multiple floating bodies in the effect of air springs occurred by installation of inner air chambers. Thus, VLCO can improve the efficiency of energy than wave energy converters of the activating object type made in Pelamis Company. In this research, the experiment was performed that a simple floating body was filled with internal fluid of same draft. The characteristics of motions were evaluated in each case of the opening or closing of the upper valves.