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Effects of Carbon Fiber Arrangement on Properties of LSI Cf-Si-SiC Composites (탄소섬유 배열이 LSI Cf-Si-SiC 복합체의 특성에 미치는 영향)

  • Ji, Young-Hwa;Han, In-Sub;Kim, Se-Young;Seo, Doo-Won;Hong, Ki-Seog;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.561-566
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    • 2008
  • Carbon fiber fabric-silicon carbide composites were fabricated by liquid silicon infiltration (LSI) process. The porous two-dimensional carbon fiber fabric performs were prepared by 13 plies of 2D-plain-weave fabric in a three laminating method, [0/90], [${\pm}45$], [$0/90/{\pm}45$] lay-up, respectively. Before laminating, a thin pyrolytic carbon (PyC) layer deposited on the surface of 2D-plain weave fabric sheets as interfacial layer with $C_3H_8$ and $N_2$ gas at $900^{\circ}C$. A densification of the preforms for $C_f-Si-SiC$ matrix composite was achieved according to the LSI process at $1650^{\circ}C$ for 30 min. in vacuum atmosphere. The bending strength of the each composite were measured and the microstructural consideration was performed by a FE-SEM.

Analysis of HFC-245fa organic Rankine cycle for geothermal power generation (지열 발전을 위한 HFC-245fa 유기 랭킨 사이클의 성능해석)

  • Baik, Young-Jin;Kim, Min-Sung;Chang, Ki-Chang;Yoon, Hyung-Kee;Lee, Young-Soo;Ra, Ho-Sang
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.5 no.1
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    • pp.1-6
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    • 2009
  • In this study, an ORC (Organic Rankine Cycle) is investigated for a low-temperature geothermal power generation by a simulation method. A steady-state simulation model is developed to analyze cycle's performance. The model contains a turbine, a pump, an expansion valve and heat exchangers. The turbine and pump are modelled by an isentropic efficiency. Simulations were carried out for the given heat source and sink inlet temperatures, and given flow rate that is based on the typical power plant thermal-capacitance-rate ratio. HFC-245fa is considered as a working fluid of the cycle. Simulation results, at the given secondary working fluids conditions, show that even though the power can be presented by both the evaporating temperature and the turbine inlet superheat, it depends on the evaporating temperature primarily.

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Characteristics of composite membranes containing ionic liquid and acid for anhydrous high temperature PEFCs (무가습 고온 PEFC용 이온성 액체 및 산이 함유된 복합막의 특성)

  • Baek, Ji-Suk;Park, Jin-Soo;Park, Seung-Hee;Yang, Tae-Hyun;Park, Gu-Gon;Yim, Sung-Dae;Kim, Chang-Soo;Shul, Young-Gun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.378-378
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    • 2009
  • The ionic liquid-based sulfonated hydrocarbon composite membranes was prepared for use in anhydrous high temperature-polymer electrolyte fuel cells (HT-PEFCs). Ionic liquid behaves like water in the composite membranes under anhydrous condition. However the composite membranes show a low conductivity and high gas permeability as the content of ionic liquid increases due to its high viscosity and content of ionic liquid, respectively. Hence, in order to enhance the proton conductivity and to reduce the gas permeability of the composite membranes with low content of ionic liquids, the acid containing a common ion of ionic liquid was added to the composite membranes. The characterization of composite membranes was carried out using small-angle X-ray scattering (SAXS), thermogravimetric analyzer (TGA) and impedance spectroscopy. As a result, the composite membranes containing acid showed higher proton conductivity than those with no acid under the un-humidified condition due to a decrease in viscosity. In addition, the proton conductivity of composite membranes increased with increasing mole concentration of acid.

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The optical properties dependent on different doping concentrations of activators Cu2+ and in ZnS:Mn,Cu,Cl phosphor (활성제 Cu2+ 및 도핑농도에 따른 ZnS:Mn,Cu,Cl 형광체의 광학적 특성)

  • Han, Sang-Do;Kwon, Ae-Kyung;Lee, Hak-Soo;Han, Chi-Hwan;Kim, Jung-Duk;Gwak, Ji-Hye
    • Journal of Sensor Science and Technology
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    • v.15 no.5
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    • pp.323-327
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    • 2006
  • Manganese, copper and chlorine-doped ZnS phosphors (ZnS:Mn,Cu,Cl) were synthesized through solid-state reaction. Manganese was added in the range of amount $1.4{\sim}5.3$ mol % to ZnS phosphors containing 0.2 or 1.0 mol % of copper and a small amount of chlorine. As-synthesized phosphors showed a spherical morphology with a mean size of ${\sim}20\;{\mu}m$ and structural properties of Wurtzite, which were identified by SEM and XRD, respectively. Optical properties of ZnS:Mn,Cu,Cl synthesized with various concentrations of activators were analysed by both of PL and EL spectra. Samples mainly showing only 580 nm-orange emission by 380 nm-UV excitation gave different EL spectra of blue, green, and orange emissions at 450, 480 and 580 nm, respectively, depending on concentrations of $Cu^{2+}$ and $Mn^{2+}$.

Design Standard of Activated Carbon Vessel for the Intermittent Emission Sources of Volatile Organic Compounds (휘발성 유기화합물의 간헐적 배출원에 대한 활성탄 흡착 시스템 설계기준)

  • Lee, Si-Hyun;Lim, Jeong-Whan;Rhim, Young-Jun;Kim, Sang-Do;Woo, Kwang-Je;Son, Mi-Sook;Park, Hee-Jae;Seo, Man-Cheol;Ryu, Seung-Kon
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.250-260
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    • 2007
  • It was investigated that the emission characteristics of volatile organic compounds (VOCs) from small and medium companies located on industrial complexes in Metropolitan area. The emission characteristics are intermittent sources in which VOCs emissions are highly depends on the working condition. Optimized ventilation system to improve air quality in working area for the three typical companies were installed. Adsorption characteristics of major VOCs such as MEK, IPA, and toluene emitted front the companies were investigated for design of the activated carbon vessel as a VOCs control facility in each company. Concentration of total hydrocarbon and gas amounts needed to ventilation were also used as a design parameter. Mixed adsorbent to improve adsorption characteristics of problematic solvents like IPA and the design guideline of the activated carbon vessel have been suggested.

Experimental Study on Heating Performance Characteristic of 100 kW Heat Pump to Generate ℃ Steam (120℃ 스팀 생성을 위한 100 kW급 히트펌프의 실험적 연구)

  • Wang, Eunseok;Na, Sun-Ik;Lee, Gilbong;Baik, Young-Jin;Lee, Young-Soo;Lee, Beomjoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.30 no.2
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    • pp.100-106
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    • 2018
  • Recently, the development of a heat pump technology to recover process waste heat and to generate steam of $120^{\circ}C$ or higher required for industrial processes, has attracted attention. The research of conventional heat pump utilizing the available energy is used primarily for air conditioning, and the production temperature is about $60^{\circ}C$, so it is difficult to utilize it for industrial use. Therefore, in this study, we developed a steam heat pump (SGHP) which recovers the waste heat of process and generates steam at $120^{\circ}C$. The low-pressure refrigerant R245fa, considered to be an eco-friendly refrigerant, has been selected as the refrigerant for SGHP in this study since its Ozone Depletion Potential (ODP) is zero and the Global Warming Potential (GWP) is relatively low. A flash tank functioning as a phase separator was installed in the rear stage of the condenser, and the saturated water of high temperature was decompressed to generate steam. It was started at the initial temperature of $70^{\circ}C$, and it was confirmed that $120^{\circ}C$ steam was produced after the system stabilized. We have conducted experiments by modifying the system, and ultimately achieved a heating capacity of 101.4 kW and a COP of 3.05.

Property Changes of Gas Diffusion Layer in a PEFC by Compression (체결압이 고분자연료전지 가스확산층에 미치는 영향)

  • Ahn, Eun-Jin;Yoon, Young-Gi;Park, Gu-Gon;Park, Jin-Soo;Lee, Won-Yong;Han, Hak-Soo;Kim, Chang-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.3
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    • pp.347-352
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    • 2006
  • 분자전해질연료전지 내의 다공성 기체확산층은 반응가스의 확산과 전자이동통로의 역할을 수행할 뿐만 아니라 전기화학반응에 의해 공기극에서 생성된 수분(기상 혹은 액상)을 반응면으로부터 분리판 채널 방향으로 이동시켜 배출시키는 중요한 역할을 한다. 따라서 물관리를 통한 성능향상을 위해서는 기체 확산층의 구조 및 재료특성에 대한 심도 릴은 연구가 필요하다. 실제 단위전지 체결시 기체확산층은 분리판의 리브(rib)에 의해 눌리게 되며, 그 부분의 기공 크기 분포의 변화를 야기한다. 또한 리브 전단부분에서 탄소 섬유가 손상을 입으며, 탄소 섬유를 감싸고 있는 PTFE coating이 벗겨지게 되어 표면화학적 특성이 달라진다. 본 연구에서는 단위전지 체결 시 분리판에 의해 눌리는 기체확산층의 기공 크기 분포 변화를 측정하였으며, 기공의 소수성에서 친수성으로의 변화를 알아보았다. Mercury 기공 측정기와 PMI 기공 측정기는 큰 기공 분포의 변화에, 질소의 흡/탈착을 이용한 BET 방식은 작은 크기의 기공 분포 변화 관찰에 사용되었다. 체결압에 의한 탄소섬유의 구조적 변화와 아울러 표면의 습윤 정도의 변화를 XPS와 물/알콜 Uptake를 이용해 알아보았다. 이 연구를 바탕으로 물관리를 통한 연료전지 성능 향상을 위한 최적 GDL 선정에 기반이 되는 자료를 도출하였다.

Volumetric Capacitance of In-Plane- and Out-of-Plane-Structured Multilayer Graphene Supercapacitors

  • Yoo, Jungjoon;Kim, Yongil;Lee, Chan-Woo;Yoon, Hana;Yoo, Seunghwan;Jeong, Hakgeun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.250-256
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    • 2017
  • A graphene electrode with a novel in-plane structure is proposed and successfully adopted for use in supercapacitor applications. The in-plane structure allows electrolyte ions to interact with all the graphene layers in the electrode, thereby maximizing the utilization of the electrochemical surface area. This novel structure contrasts with the conventional out-of-plane stacked structure of such supercapacitors. We herein compare the volumetric capacitances of in-plane- and out-of-plane-structured devices with reduced multi-layer graphene oxide films as electrodes. The in-plane-structured device exhibits a capacitance 2.5 times higher (i.e., $327F\;cm^{-3}$) than that of the out-of-plane-structured device, in addition to an energy density of $11.4mWh\;cm^{-3}$, which is higher than that of lithium-ion thin-film batteries and is the highest among in-plane-structured ultra-small graphene-based supercapacitors reported to date. Therefore, this study demonstrates the potential of in-plane-structured supercapacitors with high volumetric performances as ultra-small energy storage devices.

Electrical and Optical Properties with the Thickness of Cu(lnGa)$Se_2$ Absorber Layer (Cu(InGa)$Se_2$ 광흡수막의 두께에 따른 태양전지의 전기광학 특성)

  • Kim, S.K.;Lee, J.C.;Kang, K.H.;Yoon, K.H.;Park, I.J.;Song, J.;Han, S.O.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.108-111
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    • 2002
  • CIGS film has been fabricated on soda-lime glass, which is coated with Mo film. by multi-source evaporation process. The films has been prepared with thickness of 1.0 ${\mu}m$, 1.75${\mu}m$, 2.0${\mu}m$, 2.3${\mu}m$, and 3.0${\mu}m$. X-ray diffraction analysis with film thickness shows that CIGS films exhibit a strong (112) preferred orientation. Furthermore. CIGS films exhibited distinctly decreasing the full width of half-maximum and (112) preferred peak with film thickness. Also, The film's microstructure, such as the preferred orientation, the full width at half-maximum(FWHM), and the interplanar spacing were examined by X-ray diffraction. The preparation condition and the characteristics of the unit layers were as followings ; Mo back contact DC sputter, CIGS absorber layer : three-stage coevaporation, CdS buffer layer : chemical bath deposition, ZnO window layer : RF sputtering, $MgF_2$ antireflectance : E-gun evaporation

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