• Title/Summary/Keyword: Key Technology

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A New Model and Equation Derived From Surface Tension and Cohesive Energy Density of Coagulation Bath Solvents for Effective Precipitation Polymerization of Acrylonitrile

  • Zhou, You;Xue, Liwei;Yi, Kai;Zhang, Li;Ryu, Seung Kon;Jin, Ri Guang
    • Carbon letters
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    • v.13 no.3
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    • pp.182-186
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    • 2012
  • A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (${\gamma}$) and cohesive energy density ($E_{CED}$). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (${\gamma}$/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.

Asparagine Residue at Position 71 is Responsible for Alkali-Tolerance of the Xylanase from Bacillus Pumilus A-30

  • Liu, Xiang-Mei;Qi, Meng;Lin, Jian-Aiang;Wu, Zhi-Hong;Qu, Yin-Bo
    • Journal of Microbiology and Biotechnology
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    • v.11 no.3
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    • pp.534-538
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    • 2001
  • The xynA gene encoding an alikali-tolerant endo-1,4-${\beta}$-xylanase (XYN) was cloned from the alkalophilic Bacillus pumilus A-30. The nucleotide sequence of a 974-bp DNA fragment containing the xynA was determined. An ORF of 684 nucleotides that encoded a protein of 228 amino aicds was detected. Asparagine-71 of XYN from B. Pumilus A-30 showed to be highly conservative in alkaline xylanases of family G/11, upon comparing the amino acid sequences of 17 family G/11 xylanases. Site-directed mutation of N71D of the xynA gene resulted in a decrease of 12.4% in the specific acitivity and a significant decline in the enzyme activity in the alkaline pH range.

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Highly Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Novel Chiral tert-Amino Alcohols

  • Zhang, Cong-Hai;Yan, Sheng-Jiao;Pan, Sheng-Qiang;Huang, Rong;Lin, Jun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.869-873
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    • 2010
  • A series of novel chiral tert-amino alcohols 4a-h derived from enantiomerically pure phenylalanine were synthesized efficiently and used as chiral ligands in the catalytic enantioselective ethylation of aldehydes with diethylzinc (diethylzinc-to-aldehyde addition). The use of 10 mol % of the amino alcohols led to the corresponding sec-alcohols with excellent enantioselectivities (up to 100% ee) and high yields.

Dynamic Session Key based Pairwise Key Management Scheme for Wireless Sensor Networks

  • Premamayudu, B;Rao, Koduganti Venkata;Varma, P. Suresh
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.12
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    • pp.5596-5615
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    • 2016
  • Security is one of the major challenges in the Wireless Sensor Networks (WSNs). WSNs are more vulnerable to adversarial activities. All cryptographic security services indirectly depend on key management. Symmetric key management is the best key establishment process for WSNs due to the resource constraints of the sensors. In this paper, we proposed dynamic session key establishment scheme based on randomly generated nonce value and sensor node identity, in which each sensor node is equipped with session key on expire basis. The proposed scheme is compare with five popular existing key management systems. Our scheme is simulated in OMNET++ with MixiM and presented experimental results. The analytical study and experimental results show the superiority of the proposed scheme over the existing schemes in terms of energy, storage, resilience and communication overhead.

Intelligent Scheduling Control of Networked Control Systems with Networked-induced Delay and Packet Dropout

  • Li, Hongbo;Sun, Zengqi;Chen, Badong;Liu, Huaping;Sun, Fuchun
    • International Journal of Control, Automation, and Systems
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    • v.6 no.6
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    • pp.915-927
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    • 2008
  • Networked control systems(NCSs) have gained increasing attention in recent years due to their advantages and potential applications. The network Quality-of-Service(QoS) in NCSs always fluctuates due to changes of the traffic load and available network resources. To handle the network QoS variations problem, this paper presents an intelligent scheduling control method for NCSs, where the sampling period and the control parameters are simultaneously scheduled to compensate the effect of QoS variation on NCSs performance. For NCSs with network-induced delays and packet dropouts, a discrete-time switch model is proposed. By defining a sampling-period-dependent Lyapunov function and a common quadratic Lyapunov function, the stability conditions are derived for NCSs in terms of linear matrix inequalities(LMIs). Based on the obtained stability conditions, the corresponding controller design problem is solved and the performance optimization problem is also investigated. Simulation results are given to demonstrate the effectiveness of the proposed approaches.

A Modified Capacitor Current Feedback Active Damping Approach for Grid Connected Converters with an LCL Filter

  • Wan, Zhiqiang;Xiong, Jian;Lei, Ji;Chen, Chen;Zhang, Kai
    • Journal of Power Electronics
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    • v.15 no.5
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    • pp.1286-1294
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    • 2015
  • Capacitor current feedback active damping is extensively used in grid-connected converters with an LCL filter. However, systems tends to become unstable when the digital control delay is taken into account, especially in low switching frequencies. This paper discusses this issue by deriving a discrete model with a digital control delay and by presenting the stable region of an active damping loop from high to low switching frequencies. In order to overcome the disadvantage of capacitor current feedback active damping, this paper proposes a modified approach using grid current and converter current for feedback. This can expand the stable region and provide sufficient active damping whether in high or low switching frequencies. By applying the modified approach, the active damping loop can be simplified from fourth-order into second-order, and the design of the grid current loop can be simplified. The modified approach can work well when the grid impedance varies. Both the active damping performance and the dynamic performance of the current loop are verified by simulations and experimental results.

An Exponential Smoothing Adaptive Failure Detector in the Dual Model of Heartbeat and Interaction

  • Yang, Zhiyong;Li, Chunlin;Liu, Yanpei;Liu, Yunchang;Xu, Lijun
    • Journal of Computing Science and Engineering
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    • v.8 no.1
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    • pp.17-24
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    • 2014
  • In this paper, we propose a new implementation of a failure detector. The implementation uses a dual model of heartbeat and interaction. First, the heartbeat model is adopted to shorten the detection time, if the detection process does not receive the heartbeat message in the expected time. The interaction model is then used to check the process further. The expected time is calculated using the exponential smoothing method. Exponential smoothing can be used to estimate the next arrival time not only in the random data, but also in the data of linear trends. It is proven that the new detector in the paper can eventually be a perfect detector.

Dynamic stiffness analysis of steel-concrete composite beams

  • Li, Jun;Huo, Qiji;Li, Xiaobin;Kong, Xiangshao;Wu, Weiguo
    • Steel and Composite Structures
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    • v.16 no.6
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    • pp.577-593
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    • 2014
  • An exact dynamic stiffness method is introduced for investigating the free vibration characteristics of the steel-concrete composite beams consisting of a reinforced concrete slab and a steel beam which are connected by using the stud connectors. The elementary beam theory is used to define the dynamic behaviors of the two beams and the relative transverse deformation of the connectors is included in the formulation. The dynamic stiffness matrix is formulated from the exact analytical solutions of the governing differential equations of the composite beams in undamped free vibration. The application of the derived dynamic stiffness matrix is illustrated to predict the natural frequencies and mode shapes of the steel-concrete composite beams with seven boundary conditions. The present results are compared to the available solutions in the literature whenever possible.

Encapsulation of 2,4-Dihydroxybenzophenone into Dodecylbenzenesulfonate Modified Layered Double Hydroxide for UV Absorption Properties

  • Li, Shifeng;Shen, Yanming;Liu, Dongbin;Fan, Lihui;Wu, Keke
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.392-396
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    • 2014
  • New organic-inorganic composite of 2,4-dihydroxybenzophenone (BP-1) encapsulation into dodecylbenzenesulfonate (DBS) modified layered double hydroxide (LDH) was successfully prepared. The surface, structural, thermal and absorption properties of the BP-1/DBS-LDH nanohybrid was characterized by BET analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG) and diffuse reflectance UV-Vis absorbance spectra (DRUV-vis). The interlayer configuration of composite and the adsorption mechanism of BP-1 on MgAl-DBS-LDH were discussed. It was suspected that DBS anions located in the form of monolayer arrangement with a $75^{\circ}$ anti parallel angle between dodecylbenzenesulfonate chain axis. The diffuse reflectance UV-Vis absorbance results revealed that the UV absorbing wavelength of BP-1/DBS-LDH evidently extends to about 400 nm, which shows that the BP-1/DBS-LDH has the potential application as a UV absorber.

Strain-rate effects on interaction between Mode I matrix crack and inclined elliptic inclusion under dynamic loadings

  • Li, Ying;Qiu, Wan-Chao;Ou, Zhuo-Cheng;Duan, Zhuo-Ping;Huang, Feng-Lei
    • Structural Engineering and Mechanics
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    • v.44 no.6
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    • pp.801-814
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    • 2012
  • The strain rate effects on the interaction between a Mode I matrix crack and an inclined elliptic matrix-inclusion interface under dynamic tensile loadings were investigated numerically, and the results are in agreement with previous experimental data. It is found, for a given material system, that there are the first and the second critical strain rates, by which three kinds of the subsequent crack growth patterns can be classified in turn with the increasing strain rate, namely, the crack deflection, the double crack mode and the perpendicular crack penetration. Moreover, such a crack deflection/penetration behavior is found to be dependent on the relative interfacial strength, the inclined angle and the inclusion size. In addition, it is shown that the so-called strain rate effect on the dynamic strength of granule composites can be induced directly from the structural dynamic response of materials, not be entirely an intrinsic material property.