• Title/Summary/Keyword: Iron chloride

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Natural Dyeing Characteristics of Black Color to the Korean Traditional Hand-made Paper (Hanji) (천연염색 재료를 이용한 한지의 검정색 염색 특성)

  • Lee, Sang-Hyun;Yoo, Seung-Il;Choi, Myun-Gwan;Sin, Sun;Choi, Tea-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.4
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    • pp.406-413
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    • 2009
  • This study was carried out to investigate the natural dyeing characteristics of Korean traditional hand-made paper (Hanji). The Hanji was dyed black with extractive of gallnut (Rbusjavanica L), leaves of Amur maple (Acer ginnala), nutshell of chestnut (Castania crenata), and persimmon juice and Chinese ink. And moreover, the Hanji was dyed not only using single and combination of dyestuff but also changing mordants and mordanting procedure. And we estimated the relationship between dyeing characteristics and dyestuff concentration (o.w.f.). The gallnut was the most principal material dyeing black. The procedure of mordanting from copper acetate to Iron (II) chloride and dyeing from gallnut to Amur maple dyestuffs were the best dyeing method for the Hanji to black. The K/S value of dyed Hanji increased with increasing concentration of dyestuff.

Development of Source Profiles and Estimation of Source Contribution for VOCs by the Chemical Mass Balance Model in the Yeosu Petrochemical Industrial Complex (여수석유화학산단 내 VOCs에 대한 오염원 분류표의 개발 및 CMB 모델에 의한 기여도 산정)

  • Jeon Jun-Min;Hur Dong;Kim Dong-Sul
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.83-96
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    • 2005
  • The purposes of this study were to characterize the local levels of VOCs (volatile organic compounds), to develop source profiles of VOCs, and to quantify the source contribution of VOCs using the CMB (chemical mass balance) model. The concentration of VOCs had been measured every 6-day duration in the SRO monitoring site in the Yeosu Petrochemical Industrial Complex from September 2000 to August 2002. The total of 35 target VOCs, which were included in the TO-14 designated from the U.S. EPA, was selected to be monitored in the study area. During a 24-h period, the ambient VOCs were sampled by using canisters placing about 10 ~ 15 m above the ground level. The collected canisters were then analyzed by a GC-MS in the laboratory. Aside from ambient sampling at the SRO site, the VOCs had been intensively and massively measured from 8 direct sources and 4 general sources in the study area. The results obtained in the study were as follows; first, the annual mean concentrations of the target VOCs were widely distributed regardless of monitoring sites in the Yeosu Petrochemical Industrial Complex. In particular, the concentrations of BTX (Benzene, Toluene, Xylene), vinyl chloride were higher than other target compounds. Second, based on these source sample data, source profiles for VOCs were developed to apply a receptor model, the CMB model. Third, the results of source apportionment study for the VOCs in the SRO Site were as follows; The source of petrochemical plant was apportioned by 31.3% in terms of VOCs mass. The site was also affected by 16.7% from wastewater treatment plant, 14.0% from iron mills, 8.4% from refineries, 4.4% from oil storage, 3.8% from automobiles, 2.3% from fertilizer, 2.3% from painting, 2.2% from waste incinerator, 0.6% from graphic art, and 0.4% from gasoline vapor sources.

Dyeing Properties and Ultraviolet-cut Ability of Dyed Fabrics with Petasites japonicus Extract (머위 추출액에 의한 직물의 염색성과 자외선 차단성)

  • Choi, In-Ryu;Joen, Mi-Sun
    • The Research Journal of the Costume Culture
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    • v.19 no.1
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    • pp.96-103
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    • 2011
  • It is well known that the Petasites japonicus has been used for a long time medicine for the treatment of allergic diseases such as lacquer poisoning. However, the exact components and dyeing properties of its effects is still not known. Therefore, the purpose of this study was to investigate the dyeing property and ultraviolet-cut ability of silk and nylon fabrics that was dyed variously with the Petasites japonicus. The Petasites japonicus extract was done by boiling with distilled water at $100^{\circ}C$ for 1 hour. As mordanting agent, we used Aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$), Copper(II) sulfate pentahydrate ($CuSO_5{\cdot}5H_2O$), Iron(II)Chloride ($FeCl_2{\cdot}4H_2O$). The best K/S value of dyeing temperature and time, all the fabrics were $100^{\circ}C$, 90min. Silk fabric was dyed yellow(0.8Y 7.6/2.2) and nylon fabric was dyed reddish yellow(10.1 YR 7.4/3.0). Silk fabric and nylon fabric was changed greenish yellow on mordanting with $CuSO_5{\cdot}5H_2O$ and $FeCl_2{\cdot}4H_2O$ respectively. And the colorfastness of washing and dry-cleaning was improved by using mordanting agent(4~5 grade). Ultraviolet-cut ability(UV-B) was showed more 90% in dyed nylon fabrics.

Effects of Dietary Education on Low-sodium Diet Adaptation (식생활교육이 저나트륨식 적응에 미치는 영향)

  • Kim, Hae Young;Kim, Juhyeon
    • Journal of the Korean Society of Food Culture
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    • v.29 no.2
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    • pp.212-221
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    • 2014
  • Korean style DASH (Dietary Approaches to Stop Hypertension) and a dietary education program for sodium reduction were developed. Reduced sodium diets (15 and 30% reductions) were developed from general diets for 3 consecutive weeks from Monday through Saturday. Subjects (19 total) were classified into two groups according to dietary education. Experimental period was from June 24 to July 23, 2012. Total sum of adaptation scores for low sodium diets significantly increased in the group that underwent dietary education compared to that without (p<0.05). After the experiment, both groups showed significantly increased values in terms of food group balance, sodium-related nutrition knowledge, attitude, and practice by paired t-test. Especially, group that underwent dietary education showed significantly higher values for attitudes by ANCOVA pre-test as a variation (p<0.01). For the results of the nutrient intake survey, group that underwent dietary education showed significantly increased values for dietary fiber (p<0.01), vitamin A (p<0.001), vitamin K (p<0.001), vitamin C (p<0.01), Folic acid (p<0.001), vitamin B12 (p<0.01), calcium (p<0.01), iron (p<0.05), and zinc (p<0.05) and significantly decreased values for sodium (p<0.05) and chloride (p<0.005). Subjects adapted to reduced sodium diets showed apparent improvements in sodium-related knowledge, attitude, practice and intake of nutrient, and these improvements were even higher in the group that underwent dietary education compared to that without. Thus, adaptation to low sodium diet combined with dietary education can improve dietary habits.

Toxic Effects and Distribution of Mercury in Barley Seedlings (보리 유식물에 처리한 수은의 분포 및 독성 연구)

  • 이춘환;장호식
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.13-21
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    • 1992
  • The inhibitory effects of mercury ions on the growth of barley seedlings were studied and the distribution of metal elements in the organs of treated plants was investigated by using synchrotron radiation induced X-ray emission (SRIXE). Although the treatment of mercury ions caused growth inhibition, the mercury-specific increase in variable fluorescence and the abolishment of energy-dependent quenching in broken barley chloroplasts as shown by Moon et at. (1992) were not observed in the leaves of growth-inhibited seedlings. Instead the treatment of mercury decreased Fmax and Fo values. However, Fmax/Fo ratio and photochemical and nonphotochemical quenching coefficients were not affected significantly. By SRIXE analysis of $10\mu\textrm{m}$ mercury chloride treated seedlings, accumulation of mercury in roots was observed after 1 hour of treatment and similar concentration was sustained for 48 hours. Relative contents of mercury was high in roots and underground nodes where seeds were attachedl but was very low in leaves. Iron and zinc were also distributed mainly in the lower parts of the seedlings. However after 72 hours of treatment the contents of these metals in roots decreased and their distribution became more uniform, which may lead to death of the plants. These results suggest that the observed inhibitory effects on barley seedlings upto 48 hours after the treatment is not due to direct damages in the photosynthetic apparatus, but due to its accumulation in roots and the consequent retardation of the growth of barley seedlings. The decrease in Fmax and Fo is probably due to the decrease in chlorophyll and protein contents caused by the retardation of growth. The observed slow expansion of primary leaves could be also explained by the retardation of growth, but the fluorescence induction pattern from the leaves did not show characteristic symptoms of leaves under water stress.

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Effect of Steam Curing on Compressive Strength of Slag Binder Concrete (증기양생이 고로슬래그 콘크리트의 압축강도에 미치는 영향)

  • Lim, Byung-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.8
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    • pp.338-343
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    • 2017
  • In this study, blast furnace slag powder was used in concrete to help reduce carbon dioxide emissions and to recycle industrial waste. Blast furnace slag powder is a byproduct of smelting pig iron and is obtained by rapidly cooling molten high-temperature blast furnace slag. The powder has been used as an admixture for cement and concrete because of its high reactivity. Using fine blast furnace slag powders in concrete can reduce hydration heat, suppress temperature increases, improve long-term strength, improve durability by increasing watertightness, and inhibit corrosion of reinforcing bars by limiting chloride ion penetration. However, it has not been used much due to its low compressive strength at an early age. Therefore, this study evaluates the effects of steam curing for increasing the initial strength development of concrete made using slag powder. The relationship between compressive strength, SEM observations, and XRD measurements was also investigated. The concrete made with 30% powder showed the best performance. The steam curing seems to affect the compressive strength by destroying the coating on the powder and by producing hydrates such as ettringite and Calcium-Silicate-Hydrate gel.

Production of Fine Cobalt Metal Powders from Stellite Scrap (Stellite 스크랩으로 부터 Co 미분말의 제조)

  • 박문경;신동성
    • Resources Recycling
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    • v.3 no.1
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    • pp.9-16
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    • 1994
  • Fine cobalt metal powders was produced from domestic Stellite scrap by decomposing it with molten sodium hydroxide. Complete decomposition of the scrap could be obtained with the weigth ratio of sodium hydroxide to Stellite being about 2 at the temperature ranges of $750~800^{\circ}C$ for an hour. The cobalt-bearing compound was identified as $Co_2O_3{\dot}H_2O$ by X-ray analysis and D.T.-T.G.a.. The compound was then digested in HCI to form cobalt chloride, and after iron removal by adjusting the pH of the solution, cobaltous or cobaltic hydroxide was precipitated at the pH of about 13 or 4, respectively. The precipitates were reduced by hydrogen in the temperatures of $400~500^{\circ}C$ to fine cobalt powders of high purity with the size of 1.0 to $1.5\mu\textrm{m}$. The recovery of cobalt from Stellite scrap was about 75~86% by weight.

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A study on characteristics of influent and effluent pollutants in public sewage treatment works combined with industrial wastewater and landfill leachate (공공하수처리시설에서 수질오염물질 유입 및 배출 특성 고찰 - 산업폐수 및 매립지 침출수 연계처리 시설을 중심으로 -)

  • Jeong, Dong-Hwan;Cho, Yangseok;Ahn, Kyung-Hee;Kim, Eunseok;Kim, Changsoo;Chung, Hyen-Mi
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.673-682
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    • 2016
  • In this study, we investigated influent and effluent water pollutants in 53 Public Sewage Treatment Works (PSTWs) where industrial wastewater or landfill leachate is combined four times for two years from 2014 to 2015. Also, we analyzed the characteristics of heavy metals and volatile organic carbons at influent and effluent of these PSTWs caused by sewage treatment combined with industrial wastewater or landfill leachate. As a result, six heavy metals such as barium, copper, iron, manganese, nickel and zinc, and four volatile organic carbons (VOCs) including phenols, di(2-)ethylhexyl phthalate (DEHP), formaldehyde and toluene were observed above detection limits in most of PSTWs. Also, it was revealed that six heavy metals such as hexavalent chromium, mercury, cadmium, chromium, nickel and selenium, and four VOCs including 1,1-dichloroethylene, vinyl chloride, naphthalene, and epichlorohydrin were observed more frequently according to precipitation. As a result of reviewing the monitoring data on "Water Quality Monitoring Networks" in lower watersheds of PSTWs, both heavy metals and VOCs were below detection limits, indicating that the effluent water had little influence on the watershed. Nevertheless for the better management of influent and effluent pollutants in PSTWs, it is necessary to establish the advanced management plans for water pollutants in PSTWs, which include a list of priority substances management, monitoring plans, and guidelines for industrial wastewater and landfill leachate combined in PSTWs.

Corrosion Behavior of Boiler Tube under Circulation Water Conditions in District Heating System (지역난방 시스템의 순환수에 따른 보일러 튜브의 부식 특성)

  • Hong, Minki;Cho, Jeongmin;Song, Min Ji;Kim, Woo Cheol;Ha, Tae Baek;Lee, Soo Yeol
    • Corrosion Science and Technology
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    • v.17 no.6
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    • pp.287-291
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    • 2018
  • In this study, corrosion behavior of a SA178-A alloy used in the boiler tube of a district heating system was investigated in different environments where it was exposed to pure water, district heating (DH) water, and filtered district heating (FDH) water. After the corrosion test, the surface morphology was examined for observation of the number of pitting sites and pitting area fraction, using a scanning electron microscope. The DH water and FDH water conditions resulted in a lower corrosion potential and pitting potential, and revealed a significantly higher corrosion rate than the pure water condition. The pitting sites in the DH water (pH 9.6) were approximately eighteen times larger than those in the pure water (pH 9.6). Compared to the DH water, the corrosion potential became more noble in the FDH water condition, where iron ions were reduced through filtration. However, the corrosion rate increased in the FDH water due to an increased concentration of chloride ions, which deteriorated the stability of passive film.

Evaluation on Soil Washing of Metal-contaminated Soil using Non-Inorganic Acids (비 무기산 세척제에 의한 중금속 오염 토양 세척효과 평가)

  • Lee, Ga-Bin;Jeong, Won-Gune;Lee, Su-Min;Park, Jin;Jo, Yong-Hwan;Baek, Kitae
    • Journal of Soil and Groundwater Environment
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    • v.27 no.5
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    • pp.10-17
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    • 2022
  • Inorganic acids such as HCl, HNO3, and H2SO4 have been commonly applied to soil washing of heavy metals-contaminated soil due to their cost-effectiveness. However, implementing the 'Chemical Substance Control Act' requires off-site risk assessment of the chemicals used in the soil washing. Therefore, in this study, organic acids or Fe(III)-based washing agents were evaluated to replace commonly used inorganic acids. Ferric removed heavy metals via H+ generated by hydrolysis, which is similar to the HCl used in the control group. Oxalic acid and citric acid were effective to remove Cu, Zn, and Cd from soil. Organic acids could not remove Pb because they could form Pb-organic acid complexes with low solubility. Furthermore, Pb could be adsorbed onto the iron-organic acid complex on the soil surface. Ferric could remove exchangeable-carbonate, Fe-Mn hydroxide, and organic matter and sulfides bound heavy metals (F1, F2, and F3). Organic acids could remove the exchangeable-carbonate and Fe-Mn hydroxide bound metals (F1&F2). Therefore, this research shows that the fractionation of heavy metals in the soil and the properties of washing agents should be considered in the selection of agents in the process design.