• Title/Summary/Keyword: Irradiation time

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Relationship between Oxidation and Wear of Ultra-High Molecular Weight Polyethylene for Total Joint Arthroplasty

  • Lee, Kwon-Yong
    • KSTLE International Journal
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    • v.2 no.1
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    • pp.55-58
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    • 2001
  • The most widely-used orthopaedic grade polymer bearing liner material, ultrahigh molecular weight polyethylene (UHMWPE), for the total joint arthroplasty degrades after gamma-irradiation sterilization through the progressive oxidation in a shelf and in vivo. Oxidative degradation makes UHMWPE brittle and leads to decrease in mechanical properties. In this study the relationship between post-gamma-irradiation aging time and wear of UHMWPE was investigated. Six retrieved polyethylene hip liners implanted for 3-16 years and then stored in air for 1.5-6.5 years until tests were used. Two types of pin-on-disk wear testing were conducted by the uni-directional repeat pass rotating and by the linear reciprocating stainless steel disks against stationary polyethylene pins under 4Mpa at 1Hz with bovine serum lubrication in ambient environment. Wear of retrieved polyethylene hip liners does not have direct correlation with in vivo or total aging time. Linear reciprocal sliding motion generated more remarkable wear than uni-directional repeat pass sliding motion. It indicates that kinematic motion affects very crucially on the wear of aged UHMWPE having brittle white band region.

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Photooxidation of BR Vulcanizate Using High Pressure Mercury Lamp

  • Kim, Eunha;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.50 no.1
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    • pp.1-6
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    • 2015
  • Polybutadiene rubber (BR) has been well known that its physical and chemical properties are changed when it is exposed to ultraviolet light undergoing photooxidation. In this study, photooxdiation process of BR vulcanizate was investigated using a high pressure mercury lamp used as an outdoor lighting, which has high UV radiation efficiency and reasonable cost. Discoloration and crack formation of photooxdized BR vulcanite surface were examined using an image analyzer. Change of chemical functional groups of BR vulcanite surface by photooxidation was investigated using ATR-FTIR, and variation of the crosslink density with the UV irradiation time was investigated. By increasing the UV irradiation time, the crosslink density steeply increased after a period of time and did not increase any more. Formation of hydroxyl (~OH) and carbonyl (~C=O) groups on the BR vulcanizate surface increased and the1,4-cis unit was converted to the 1,4-trans unit as the photooxidation was proceeded.

Physicochemical Changes in UV-Exposed Low-Density Polyethylene Films

  • Salem, M.A.;Farouk, H.;Kashif, I.
    • Macromolecular Research
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    • v.10 no.3
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    • pp.168-173
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    • 2002
  • Unstabilized low-density polyethylene (LDPE) films and films formulated with hindered amine light stabilizer (HALS) were exposed to UV-radiation; and the physicochemical changes during photooxidation processes have been investigated using tensile, FTIR spectre-photometric and thermal analytical (DSC) techniques. The dependence of tensile properties (elongation- and stress-at-break), carboxyl index and heat of fusion on UV-irradiation time have been discussed. The use of HALS is found to be effective in maintaining the UV-mechanical properties of the LDPE films. The experimental results showed that there exists no correlation between mechanical properties and carbonyl index, whereas crystallinity correlates well with carbonyl index in unstabilized and stabilized films for irradiation times greater than 100 h. The rate of formation of carbonyl groups is found to be dependent on UV exposure time. Crystallinity of the film samples is strongly influenced by both exposure time and presence of HALS.

A Study on the UV Degradation characteristics of FRP by Plasma Surface Modification (플라즈마 표면개질에 따른 FRP의 자외선 열화 특성에 관한 연구)

  • Lim, K.B.;Lee, S.H.;You, D.H.;Hwang, M.W.;Lim, E.C.;Cho, G.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1544-1546
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    • 2003
  • In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system Pressure, 100 W of discharge power, and 3 minutes of discharge time. The decrease in surface potential of charged samples by corona discharge indicates that the amount of accumulated electrical charges reduces and the charges that have been injected lessen rapidly when the duration of UV irradiation increases. The surface resistivity and the tensile strength of plasma treated samples, a longer UV irradiation time resulted in decreased insulation.

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Liquid crystal alignment by photo-dimerization reaction of PCEMA photo polymer (PCEMA 광폴리머의 광중합 작용을 이용한 액정배향)

  • 황정연;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.541-544
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    • 1999
  • We synthesised a novel photo-alignment material of PCEMA (poly(cinnamolyethyl methacrylate)) on photo-dimerization reaction. Next we investigated the electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PCEHA surface. The excellent voltage-transmittance characteristics of photo-aligned TN-LCD on PCEMA surface were obtained. The threshold voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on PCEMA surface. Also, the response time of photo-aligned TN-LCD on PCEMA surface is almost the same as rubbing-aligned TN-LCD.

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Treatment Planning Software for High Dose Rate Remote Afterloading Brachytherapy of Uterine Cervical Cancer (Personal computer를 이용한 자궁경부암의 고선량을 강내치료 계획)

  • Huh, Seung-Jae;Kang, Wee-Saing
    • Radiation Oncology Journal
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    • v.4 no.2
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    • pp.183-186
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    • 1986
  • In brachytherapy of uterine cervical cancer using the high dose rate remote afterloading system, it is of prime importance to determine the position of the radiation sources and to estimate the irradiation time. However, calculation with manual method is so time consuming and laborious, that authors designed a software as an aid to intracavitary radiotherapy Planning using the personal computer to obtain the precision of treatment without being too complicated for routine use. Optimal source arrangement in combination with dose rate at each specific points and irradiation time can be easily determined using this software in several minutes.

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Optimum Blind Control at the End of Operation Time Zone for Preventing Glare on Work-plane and Maximizing Daylight and Solar Heat Gain (작업면 현휘 방지와 주광 및 일사 유입 최대화를 위한 제어 종료 영역에서의 최적 블라인드 제어)

  • Seong, Yoon-Bok;Yeo, Myoung-Souk;Koo, So-Young;Kim, Kwang-Woo
    • Journal of the Korean housing association
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    • v.23 no.1
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    • pp.27-41
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    • 2012
  • The objective of this study is to develop the blind control strategy and method which reduce negative effect of incoming daylight on visual comfort of occupants, minimize psychological anxieties caused by frequent motions of a blind, and maximize positive effect of incoming daylight and solar irradiation by opening/closing of a blind. As previous researches on blind controls have limited outdoor environmental conditions to those in specific regions, orientations and dates, these resulted in problems at various conditions for general-purpose application. Major problem is that the time interval and amount of blind movement do not meet the control objective at the end of control zone and discontinuous curve. To overcome these limitations revealed in the previous researches, following tasks were performed in this study. 1) To establish the control objective to accomplish the goal of this study. 2) To develop the control methods and algorithms which prevent glare on the work-plane at any time and which control the time interval and amount of blind movement to follow the control objective at various profile angle curves. 3) To validate the general-purpose applicability and performance of the developed control methods and algorithms by simulation and its data analysis at various conditions. It was found that the proposed methods and algorithms can prevent the direct glare on the work-plane at all the time and also increase the incoming daylight and solar irradiation.

Optimum Treatment Parameters for Photodynamic Antimicrobial Chemotherapy on Streptococcus mutans Biofilms (Streptococcus mutans biofilm에 대한 광역동 치료의 최적조건에 관한 연구)

  • Choi, Seojung;Park, Howon;Lee, Juhyun;Seo, Hyunwoo;Lee, Siyoung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.42 no.2
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    • pp.151-157
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    • 2015
  • The purpose of this study was to evaluate the effects of Photochemotherapy using a combination of erythrosine and standard halogen dental curing lights on the viability of Streptococcus mutans in the biofilm phase. To investigate the optimum treatment parameters, the researchers controlled the concentration of erythrosine, light irradiation time and the treatment time of erythrosine. The higher concentration of erythrosine (0, 10, 20, 40, 80 M) in the presence of light irradiation created greater effects in reducing the viability of S. mutans. The results showed a statistically significant difference among the antimicrobial effects in 20, 40, 80 M erythrosine. The higher irradiation time of light (0, 5, 15, 30, 60, 75s) in the presence of erythrosine showed greater effects in reducing the viability of S. mutans. There was statistically significant difference in 30, 60, 75 seconds. The higher treatment time of erythrosine (0, 1, 2.5, 5min) in the presence of erythrosine created greater effects on reduction of S. mutans viability. Statistically significant differences were found between 2.5 and 5 minutes of erythrosine treatment time. The results of this study showed that the photochemotherapy on S. mutans using erythrosine and the halogen dental curing lights conventionally used in dental clinics is effective in the condition of 20-40 M erythrosine concentration, irradiation time over 30 seconds, and erythrosine treatment time over 2.5 minutes.

Effects of Ultrasonic Energy on Mn-Zn Ferrite Powder Behavior (초음파 에너지가 mn-Zn Ferrite 분체에 미치는 영향)

  • 이경직;이대희;이석기;이병교
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.751-755
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    • 1999
  • Effect of ultrasonic-wave irradiation on the Mn-Zn ferrite powder suspension prepared by solid-state reaction and alcoholic dehydration methods was investigated. Size distribution and morphology of the powders prepared at different temperature were examined as a function of irradiation time. It was observed that the powders were reduced in size by ultrasonic energy through distinct routes.

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Blue-Light Dependent Chloroplast Rearrangement In Panax ginseng C.A. Meyer (인삼의 청색광의존성 엽록체재배치(Chloroplast rearrangement))

  • 양덕조;김명원
    • Journal of Ginseng Research
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    • v.17 no.3
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    • pp.236-239
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    • 1993
  • We studied the chloroplast rearrangement, short-term regulation depending on the light conditions in plants, and the characteristic of photosynthic rate as affected by in Panax ginseng C.A. Meyer. The chloroplast rearrangement of ginseng mesophyll cell was induced with the irradiation of blue light (400~500 nm) and through this process the rate of leaf transmittance increased 5~7.5%. The time to reach the maximum value of photosynthesis was shorter above 20 minutes with the blue light irradiation than that of the red light.

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