• Title/Summary/Keyword: K-PHI zeolite

Search Result 3, Processing Time 0.021 seconds

Fabrication of K-PHI Zeolite Coated Alumina Hollow Fiber Membrane and Study on Removal Characteristics of Metal Ions in Lignin Wastewater

  • Zhuang, XueLong;Shin, Min Chang;Jeong, Byeong Jun;Lee, Seung Hwan;Park, Jung Hoon
    • Korean Chemical Engineering Research
    • /
    • v.59 no.2
    • /
    • pp.174-179
    • /
    • 2021
  • Recently, hybrid coal research is underway to upgrade low-grade coal. The hybrid coal is made by mixing low-grade coal with bioliquids such as molasses, sugar cane, and lignin. In the case of lignin used here, a large amount of lignin is included in the wastewater of the papermaking process, and thus, research on hybrid coal production using the same is attracting attention. However, since a large amount of metal ions are contained in the lignin wastewater from the papermaking process, substances that corrode the generator are generated during combustion, and the amount of fly ash is increased. To solve this problem, it is essential to remove metal ions in the lignin wastewater. In this study, metal ions were removed by ion exchange with a alumina hollow fiber membrane coated with K-Phillipsite (K-PHI) zeolite. The alumina hollow fiber membrane used as the support was prepared by the nonsolvent induced phase separation (NIPS) method, and K-PHI seeds were prepared by hydrothermal synthesis. The prepared K-PHI seed was seeded on the surface of the support and coated by secondary growth hydrothermal synthesis. The characteristic of prepared coating membrane was analyzed by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDX), and the concentration of metal ions before and after ion exchange was measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The extraction amount of K+ is 86 mg/kg, and the extraction amount of Na+ is 54.9 mg/kg. Therefore, K-PHI zeolite membrane has the potential to remove potassium and sodium ions from the solution and can be used in acidic lignin wastewater.

Capacity and the moment-curvature relationship of high-strength concrete filled steel tube columns under eccentric loads

  • Lee, Seung-Jo
    • Steel and Composite Structures
    • /
    • v.7 no.2
    • /
    • pp.135-160
    • /
    • 2007
  • Recently, CFT column has been well-studied and reported on, because a CFT column has certain superior structural properties as well as good productivity, execution efficiency, and improved rigidity over existing columns. However, CFT column still has problems clearing the capacity evaluation between its steel tube member and high-strength concrete materials. Also, research on concrete has examined numerical values for high-strength concrete filled steel square tube columns (HCFT) to explain transformation performance (M-${\phi}$) when a short-column receives equal flexure-moment from axial stress. Moment-curvature formulas are proposed for HCFT columns based on analytic assumption described in this paper. This study investigated structural properties (capacity, curvature), through a series of experiments for HCFT with key parameters, such as strength of concrete mixed design (58.8 MPa), width-thickness ratio (D/t), buckling length to sectional width ratio (Lk/D) and concrete types (Zeolite, Fly-ash, Silica-fume) under eccentric loads. A comparative analysis executed for the AISC-LRFD, AIJ and Takanori Sato, etc. Design formulas to estimate the axial load (N)-moment (M)-curvature (${\phi}$) are proposed for HCFT columns based on tests results described in this paper.

Studies on Artificial Cultivation of Pleurotus eryngii (De Canolle ex Fries) Quel. (큰느타리(Pleurotus eryngii)의 인공재배에 관한 연구)

  • Lee, Dae-Jin;Kim, Kwang-Po;Lee, Byung-Eui
    • The Korean Journal of Mycology
    • /
    • v.31 no.3
    • /
    • pp.192-199
    • /
    • 2003
  • This study was carried out to investigate the artificial cultivation of Pleurotus eryngii on the optimal medium vessel, periods of cultivation and the optimal method of pinheading for both yield and quality of fruiting body were also performed. The optimal composition of sawdust medium in polypropylene(PP) bottle was combination of sawdust(70%) and corncob(30%) but increased amount of corncob delayed the period of mycelial growth. The mycelial growth and the yield of fruiting body in the medium with beat pulp were worse than that without beat pulp. The optimal composition of nutrients for both yield and quality of fruit body tuned out to be a combination of rice bran(12%), wheat bran(12%) and cottonseed cake(6%). Additions of zeolite, shell lime and bean curd dregs were not effective in mycelial growth and yield of fruit body. When testing size of PP bottle for cultivation, the larger of bottle mouth is, the more pinheading number found, but the number of available fruit body is not significantly different. The culture in $1100\;ml-{\phi}75\;mm$ bottle is the best in the yield and quality of fruit body than those in $555\;ml-{\phi}50\;mm,\;850\;ml-{\phi}58\;mm,\;850\;ml-{\phi}65\;mm\;and\;1100\;ml-{\phi}65\;mm$ bottle. Using the PP bag for cultivation, a square shaped bag was better than a round shaped and black square shaped in mycelial growth and yield of fruit body. The most suitable period of incubation was 35 days after inoculation at $22{\pm}2^{\circ}C$. When the incubation periods was decreased less than 35 days, the pileus formation and yields were very bad but a pinheading condition looked similar, For an optimal pinheading, turning upside down was better than standing and covering.