• 제목/요약/키워드: Kamlet-Taft equation

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Solvent Effects on the Electronic Spectra of Some Heterocyclic Azo Dyes

  • Behera, Pradipta Kumar;Xess, Anita;Sahu, Sachita
    • Bulletin of the Korean Chemical Society
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    • 제35권2호
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    • pp.610-616
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    • 2014
  • The influence of solvent polarity on the absorption spectra of some synthesized azo dye with heterocyclic moieties and ${\beta}$-naphthol (1-3) have been investigated using a UV-Visible spectrophotometer. The spectral characteristics of the azo dyes (1-3) in different solvents at room temperature were analyzed. The solvatochromic empirical variables like ${\pi}^*$, ${\alpha}$, and ${\beta}$ have been used to discuss the solvatochromic behaviour of the dyes and to evaluate their contributions to the solute-solvent interactions. A multi-parameter regression model for quantitative assessment of the solute/solvent interaction and the absorption has been used to explain the solvent effect on azo dyes (1-3).