• Korean Journal of Heritage: History & Science
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• v.53 no.1
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• pp.168-183
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• 2020

Efforts had been made to eliminate the brittleness unique to cast ironware from 5 BC up until the time that cast ironware became widely used. One of the techniques used to this end was to produce the cast ironware in one kiln and then anneal it in another kiln. This technique condensed or removed the carbon in the structure to eliminate the brittleness of cast ironware and enable forging. To clarify the nature of this technique, this study examined cast ironware made of malleable cast iron, which manifests the characteristics of the annealing technique for cast ironware excavated on the Korean peninsula, based on current steelmaking technology and research results from China and Japan. Results confirmed that all cast ironware made of malleable cast iron had been imported into Korea until the Proto-Three Kingdoms Period. Also, since the Chiljido (Seven-Branched Sword), which is housed at the Ishigami Shrine in Japan, appears to have been produced in the Korean peninsula, it is determined that Baekje in the 4^th century must have possessed such an annealing technique. At that time, however, iron was produced mainly with an iron bloom, and a large amount of forged iron was produced with a steel bloom smelted from an iron bloom. In addition, most of the cast ironware that was used previously, except for cast iron hoes, had been replaced by forged ironware. In other words, this annealing technique was not used frequently until the Three Kingdoms Period. However, it spread broadly during the Unified Silla Period in so much as it was identified in the Jangan-ri remains, which represented the regional hub of iron production and distribution.

• Korean Journal of Heritage: History & Science
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• v.35
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• pp.138-158
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• 2002

To compare and analyze technical system related to manufacturing of ironware during the period of the Three Kingdoms, an analysis was conducted on the minute system of metalwork, as study objects, of the remains of the Mt. Wolpyeong fortress wall in Daejeon in the period of capital during the era of the Three Kingdoms in the 5th century, the Sanwol-ri remains in the 6th century in Gunsan and the remains of ironware excavated from the great ancient tomb of Hwangnam of the Silla dynasty in the 5th century. The result of analysis shows that in the most of the casting products, the minute system of white cast iron were contained. While the iron part of decarbonization was in the system by casting as white cast iron in the central part, on the surface layer it was turned out that comparatively uniform 100% pearlite system of about 1~2mm degree was existing. The part of pearlite on the surface layer was caused by decarbonization, which appears in all the parts of blade front end and handle. Therefore, it was found that the iron part of decarbonization was manufactured by casting, and then was processed at the high temperature by decarbonization. For the products of forging, after processing the products on the basis of pure iron for materials, they manufactured the ironware that raises the strength by carbonizing that keeps carbon infiltrated on the necessary part, by the method of black smith welding that add pure iron to steel, or by varying the method of heat processing onto the part required of strength. Though limited, we could understand that the technical systems for manufacturing skill of ironware in the areas of Baekje and Silla were different each other. In the technical system for Hwangnam great ancient tomb in the Silla area, it is found that they had raised the strength on the necessary part by applying the steelmaking method of carbonizing in the last stage of production of products, in the meantime in Baekje area, it appears that they had produced steel in advance in the first stage of production of the products, and used the produced steel only to the necessary part.

• Journal of Conservation Science
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• v.28 no.4
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• pp.367-376
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• 2012

The ironware production technology is a measure to fathom the society's level of development in time. To understand iron-manufacure methods in the past, various investigations on the fine structures and additions of ironware remains and Iron ingot have been conducted in a way of natural science. This study metallurgically reclassifies remains excavated in iron-manufacture remains located in Beokje, Goyang, which are thought to be in time of Goryeo Dynasty, and draws an inference from the element analysis on the iron-manufacture and smelting technology. Iron ingot samples with a cast iron structure are divided into those with a white cast iron structure and those with a grey cast iron rich in P. The P content of grey cast iron appeared to be the result of adding a flux agent like lime, iron ingot and carbon steel iron ingot with a cast iron structure excavated in the area is regarded as pig iron which was made without a refining process. In this study it seems that two methods of making ironware were used in the area; one is the method of making ironware by pouring cast iron to the casting, and the other is the method of making carbon steel through the refinement of pig iron. It appears that highly even steel structure of carbon steel and a small amount of MnS inclusion are very similar with that of the modern steel to which Mn is artificially added. Nevertheless, these data alone cannot be used to determine the source of Mn in the carbon steel of the excavated from the iron-manufacture remains, which raises the need for further studies on the source and the possibility of carbon steel via the iron-manufacture process of cast iron.

• Korean Journal of Heritage: History & Science
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• v.33
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• pp.36-67
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• 2000

Square-shaped moated burial precincts(方形周溝墓) can be classified into type I that has bridges only at the comers, type II that has bridges at the comers and sides, type III that has bridges only at the sides, type IV that is surrounded by the moat without bridges, type V that has its sides less than those of type I ~ V by 1 or 2, and type VI that has the round-shaped ground. But the time differences among the types are not known yet. For the burial appliances of square-shaped moated burial precincts, there are stone coffins, pit burials and jar burials. The major burial appliances situated in the mound are stone coffins and pit burials, and jar burials are subsidiary appliances that were buried at the shoulder part of the mound or at precincts. According to the case of Gwanchang-ri KM423, grave mounds, which arc closely related with the burial appliances, were built by heaping up the earth in and around the precinct as low as only enough to protect the burial appliances. Considering the relics unearthed in the burial compartment of KM437, the time when square-shaped moated burial precincts were formed is estimated to be the age when Songguk-ri type earthenware and clay stripes earthenware co-existed. It was the early Iron Age when ironware began to sp read in this country. Emerging first in that age, square-shaped moated burial precincts were presumably formed until around the end of BC or the beginning of AD, when KM404 and KM423, which were unearthed with plain earthenware, grey earthenware and ironware, were formed. When analyzing the form of small-sized graveyards in precincts, the unearthed relics and the locations, the people who formed square-shaped moated burial precincts were considered as those who had a culture comprising clay stripes earthenware, which appears newly in the Songguk-ri type earthenware of native, and ironware, and a settled agricultural society based on paddy fields and labor forces of family units.

• Journal of Conservation Science
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• v.30 no.4
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• pp.335-343
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• 2014

This study classified the result of non-metallic inclusion analysis and result of microstructure investigation on the ironware excavated in the Baekje region into Han River, Geum River, and Yeongsan River to estimate the iron making temperature and study the characteristics of regional and temporal characteristics of the heat treatment technology and steel making technology. Regardless of era, bloom iron and sponge iron are judged to be the major method for making as a directreduction process in all three regions. The result of the reinterpretation of the non-metallic inclusion by the oxide ternary constitutional diagram suggest that the temperature inside of the furnace is estimated to be between $1,100{\sim}1,300^{\circ}C$ while making the steel. The magnetic iron ores are the major raw material of steel ore and irons with high $TiO_2$ are estimated to use iron sands. Ironware with $CaO/SiO_2$ rate higher than 0.4% are considered to have artificially added the flux of calcareous materials. It was found that the iron making method is the solid caburizing-steel which caburizes low-carbon steels by the CO gas and $CO_2$ gas created when heating the forging furnace with charcoal. Also, the ironware manufacturers in the Baekje during 3rd century recognized the heat treatment technology as they performed carburizing process and quenching to intentionally increase the strength of necessary parts.

• Korean Journal of Heritage: History & Science
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• v.43 no.3
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• pp.48-101
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• 2010

This paper estimated the calendar date of pottery with ring-rim(粘土帶土器) with the radiocarbon dating. This was based on archaeological facts with comparing line relations and radiocarbon dates of Yayoi pottery(彌生土器). As a result, I understood that pottery with circle ring-rim(圓形粘土帶土器) appeared in BC 6c, pottery with triangle ringrim(三角形粘土帶土器) appeared at the time in BC 300 . Based on the calendar date and aspect of ironware and pottery in grave, I kept in BC 4c with appearance date of ironware. And I kept in BC 5c with appearance date of the slim bronze dagger culture. Korea and Japan common chronological order were built for the first time based on radiocarbon dates, line relations of pottery with ring-rim and Yayoi pottery. This is the calendar date to date back approximately 100~300 years from the existing the calendar date. Current periodization does not match in the calendar date when I built it newly. Therefore I suggested it as follows. Early iron age is from the first~middle part BC 4c to BC 100. And the latter half of Bronze age is from BC 6c to the front appearance of ironware. Then Songguk-ri type(松菊里式) becomes staudard type of pottery in the middle stage of Bronze age.

• 보존과학연구
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• s.7
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• pp.292-303
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• 1986

The purpose of this paper is to select the suitable resin as changed in environmental and ingredients, in the conservation of metallic objects. Disposal way of metallic objects were used to various resin and grease which will must be well selected in the nature of relics. The contents of this report are summed up as follows ; The resins of Incralac, Ruscoat, wash primer, Amerlock-400 wrer coated on the slice of ironware (5% saltspray test on the view of nature & Adherence). After the coating, add increasing speed to a corrosion rate, and then the adherence of resins were tested. In this study corrosion test, 0.10-0.25% Amerlock-400 jis proved to be a rare one of corrosion rate and 1.0-2.5% Wash primer is found to be a plenty one of corrosion area.

• 보존과학연구
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• s.29
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• pp.91-110
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• 2008

The museum of Chonnam National University unearthed and researched an Andong tumulus located in Gildu-ri, Podumyeon, Goheung, Jeonnam in March 2006, and many remains were excavated from the tomb. The Conservation Science division of the National Research Institute Cultural Heritage was asked to deal with about 100 pieces of relics with gilt bronze, including a Gilt-Bronze Cap, and ironware remains from the excavated site for the museum of Chonnam National University and urgently dealt with the excavated site for 4 days from March 27 to March 30, 2006. All of the remains were dealt with and cleaned up in this way, were moved to the National Research Institute Cultural Heritage, and have been under a conservation treatment until now. In this study, excavated conditions, the handling of the excavated site, the conservation treatment process until now, and the forthcoming conservation treatment plans will be examined specifically focusing on the Gilt-Bronze Cap with gilt bronze among many other remains.

• Bangmulgwan gwa yeongu (The National Museum of Korea Journal)
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• v.1
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• pp.150-173
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• 2024

The Gyeongsang region experienced an epoch-making social transformation approximately around the second to first century BCE, including the replacement of Bronze Age types of tombs (such as dolmens, stone cist tombs, and earthen tombs with flat capstones) with clusters of wooden coffin tombs and the emergence of wajil pottery (soft stoneware) and ironware. These shifts in the archaeological material evidence have been discussed in the context of the formation of the states that comprised the three Han confederacies and in relation to wooden coffin tombs built in later periods. This paper explicates the appearance of clustered wooden coffin tombs with accompanying ironware by categorizing them. In particular, it examines the emergence of wooden coffin tombs by creating the Wolseong-dong type, which differs from Tomb No. 5 in Joyang-dong and Tomb No. 1 in Daho-ri with their deep burial pits and large quantities of prestige goods and soft stoneware items. The Wolseong-dong type of tomb commonly features ironware, including flat-bladed iron axes, oblong cast iron axes, iron wire, iron chisels, and iron swords; a small slender, rectangular wooden coffin tomb with a shallow burial pit of less than sixty centimeters; and pottery of a type preceding soft stoneware, such as long-necked jars, triangular attached-rim pottery bowls and pots, and mounted vessels. There are also a few bronzeware items found in them, but no prestige goods. This study scrutinizes tombs in Tamni-ri in Uiseong, Hagu-ri in Gyeongju, and Hakjeongdong in Daegu by comparing them with the Wolseong-dong type, and it confirms that in Sinseodong in Daegu, Wolseong-dong type tombs and later Joyang-dong type tombs have separate spatial distributions within the site. This also indicates that the Wolseong-dong type is a valid categorization among wooden coffin tombs. Although the rise of the Wolseong-dong type tomb is associated with the migration of a group, I reserve judgement on whether its origins should be understood in the context of the iron culture in the southwestern region of South Korea that was sparked by King Jun's advance to the south or if they lie in the western region of North Korea. Either way, the Wolseong-dong type is thought to be the tombs of a group of people with lower hierarchical status than the occupants of the later Joyang-dong type.

• Korean Journal of Heritage: History & Science
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• v.50 no.1
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• pp.4-17
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• 2017

In this research, the chemical composition of the iron artifacts from the late 6th-century to early 7thcentury Baekje remains in Gwanbuk-ri, Buyeo, specifically of the nine iron artifacts including slags, furnace walls and ingot iron excavated in the District "Na", were examined by observing their chemical compounds and microstructures. As a result, GB1 and GB6 were determined to be proto-reduction lumps whereas GB2, GB3, GB4 and GB5 were determined to be tempered slags, respectively. Also, he furnace wall GB7 were containing mullite and cristobalite, which are high temperature index minerals, The extrusion temperature was found out to be about $1200{\sim}1300^{\circ}C$, and it is most likely that the smelting temperature in the furnace was in that temperature range. GB8 ingot iron was determined to be a forged ironware. This ingot iron was an intermediary product for making ironware and its nonmetallic inclusions displayed similar microstructure and contents compared to the forged iron. Because of the existence of proto-reduction lumps and forged iron, the iron making facility located in District "Na" most likely had a small-scale iron making facility that handled iron bloom smelting and refining processes.