• Title/Summary/Keyword: Iron filings

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Hybrid Barriers of Iron and Modified-bentonite for the Remediation of Multi-contaminated Water (복합오염물질 제거를 위한 철과 개량 벤토나이트의 복합층에 관한 연구)

  • Cho, Hyun-Hee;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.512-519
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    • 2004
  • Hybrid barriers using reduction and immobilization were tested to remediate the groundwater contaminated with multi-pollutants in this study. Iron filings and HDTMA(hexadecyltrimethylammonium)-bentonite were simulated in columns to assess the performance of hybrid barriers for remediation of trichloroethylene(TCE)-contaminated water. TCE reduction rate for the mixture of iron filings and HDTMA-bentonite was about 7 times higher than that for iron filings, only suggesting the reduction of TCE was accelerated when HDTMA-bentonite was mixed with iron filings. TCE reduction rate for the two layers of iron and HDTMA-bentonite was nearly similar to that for iron filings alone, but the partition coefficient($K_d$) for the two layers was 4.5 times higher than for that iron filings only. TCE was immobilized in the first layer with HDTMA-bentonite, and then dechlorinated in the second layer with iron filings. HDTMA-bentonite may contribute to the increase in TCE concentration on iron surface so that more TCE can be reduced. Also, TCE removal in the hybrid barriers was not affected by chromate and naphthalene while the reduction rate of TCE with the co-existing contaminants by iron filings was significantly decreased. Significant TCE removal in this research indicates that the proposed hybrid barrier system has the potential to become the effective remediation alternative during the occurrence of oil shock. Also, if subsurface environments are contaminated with multi-pollutants that contain non-reducible compounds as well as reducible compounds such as TCE, the conventional reactive barriers cannot be applied to this subsurface environment, while the proposed hybrid system can be applied successfully.

Optimization analysis on collection efficiency of vacuum cleaner based on two-fluid and CFD-DEM model

  • Wang, Lian;Chu, Xihua
    • Advances in Computational Design
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    • v.5 no.3
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    • pp.261-276
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    • 2020
  • The reasonable layout of vacuum cleaner can effectively improve the collection efficiency of iron filings generated in the process of steel production. Therefore, in this study, the CFD-DEM coupling model and two-fluid model are used to calculate the iron filings collection efficiency of vacuum cleaner with different inclination/cross-sectional area, pressure drop and inlet angle. The results are as follows: The CFD-DEM coupling method can truly reflect the motion mode of iron filings in pneumatic conveying. Considering the instability and the decline of the growth rate of iron filings collection efficiency caused by high pressure drop, the layout of 75° inclination is suggested, and the optimal pressure drop is 100Pa. The optimal simulation results based on two-fluid model show that when the inlet angle and pressure drop are in the range of 45°~65° and 70Pa~100Pa, larger mass flow rate of iron filings can be obtained. It is hoped that the simulation results can offer some suggestion to the layout of vacuum cleaner in the rolling mill.

복합오염물질제거를 위한 현장반응층 이용에 관한 연구

  • 조현희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.168-171
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    • 2003
  • This research was conducted to assess the performance of the mixed reactive materials with sand, iron filings, and HDTMA-bentonite for trichloroethylene (TCE) and chromate removal under controlled groundwater flow conditions. TCE and chromate removal rates with the mixtures of iron filing/HDTMA-bentonite were highest among four columns due to reduction by iron filings and sorption by HDTMA-bentonite. The greater capacity of the mixed iron filing/HDTMA-bentonite compared HDTMA-bentonite was due to an enhanced chromate reduction in addition to chromate sorption. The presence of chromate caused greater inhibition of TCE removal in the column with iron filings, while the presence of TCE caused less inhibition of TCE. Also, nitrate caused the decrease in TCE removal relative to chloride. Nitrate ions may also significantly affect TCE reduction rates by competing for electrons with the chlorinated compounds. The anion and co-existed contaminants competing effects should be considered when designed permeable reactive barriers (PRBs) composed of zero valent iron for field applications to remediate TCE and chromate.

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Elementary Students' Conceptions of Magnetic Field by Drawing lines of Magnetic Field (자기력선 그림을 통한 초등학생들의 자기장 개념 조사)

  • Kwon, Sung-Gi;Shin, Mi-Sung
    • Journal of Korean Elementary Science Education
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    • v.26 no.4
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    • pp.440-448
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    • 2007
  • The purpose of this study is to examine elementary students' conceptions of magnetic fields around various magnets by drawing tasks. A total of 105 elementary students from the 3rd and 6th grade levels were asked to draw how iron filings would arrange around magnets. We classified their drawings of magnetic field lines with some criteria to identify conceptions of magnetic forces and checked them through interviewing about their representative drawing. Through analyzing drawings, we discovered that 40% of elementary students drew the correct arrangement of iron filings around a bar magnet. In the case of two bar magnets in opposite directions, 33% of them drew correct patterns of iron dust and around two magnets in the same direction only 20% did well. Only 2.9% and 7.6% of students presented the correct drawings of magnetic fields near a disc and a horseshoe magnet. While 3rd grade students were supposed to be poor in drawings of magnetic fields around a loose and a dense coil which was not learned about, only 31% and 23% of 6th grade students who have just studied electromagnetism properly drew patterns of iron dust. This shows that only one quarter of students understood the magnetic filed lines even after instruction of electromagnetism. Many of 6th grade students learned a solenoid becomes just as a permanent magnet, but very few of them correctly drew a magnetic field line could distinguish between the iron dust around a loose and dense coil. After interviewing students, it is found that students consider magnetic forces to be existed only in parts of magnet because many of them drew magnetic field line of a specific areas around magnets. Students had misconceptions that magnetic forces exist only on the poles not in the middle around a horseshoe magnet. Also the disc-shape magnet made students to reveal various types of misconceptions: N- and S-poles are mixed in a whole magnet and right part of a disc-shape magnet is N-pole, left part is S-pole. Students who had not studied magnetic fields of around a magnet and electromagnets could not draw the correct patterns of iron dust suggest that it is indispensable for students to teach how patterns of iron filings would represent a visual image of magnetic fields in order to understand magnetic fields.

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Microbial Reduction of Iron(III) Oxides: Implication for Permeable Reactive Barriers. (철환원 미생물을 이용한 3가 철의 환원에 관한 연구)

  • 임현정;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.250-253
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    • 2002
  • Remediation of groundwater using zero valent iron filings has received considerable attention in recent years. However, zero valent iron is gradually transformed to iron(III) oxides at permeable reactive barriers, so the reduction of iron(III) oxides can enhance the longevity of the reactive barriers. In this study, microbial reduction of Fe(III) was performed in anaerobic condition. A medium contained nutrients similar to soil solution. The medium was autoclaved and deoxygenated by purging with 99.99% $N_2$ and pH was buffered to 6, while the temperature was regulated as 2$0^{\circ}C$. Activity of iron reducing bacteria were not affected by chlorinated organics but affected by iron(III) oxide. Although perchloroethylene(PCE) was not degraded with only ferric oxide, PCE was reduced to around 50% with ferric oxide and microorganism. It shows that reduced iron can dechlorinate PCE.

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TCE제거를 위한 반응층과 고정화층의 결합 실험

  • 조현희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.67-70
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    • 2002
  • Remediation of groundwater contaminated with chlorinated organics, nitro aromatics, and heavy metals using zero valent iron (ZVI) filings has paid considerable attention in recent years. When the contaminants of high concentration leaked abundantly in subsurface environment, permeable reactive barrier technology using iron filing is taken a long time for the remediation of contaminated groundwater, The problem of contaminant shock is able to be solved using surfactant (hexadecyltrimethylammonium, HDTMA) modified bentonite (SMB) as immobilizing material. Therefore, the purpose of this research was to develop the combined remediation technology using conventional permeable reactive and immobilizing barrier for the enhanced decontamination of chlorinated compounds. Four column experiments were conducted to assess the performance of the mixed reactive materials with Ottawa sand, iron filing, and HDTMA-bentonite for trichloroethylene (TCE) removal under controlled groundwater flow conditions. TCE reduction rates with sand/iron filing/HDTMA-bentonite were highest among four column due to dechlorination of TCE by iron filing and sorption of TCE by SMB.

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영가 철로 구성된 Flow-Through Column내에서 미생물 처리에 이한 폭발성 물질의 제거 향상

  • 오병택;윤제용
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.73-76
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    • 2004
  • Rusted iron could retain activity to redox-sensitive pollutants in batch reactor. Flow-through columns packed with permeable reactive iron filings (Fe$^{0}$ ) between soil and sand layers were used to evaluate the applicability of bio-enhanced iron barriers to treat explosives-contaminated groundwater. One column was bioaugmented with municipal anaerobic sludge to evaluate the enhancement of biodegradation. Military contaminants (RDX, HMX, TNT, 2,4DNT, 2,6DNT), which coexist in soils at military sites, were completely removed in the bioaugmented Fe$^{0}$ layer after 8 months of operation. Overall, this research suggests that Fe$^{0}$ barriers can effectively clean up groundwater contaminated with military explosives, and that treatment efficiency can be enhanced by bioaugmentation.

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Analysis of Iron-filings Trapping Characteristics on Concrete Slab Track using Permanent Magnet (영구자석을 이용한 콘크리트 궤도상의 쇠가루 포집장치 특성 분석 연구)

  • Park, Chan-Bae;Lee, Ju
    • Journal of the Korean Society for Railway
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    • v.14 no.4
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    • pp.348-353
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    • 2011
  • Iron fillings which were accumulated around the rail was often the cause of abnormal signal in case of signaling equipment using rail as transmission line. Iron fillings were generated on curved section of railroad due to the friction between rail and wheel, and metro line company urged to find the way to remove these iron fillings, because these were often the cause of abnormal signal. Magnetic device for trapping iron fillings around concrete slab tracks is introduced. The characteristics of magnetic device were analyzed using basic design and numerical analysis method. Magnetic device for trapping iron fillings were examined for application to the train which were operating in commercial line.

ZanF를 이용한 질산성 질소 환원 및 암모늄부산물 동시제거

  • 이승학;이광헌;이성수;박준범
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.107-110
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    • 2003
  • Reduction of nitrate by zero valent iron (Fe$^{0}$ ) has been previously studied, but the proper treatment for the by-product of ammonium has not been reported. However, in terms of nitrogen contamination, ammonium may be regarded as another form of nitrogen contaminants since it can be oxidized to nitrate again under aerobic conditions. This study is focused on simultaneous removal of nitrate and its by-product of ammonium, with the ZanF (Zeolite anchored Fe), a product derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed without buffer at two different pH condition with ZanF, iron filing, Fe(II)-sorbed zeolite, and pure zeolite to estimate the nitrate reduction and the ammonium production. At higher pH, removal rate of nitrate was reduced in both ZanF and iron filings. ZnF removed 60 % of nitrate at initial pH of 3.3 with no production of ammonium, while iron filing showed equivalent production of ammonium to the reduced amount of nitrate. In terms of nitrogen contamination, ZanF removed about 60 % and 40 % at initial pH of 3.3 and 6, respectively, while iron filing presented negligible removal against total nitrogen including nitrate and ammonium.

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The Meaning of Scientific Observation and an Analysis of Students' Observational Activity (과학적 관찰의 의미와 탐구과정에서 학생들의 관찰 행동 분석)

  • Park, Jong-Won;Kim, Ik-Gyun
    • Journal of The Korean Association For Science Education
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    • v.19 no.3
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    • pp.487-500
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    • 1999
  • Observation is one of the important aspects in science and science education. However. observation has so many varieties that the purpose and the meaning of scientific observations used in science education are different in persons, contexts, and subjects. In this study, we tried to understand the natures of scientific observation and investigated students' observational activities using four observation tasks: candle, double pendulum, iron filings around bar magnet, two electric bulbs connected in series. We required the subjects to observe the given tasks and described what did they observe. Based on students' observational descriptions, students' observational activities could be classified in four categories: primitive, interpretive, operational, and interfered observation. Also, we could find that some of the descriptions were non-observational activities such as predicting and questioning and so on. Finally, implications for the teaching of observation in science education are suggested.

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