• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.84-89
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• 1986

A newflexible $N_2O_2$-type tetradentate ligand. Ethylenediamine-N,N'-di-${\alpha}$-isobutyric acid(eddib), has been synthesized, and dichloro cobalt(III) complex of eddib has been prepared via the air-oxidation technique. Only S-cis isomer has been yielded during the preparation of complex. Ring strain and steric hinderance are cited as the cause for the preference for the S-cis geometric configuration. On series of cobalt(III) complexes of eddib, $[Co(eddib)L]^{n+}$ $(L = Cl{\cdot}(H_2O),\;CO_3^{2-},\;(H_2O)_2)$have been prepared in situ. In their electronic absorption spectra, the absorption maxima and their intensities of the above series of complexes are on the ordinary line of the spectrochemical and hyperchromic series. Elemental analysis, IR, NMR and electronic absorption spectra have been used to characterize the complex and geometries of the complex.

• Korean Journal of Food Science and Technology
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• v.25 no.3
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• pp.214-219
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• 1993

Properties of the antioxidative fraction isolated from browning reaction product (BRP) that were obtained from 2 M L-ascorbic acid (AsA) solution (adjusted to pH 7.0) by heating for 25 hrs at $85^{\circ}C$ were investigated. Both of dialyzable and nondialyzable fraction isolated from BRP showed antioxidative effect. Dialyzable fraction has stronger antioxidative activity than nondialyzable. Dialyzable fraction was divided into the three fractions (A, B, C) by gel filtration. Among these fractions, the fraction (A) that had the highest reducing power and lowest browning drgree had lowest antioxidative activity. The fraction (C) that had lowest reducing power and highest browning degree showed strongest antioxidative effect. In the UV-visible spectrum of these fractions, the maximum absorption wavelengths of fraction A and B were 266.1 and 257.4nm, respectively, and fraction C showed a weaker absorption peak at 274.8nm. Infrared (IR) spectrum results showed that all fractions (A, B, C) had both hydroxy and carboxylic groups, and fraction B and C had carboxylic ester group.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.28 no.3
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• pp.285-290
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• 1983

Two methods were tested to establish the cropping period for rice cultivation using the meteorological data. The Hanyu-Uchijima method was based on the normal average temperature to select the earliest possible transplanting date (ETD), the earliest heading date (EHD), the optimum heading date (OHD) and the latest maturing date (LMD). The probability method was based on the temperature occurrence probability. The cropping period based on the probability method gave higher stability than H-U method for year variability. The ETD by the probability of 75 to 90 percents was May 12 to 22 for northern part of Korea, May 15 to 25 for east coastal area and May 4 to 16 for southern part, respectively. In Chuncheon area, the rice varieties requiring more than 1700 degree-days from transplanting to heading might not be appropriate due to low temperature condition and those requiring 1900 degree days were not allowable in Kangreung area. The OHD was July 30 to August 8 in northern part of the country and August 11 to 16 in southern part for Tongil varieties which demand higher temperature than common Japonica varieties. The OHD for Japonica varieties were 5 to 7 days later than Tongil varieties. The LMD was September 30 to October 2 in northern part, October 13 to 14 in east costal area and October 7 to 14 in southern part, and was earlier than the first frost date.

• Analytical Science and Technology
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• v.7 no.1
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• pp.33-39
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• 1994

The purpose on this study was to develop a new improved chromatographic method for determination of trace phenols from environmental waste water. The research was carried out with selected 8 phenols, and solid-phase extraction was employed as sample pretreatment method. The coupling of XAD-4 and Dowex $1{\times}8$ resin as preconcentration column increased the selectivities toward interferences coexisted in matrix. Automation was accomplished with on-line process of pretreatment and HPLC system. After elution of sample through XAD-4 column, phenols were adsorbed by dispersion force, then displaced from it by ACN basified, simultaneously and selectively readsorbed via anion exchange on Dowex $1{\times}8$. Dowex $1{\times}8$ column was washed by water. Phenols readsorbed were removed from Dowex $1{\times}8$ column by a minimum volumn of methanol containing HCl. Each pretreatment step was connected by switching valves and the eluate was directly on-line injected to obtain fast and reliable results into the HPLC. Recovery of phenols was greater than 90%. To examine utility of this method, analysis of phenols from laboratory waste water sample which was added some organic pollutants to find with phenols on environmental waste water were also accomplished without their interference effects.

• Korean Journal of Food Science and Technology
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• v.29 no.1
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• pp.77-81
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• 1997

In order to develop a new type of natural seasoning material combining fish meat with seaweed, a processing method of the mixture of enzyme treated mackerel meat and Laminaria powder was studied. Mackerel meat previously boiled and deboned was treated with proteolytic enzyme to enhance taste of meat by proper hydrolysis. The enzyme-treated meat was dried at $100{\pm}2^{\circ}C$ for 4 hrs, and finally mixed with kelp power, moistened in advance, plus binding agents (0.02% calcium carbonate) to aid the formation of pellets by extrusion. Boiled mackerel meat of enzyme treated (0.03% Protease-A) at $50^{\circ}C$ for 90 min was adequate to result an increase in 6 times of total free amino acid content and about 10% increase of taste-enhancing amino acids such as glutamic acid, glycine, arginine, lysine.

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.177-185
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• 2011

In order to reduce traffic accidents at long road sections involving high risks of traffic accidents, including tunnels, bridges or curves, the National Police Agency have decided a tentative installation and operation of an automated point-to-point speed enforcement system based on cameras at January, 2007. The first system was established at the direction to Kangreung of Dunnae Tunnel at December, 2007. Currently, the automated point-to-point speed enforcement system operates at 11 sections including eight sections on expressways and three sections on national highways. However, there have been few researches on the effects of the system upon the reduction of traffic accidents in a scientific way. To this end, this research effort was initiated to evaluate the effect of the automated point-to-point speed enforcement system on traffic safety by comparing the number of traffic accidents before and after the installation of the system using a comparison-group(C-G) method. Three-year-long traffic accident data for the expressways were collected in order to evaluate the system. As a result, the installation of the system was found to reduce traffic accidents by 49.97% in average.

• Journal of the Korean earth science society
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• v.28 no.2
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• pp.202-213
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• 2007

The Odaesan earthquake $(M_L=4.8)$ occurred near Mt. Odae, Jinbu-Myon, Pyongchang-Gun, Kangwon Province on January 20, 2007. It has a shallow focal depth about 10 km. Its felt area covers most of the southern peninsula except some southern and western inland area. The maximum MM intensity was VI in the areas including Jinbu, Doam, Kangreung, Jumunjin, and Pyongchang. In these areas, there was a very strong shaking that caused several cracks on the walls of buildings and houses, slates falling off the roof, tiles being off the wall, things falling off the desk, and rock falling from the mountains. In order to get fault plane solutions, grid searches were performed by fitting distributions of P-wave first-motion polarities and SH/P amplitude ratios for each event. The results showed that the main shock represented right-lateral strike-slip sense and two aftershocks, reverse sense. It seems that the seismogenic fault may be the NNE-SSW trending Weoljeongsa fault near the epicenter based on the distribution of epicenters (foreshock, main shock, and aftershocks), damage area, and fault plane solution. The distribution of the epicenters indicates that the length of the subsurface rupture is estimated to be about 2 km.

• Journal of the Korean Chemical Society
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• v.33 no.6
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• pp.633-643
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• 1989

The R$Rh_2(ap)_4$(2,2-trans) isomer (ap = 2-anilinopyridinate), which has two anilino nitrogens and two pyridyl nitrogens bound to each rhodium ion trans to their own kind, shows activation towards the one electron reduction of dioxygen at -0.40 V vs SCE. The ESR spectrum taken at 123 K proves the formation of a $[Rh_2(ap)_4(O_2)]$ ion with oxygen axially bound to one rhodium ion and the complex is at a RhⅡ2 oxidation state. The complex will form [$Rh_2(ap)_4(O_2)(CH_3CN)]^-$ in presence of $CH_3CN/CH_2Cl_2$ mixture without breaking the Rh-$O_2^-$ bond. When oxidized at -0.25 and 0.55 V, $[Rh_2(ap)_4(O_2)]$ will undergo two one electron oxidations to form $Rh_2(ap)_4(O_2)[Rh_2(ap)_4(O_2)]^+$. Both species have an axially bound superoxide ion but the former is at $Rh^{II}Rh^{III }$and the later at $Rh^{III}_2$ oxidation states. The ESR spetra and $CH_3CN$ addition study, on the other hand, show that the later complex is better described as $[Rh_{II}Rh^{III}(ap)_4(O_2)]^+$ with the odd electron localized on rhodium ion and the complex has an axially coordinated molecular oxygen. The electrochemical and ESR studies also show that the degree of dioxygen activation is a function of electrochemical redox potential.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.8
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• pp.813-821
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• 2005

This paper presents a modeling study of thermal dynamics and turbid current in the Obong Lake, Kangreung. The lake formed by the artificial dam in 1983 for agricultural water supply, is currently under consideration of reconstruction in order to expand the volume of reservoir for water supply and flood control in downstream area. The US Army Corps of Engineers' CE-QUAL-W2, a two-dimensional laterally averaged hydrodynamic and water quality model, was applied to the lake after reconstruction as well as the present lake. The model calibration and verification were conducted against surface water levels and temperature of the lake measured during the years of 2001 and 2003. The model results showed a good agreement with fold measurements both in calibration and verification. Utilizing the validated model, an impact of dam reconstruction on vertical temperature and hydrodynamics were predicted. The model results showed that steep temperature gradient between epilimnion and hypolimnion would be formed during summer, along with extension of cold deep water after reconstruction. During winter and spring seasons, however, the vertical temperature profiles was predicted to be quite similar both before and after reconstruction. This results indicated that thermal stratification would become stronger during summer and stay longer after dam reconstruction. From the examination of predicted water movements, it was noticed that the upstream turbid current would infiltrate into the interface between metalimnion and hypolimnion and then suspended solids would slowly settle down to the bottom before reconstruction. After reconstruction, however, it was shown that the upstream turbid current would stay longer in metalimnion with similar density due to strong stratification. The model also predicted that dam reconstruction would make suspended solids near the dam location significantly decrease.

• Korean Journal of Food Science and Technology
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• v.30 no.3
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• pp.552-556
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• 1998

In this study, the quality stability of a kind of natural seasoning material, the mixture of enzyme treated mackerel meat and Laminaria powder during the storage was investigated by measuring the TBA(thiobarbituric acid)value, extend of browning, changes in amino nitrogen and chlorophyll a, and fatty acid composition, and the results of sensory evaluation. Addition of sodium alginates (0.08%) and calcium carbonate (0.02%) seemed effective as a binder to yield clarity of the hot water extract of the product. In results, the mixture of Laminaria powder and the enzyme treated mackerel meat added with 0.08% sodium alginate and 0.02% calcium carbonate was more stable in overall quality than the other cases of preparation. And the taste of the mixture could favorably compete with that of dried anchovy extracts.