• Journal of Industrial Technology
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• v.17
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• pp.169-174
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• 1997

This investigation was carried out to study on the generation property, management and seperate collection rate of solid waste in the Gu-Gok Falls. Generation rate of solid waste was 80.785kg/day and unit waste generation rates was $65.55g/day{\cdot}tourist$ one person. Physical component of solid waste were garbage 46%, papers 20%, empty bottles 10%, respectively. A plan is required to decrease generation rate of garbage waste. As result to investigate separated garbage can, papers and can were separated more than 60%. But empty bottles and scrap iron were separated less than 50%. P.E.T, steel can, aluminum can and empty bottles were 20% of total generation rate, and profit of reuse is \700,800/year.

• Journal of Powder Materials
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• v.20 no.1
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• pp.48-52
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• 2013

A study of oxidation kinetic of Fe-36Ni alloy has been investigated using thermogravimetric apparatus (TGA) in an attempt to define the basic mechanism over a range of temperature of 400 to $1000^{\circ}C$ and finally to fabricate its powder. The oxidation rate was increased with increasing temperature and oxidation behavior of the alloy followed a parabolic rate law at elevated temperature. Temperature dependence of the reaction rate was determined with Arrhenius-type equation and activation energy was calculated to be 106.49 kJ/mol. Based on the kinetic data and micro-structure examination, oxidation mechanism was revealed that iron ions and electrons might migrate outward along grain boundaries and oxygen anion diffused inward through a spinel structure, $(Ni,Fe)_3O_4$.

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.505-510
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• 2012

A study of the recovery of tin and nickel from steel ball scraps for barrel plating was carried out through a physical treatment, a leaching treatment, hydrogen reduction and an electrolysis experiment. The recovery of the iron component was over 95% by the physical treatment. We obtained tin oxide in the form of metastannic acid ($SnO_2{\cdot}xH_2O$) with impurities of less than 5% from the leaching treatment. We also recovered the high-purity metallurgical tin at a rate that exceeded 99.9% by the electrolysis of crude tin obtained from the hydrogen reduction of metastannic acid.

• Resources Recycling
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• v.20 no.4
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• pp.46-51
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• 2011

A study on the recovery of tin from the steel ball scraps for barrel plating has been carried out the physical treatment and leaching experiment. The recovery of iron component was over 95% by the physical treatment, and the recovery of tin component was also over 95% by the hydro process.

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.15-21
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• 2012

MTBE (Methyl tertiary-butyl ether) has been commonly used as an octane enhancer to replace tetraethyl lead in gasoline, because MTBE increases the efficiency of combustion and decreases the emission of carbon monoxide. However, MTBE has been found in groundwater from the fuel spills and leaks in the UST (Underground Storage Tank). Fenton's oxidation, an advanced oxidation catalyzed with ferrous iron, is successful in removing MTBE in groundwater. However, Fenton's oxidation requires the continuous addition of dissolved $Fe^{2+}$. Zero-valent iron is available as a source of catalytic ferrous iron of MFO (Modified Fenton's Oxidation) and has been studied for use in PRBs (Permeable Reactive Barriers) as a reactive material. Therefore, this study investigated the condition of optimization in MFO-PRBs using waste zero-valent iron (ZVI) with the waste steel scrap to treat MTBE contaminated groundwater. Batch tests were examined to find optimal molar ratio of MTBE : $H_2O_2$ on extent to degradation of MTBE in groundwater at pH 7 with 10% waste ZVI. As the results, the ratio of optimization of MTBE to hydrogen peroxide for MFO was determined to be 1:300[mM]. The column experiment was conducted to know applicability of MFO-PRBs for MTBE remediation in groundwater. As the results of column test, MTBE was removed 87% of the initial concentration during 120days of operational period. Interestingly, MTBE was degraded not only within waste ZVI column but also within sand column. It means the aquifer may affect continuously the MTBE contaminated groundwater after throughout the waste ZVI barrier. The residual products showed acetone, TBF (Tert-butyl formate) and TBA (Tert-butyl acetate) during this test. The results of the present study showed that the recycled materials can be effectively used for not only a source of catalytic ferrous iron but also a reactive material of the MFO-PRBs to remove MTBE in groundwater.

• Resources Recycling
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• v.28 no.5
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• pp.30-41
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• 2019

Global production of zinc is about 13 million tons and zinc is the fourth-most widely used primary metal in the world following iron, aluminum and copper. When zinc is recycled to produce secondary zinc, it can save about 75 % of the total energy that is needed to produce the primary zinc from ore, and in therms of $CO_2$ emissions reduced by about 40 %. However, since zinc is mainly used for galvanizing of steel, the recycling rate of zinc is about 25 %, which is lower than other metals. The raw materials for recycling of zinc include dusts generated in the production of steel and brass, sludge in the production process of non-ferrous metals, dross in the melting of zinc ingots or hot dip galvanizing, waste batteries, and metallic scrap. Among them, steelmaking dust and waste batteries are most actively recycled up to now. Most of the recycling process uses pyrometallurgical methods. Recently, however, much attention has been given to a combined process of pyrometallurgical and hydrometallurgical processes.

• Resources Recycling
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• v.32 no.1
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• pp.50-59
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• 2023

The amount of dust generated during the dissolution of scrap in an electric arc furnace is approximately 1.5% of the scrap metal input, and it is primarily collected in a bag filter. Electric arc furnace dust primarily consists of zinc and ion. The processing of zinc starts with its conversion into pellet form by the addition of a carbon-based reducing agent(coke, anthracite) and limestone (C/S control). These pellets then undergo reduction, volatilization, and re-oxidation in rotary kiln or RHF reactor to recover crude zinc oxide (60%w/w). Next, iron is discharged from the electric arc furnace dust as a solid called Fe clinker (secondary by-product of the Fe-base). Several methods are then used to treat the Fe clinker, which vary depending on the country, including landfilling and recycling (e.g., subbase course material, aggregate for concrete, Fe-source for cement manufacturing). However, landfilling has several drawbacks, including environmental pollution due to leaching, high landfill costs, and wastage of iron resources. To improve Fe recovery in the clinker, we pulverized it into optimal -sized particles and employed specific gravity and magnetic force selection methods to isolate this metal. A carbon-based reducing agent and a binding material were added to the separated coarse powder (>10㎛) to prepare briquette clinker. A small amount (1-3%w/w) of the briquette clinker was charged with the scrap in an electric arc furnace to evaluate its feasibility as an additives (carbonaceous material, heat-generating material, and Fe source).

• Geotechnical Engineering
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• v.12 no.3
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• pp.17-34
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• 1996

The objective of this paper is to evaluate the asphalt mixture performance with pyrolyzed carbon black(CBP) and air -cooled iron blast furnace slag. Marshall mix design was performed to determine the optimum binder content, The optimum binder content ranged from 6.3 percent to 7.75 percent. Dynamic creep testing was carried out using mixtures at the optimum binder content. Based on the test results, the use of pyrolyzed carbon black and slag in the asphalt pavement showed a positive result, such as the increase of Marshall stability, the decrease of the strain rate and the decrease in the mix stiffness rate at high temperature(5$0^{\circ}C$) and 137.9 kPa confinement. Within the limits of this research. it was concluded that pyrolyzed carbon black as an additive and slag as a coarse aggregate could be used to produce an asphalt paving mixture that has good stability, stiffness, and rutting resistance.

• Resources Recycling
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• v.15 no.6 s.74
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• pp.3-9
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• 2006

In this study, a machine vision system using a color recognition method has been designed and developed to automatically sort out specified materials from a mixture, especially Cu and other non-ferrous metal scraps from a mixture of iron scraps. The system consists of a CCD camera, light sources, a frame grabber, conveying devices and an air-nozzle ejector, and is program-controlled by a image processing algorithms. The ejectors designed to be operated by an I/O interface communication with a hardware controller. In the functional tests of the system, its efficiency in the separation of Cu scraps from its mixture with Fe ones reaches to 90% or more at a conveying speed of 15m/min, and thus the system is proven to be excellent in terms of the separating efficiency. Therefore, it is expected that the system can be commercialized in the industry of shredder makers if an automated sorting system of high speed is realized.

• Journal of the Korean Geographical Society
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• v.39 no.1
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• pp.88-101
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• 2004

This paper aims to examin the channel of waste collection, as well as to clarify the relationship between collection types and regional characteristics. According to the analysis results, a kind of used paper and old metal are mainly collected in regions which have a large population size, high population increasing rates, high population composition rates of secondary industry and high degree of self-supporting in public finance. On the other hand, in regions which have a small population size, low population increasing rates or a decrease in population, and high population composition rates of primary industry and rates of agricultural household, there are high collection rates for others recyclable wastes, a kind of scrap iron, used paper, and used bottle. These results show that the collection types of recyclable domestic wastes are different depend on industry developed degree in region.