• Title/Summary/Keyword: K3

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Removal CO2 Using Na2CO3, K2CO3 and Li2CO3 Impregnated Activated Carbon -Characteristics of CO2 Adsorption in Fixed Bed Reactor- (Na2CO3, K2CO3 및 Li2CO3 첨착활성탄을 이용한CO2 제거 -고정층 반응기에서의 CO2 흡착특성-)

  • Choi, Won-Joon;Jung, Jong-Hyeon
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.240-246
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    • 2008
  • The purpose of this study was to gain basic information on the characteristics of $CO_2$ adsorption in relation to $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon in a Fixed Bed Reactor. From the results of this study the following conclusions were made: $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon had a longer breakthrough time and more enhanced adsorption capacity than activated carbon alone. When tested with isothermal adsorption and tested for $CO_2$ adsorption the amount of $CO_2$ adsorbed varied with temperature, $CO_2$ inlet concentration, gas flow rate, aspect ratio, etc. Based on the results, when Langmuir, Freundlich and Dubinin-Polanyi adsorption isotherms were used for linear regression of isothermal adsorption data, Langmuir adsorption isotherm was the most suitable. And, the optimum condition for $Na_2CO_3$ and $K_2CO_3$ impregnated activated carbon make-up was 1N and $Li_2CO_3$ was 0.1N. It could be concluded that adsorption capacity was decreased with adsorption temperature and increased gas concentration. When the aspect ratio (L/D) was varied 0.5, 1.0 and 2.0, the significant drop of adsorption amount was observed below 1.0 and breakthrough time was shortened with gas flow rate.

HDAC3 acts as a negative regulator of angiogenesis

  • Park, Deokbum;Park, Hyunmi;Kim, Youngmi;Kim, Hyuna;Jeoung, Dooil
    • BMB Reports
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    • v.47 no.4
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    • pp.227-232
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    • 2014
  • Histone deacetylase-3 (HDAC3) is involved in cellular proliferation, apoptosis and transcriptional repression. However, the role of HDAC3 in angiogenesis remains unknown. HDAC3 negatively regulated the expression of angiogenic factors, such as VEGF and plasminogen activator inhibitor-1 (PAI-1). HDAC3 showed binding to promoter sequences of PAI-1. HDAC3 activity was necessary for the expression regulation of PAI-1 by HDAC3. VEGF decreased the expression of HDAC3, and the down-regulation of HDAC3 enhanced endothelial cell tube formation. HDAC3 negatively regulated tumor-induced angiogenic potential. We show the novel role of HDAC3 as a negative regulator of angiogenesis.

Surface characteristics of ITO treated with $UV/O_3-O_3$ and OLED device properties ($UV/O_3$$O_3$로 처리된 ITO의 표면 특성과 OLED 소자 특성)

  • Kim, Il;You, D.H.;Park, G.B.;Yuk, J.H.;Park, J.K.;Jo, G.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1361-1362
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    • 2006
  • In this research We investigated the effect of UV/O3, $O_3$ treatments of Indium-tin oxide(ITO) surface on the performance of organic light emitting devices(OLEDs). The fundamental structure of OLEDs was ITO(anode) / TPD(Hole Transport Layer) / $Alq_3$ / Al(cathode). We performed UV/O3, $O_3$ treatments and found that both treatments enhanced the performance of OLEDs. Current-Voltage, Luminance-Voltage characteristics were measured at room temperature.

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Effect of Chemical Drying Agents on the Field Drying Rate of Alfalfa and Rye Hay (Alfalfa와 호밀에 있어서 속성 건초조제를 위한 건조제 처리효과)

  • Seo, Sung;Kim, Jong-Geun;Chung, Eui-Soo;Kang, Woo-Sung;Yang, Jong-Sung
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.2
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    • pp.89-94
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    • 1998
  • A field experiment was carried out to determine the effects of chemical drying agents at mowing on the field drying rate of alfalfa (cv. Vernal) and rye (cv. Koolgrazer) for hastening hay manuf8cture. In alfalfa; chemicals ($K_2CO_3$ 2% $K_2CO_3$ 3% $Na_2CO_3$ 2% $CaCO_3$, 2% $K_2CO_3$2% + $Na_2CO_3$, 1% only water spray and control) were treated at early bloom stage in 1995. Chemicals ($K_2CO_3$, 2%, $Na_2CO_3$, 2% $CaCO_3$, 2% and control) were applicated at different harvest stages (early heading, heading and bloom) in rye, 1996. The drying rate of alfalfa by $K_2CO_3$ treatment among chemicals was higher than control, and the duration of field dry was shortened by one day with $K_2CO_3$ application, but there was no difference in drying efficiency between $K_2CO_3$ 2% and $K_2CO_3$ 3%. In rye, however, no moisture reduction by chemicals was observed. The days required for field dry were 6, 4, and 3 days at warly heading heading and bloom stage respectively; regardless of chemical drying agents and conbol. The nutritive value of rye hay with chemicals at baling was very slightly higher than control, but there was no significant difference. Also, no difference of hay quality was found among drying agents. In conclusion, $K_2CO_3$can enhance the field drying rate of alfalfa hay, but the drying efficiency was not high, particularly in rye hay. Harvesting at early heading to heading stage was desirable for manufacture of high quality rye hay.

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Comparison of Naphthalene Degradation Efficiency and OH Radical Production by the Change of Frequency and Reaction Conditions of Ultrasound (초음파 주파수 및 반응조건 변화에 따른 나프탈렌 분해효율과 OH 라디칼의 발생량 비교)

  • Park, Jong-Sung;Park, So-Young;Oh, Je-Ill;Jeong, Sang-Jo;Lee, Min-Ju;Her, Nam-Guk
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.79-89
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    • 2009
  • Naphthalene is a volatile, hydrophobic, and possibly carcinogenic compound that is known to have a severe detrimental effect to aquatic ecosystem. Our research examined the effects of various operating conditions (temperature, pH, initial concentration, and frequency and type of ultrasound) on the sonochemical degradation of naphthalene and OH radical production. The MDL (Method detection limit) determined by LC/FLD (1200 series, Agilient) using C-18 reversed column is measured up to 0.01 ppm. Naphthalene vapor produced from ultrasound irradiation was detected under 0.05 ppm. Comparison of naphthalene sonodegradion efficiency tested under open and closed reactor cover fell within less than 1% of difference. Increasing the reaction temperature from $15^{\circ}C$ to $40^{\circ}C$ resulted in reduction of naphthalene degradation efficiency ($15^{\circ}C$: 95% ${\rightarrow}$ $40^{\circ}C$: 85%), and altering pH from 12 to 3 increased the effect (pH 12: 84% ${\rightarrow}$pH 3: 95.6%). Pseudo first-order constants ($k_1$) of sonodegradation of naphthalene decreased as initial concentration of naphthalene increased (2.5 ppm: $27.3{\times}10^{-3}\;min^{-3}\;{\rightarrow}$ 10 ppm : $19.3{\times}10^{-3}\;min^{-3}$). Degradation efficiency of 2.5 ppm of naphthalene subjected to 28 kHz of ultrasonic irradiation was found to be 1.46 times as much as when exposed under 132 kHz (132 kHz: 56%, 28 kHz: 82.7%). Additionally, its $k_1$ constant was increased by 2.3 times (132 kHz: $2.4{\times}10^{-3}\;min^{-1}$, 28 kHz: $5.0{\times}10^{-3}\;min^{-1}$). $H_2O_2$ concentration measured 10 minutes after the exposure to 132 kHz of ultrasound, when compared with the measurement under frequency of 28 kHz, was 7.2 times as much. The concentration measured after 90 minutes, however, showed the difference of only 10%. (concentration of $H_2O_2$ under 28 kHz being 1.1 times greater than that under 132 kHz.) The $H_2O_2$ concentration resulting from 2.5 ppm naphthalene after 90 minutes of sonication at 24 kHz and 132 kHz were lower by 0.05 and 0.1 ppm, respectively, than the concentration measured from the irradiated M.Q. water (no naphthalene added.) Degradation efficiency of horn type (24 kHz) and bath type (28 kHz) ultrasound was found to be 87% and 82.7%, respectively, and $k_1$ was calculated into $22.8{\times}10^{-3}\;min^{-1}$ and $18.7{\times}10^{-3}\;min^{-1}$ respectively. Using the multi- frequency and mixed type of ultrasound system (28 kHz bath type + 24 kHz horn type) simultaneously resulted in combined efficiency of 88.1%, while $H_2O_2$ concentration increased 3.5 times (28 kHz + 24 kHz: 2.37 ppm, 24 kHz: 0.7 ppm.) Therefore, the multi-frequency and mixed type of ultrasound system procedure might be most effectively used for removing the substances that are easily oxidized by the OH radical.

Involvement of Phosphatidylinositol 3-Kinase in the Insulin Signaling in Preimplantation Mouse Embryos (생쥐 착상전 배아의 인슐린 신호전달 과정에 Phosphatidylinositol 3-Kinase의 관련성)

  • Gye, Myung-Chan;Nah, Hee-Young;Kim, Moon-Kyoo
    • Development and Reproduction
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    • v.4 no.1
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    • pp.29-35
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    • 2000
  • A phosphatidylinositol 3-kinase (PI3K) is a upstream component of insulin signaling by which protein synthesis can be stimulated in many systems. To elucidate involvement of PI3K and its downstream mammalian target of rapamycin (mTOR) in the insulin signaling in pleimplantation mouse embryos, 8-cell embryos were cultured to blastocysts in the presence or absence of insulin and/or inhibitor drugs. The number of blastomeres per blastocyst, protein synthesis, and protein phosphorylation were examined. There was significant difference in embryonic development to blastocyst stage and hatching was potentiated by the insulin supplementation. The increase in the mean celt numbers per blastocyst was apparent in the insulin culture. Wortmannin, a PI3K inhibitor and rapamycin, an inhibitor of mTOR abolished the stimulatory effect of insulin on morphological development mitosis and protein synthesis. In autoradiography, phosphoproteins pp22 and pp30 which undergo phosphorylation in response to insulin were identified. Taken together, it can be suggested that PI3K and mTOR engaged in insulin signaling in the mouse embryo 8-cell onward and mediate embryotropic offset of insulin.

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Effect of Soaking in KNO3 or K3PO4 Solution and Sowing Date of Bulbils on the Seed Bulbs Production of Garlic (Allium sativum L.) (마늘주아(珠芽)에 대한 KNO3및 K3PO4 처리(處理)와 파종시기(播種時期)가 종구(種球) 생산(生産)에 미치는 영향(影響))

  • Cho, Yong-Cho;Jeong, Byoung-Ryong
    • Horticultural Science & Technology
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    • v.16 no.2
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    • pp.219-221
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    • 1998
  • This study was carried out to investigate seed bulbs production of 'Namdo' garlic (Allium sativum L.) by treating with 200 mM $K_3PO_4$ and 200 mM $KNO_3$ solution to bulbils. The growth characteristics of garlic plants derived from bulbils sown on 3 different dates were compared to those of plants derived from non-treated bulbils. Time required for 50% shoot emergence ($T_{50}$) was shortened as the sowing dates delayed. However, the final emergence rate was increased in the early sowing dates, and was high when treated with $K_3PO_4$ and sown on Oct. 10. The % clove differentiation of bulb was not significantly affected by sowing date and chemicals treatment of the bulbils. In all treatments, % clove differentiation was greater than 85%. The average bulb weight was increased with earlier sowing. Bulbils treated with $K_3PO_4$ and sown on Oct. 10 exhibited the best growth and yield. which was 27% higher compared to the non-treated bulbils.

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Lead-free BaTiO3-(Bi0.5K0.5)TiO3 PTCR Ceramics and Effects of Nb2O5 on Its PTCR Characteristics (무연 BaTiO3-(Bi0.5K0.5)TiO3 PTCR 세라믹과 PTCR 특성에 미치는 Nb2O5의 효과)

  • Jeong, Young-Hun;Park, Yong-Jun;Lee, Mi-Jae;Lee, Young-Jin;Paik, Jong-Hoo;Choi, Jin-Soo;Lee, Woo-Young
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.475-481
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    • 2008
  • Positive temperature coefficient of resistivity (PTCR) characteristics of (1-x)$BaTiO_3-x(Bi_{0.5}K_{0.5})TiO_3$ ceramics doped with $Nb_2O_5$ were investigated in order to develop the Pb-free PTC thermistor available at high temperatures of > $120^{\circ}C$. The PTCR characteristics appearing in the ($B_{i0.5}K_{i0.5})TiO_3$ (< 5 mol%) incorporated $BaTiO_3$ ceramics, which might be mainly due to $Bi^{+3}$ ions substituting for $Ba^{+2}$ sites. The 0.99$BaTiO_3-0.01(Bi_{0.5}K_{0.5})TiO_3$ ceramics showed good PTCR characteristics of a low resistivity at room temperature (${\rho}_r$) of $31{\Omega}{\cdot}cm$ a high ${\rho}_{max}/{\rho}_{min}$ ratio of $5.38{\times}10^3$, and a high resistivity temperature factor (${\alpha}$) of $17.8%/^{\circ}C$. The addition of $Nb_2O_5$ to 0.99$BaTiO_3-0.01(Bi_{0.5}K_{0.5})TiO_3$ ceramics further improved the PTCR characteristics. Especially, 0.025 mol% $Nb_2O_5$ doped 0.99$BaTiO_3-0.01(Bi_{0.5}K_{0.5})TiO_3$ ceramics exhibited a significantly increased ${\rho}_{max}/{\rho}_{min}$ ratio of $8.7{\times}10^3$ and a high ${\alpha}$ of $18.6%/^{\circ}C$, along with a high $T_c$ of $148^{\circ}C$ despite a slightly increased ${\rho}_r$ of $31{\Omega}{\cdot}cm$.

Influence of Activation of Mesoporous Carbon on Electrochemical Behaviors of Pt-Ru Nanoparticle Catalysts for PEMFCs (고분자 전해질 연료전지 백금-루테늄 나노입자 촉매의 전기화학적 거동에 대한 중형기공 탄소 지지체의 활성화 효과)

  • Kim, Byung-Ju;Park, Soo-Jin
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.35-39
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    • 2011
  • In this work, mesoporous carbons (CMK-3) were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in polymer electrolyte membrane fuel cells (PEMFCs). The CMK-3 were chemically activated to obtain high surface area and small pore diameter with different potassium hydroxide (KOH) amounts, i.e., 0, 1, 3, and 4 g as an activating agent. And then Pt-Ru was deposited onto activated CMK-3 (K-CMK-3) by a chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto K-CMK-3 were determined by surface area and pore size analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and inductive coupled plasma-mass spectrometry (ICP-MS). The electrochemical properties of Pt-Ru/K-CMK-3 catalysts were also analyzed by cyclic voltammetry (CV). From the results, the K3g-CMK-3 carbon supports activated with 3 g KOH showed the highest specific surface areas. In addition, the K3g-CMK-3 led to uniform dispersion of Pt-Ru onto K-CMK-3, resulted in the enhancement of elelctro-catalystic activity of Pt-Ru catalysts.