• 보존과학연구
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• s.32
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• pp.89-98
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• 2011

It is quite difficult to identify its corrosion compound because they have a wide variety of crystal structures and they are mixed with two component. This study was conducted with the standard iron corrosion compounds through the analysis by Raman Micro-Spectroscopy, which aims to obtain standard Raman Data. To assess the reliability of standard iron corrosion compounds, SEM-EDS analysis and XRD analysis were conducted. Through SEM-EDS analysis, the elements of corrosion compound matched with those of standards iron corrosion compounds except Goethite. XRD analysis showed that the structures of corrosion compounds were identical to those of standard iron corrosion compounds, however, it was identified that Iron sulfate ($FeSO_4{\cdot}6H_2O$) is the Rozenite ($FeSO_4{\cdot}4H_2O$). Through Raman Micro-Spectroscopy analysis, the new peak was detected from the wavenumbers of hydroxide and iron oxide. It is considered that it is due to changes in the wavelength of the laser. As the wavenumbers of iron chloride and iron sulfate have been identified, eight kinds of Raman Data were obtained. It can be considered to contribute to cultral heritage for iron objects that Raman Micro-Spectroscopy analysis which is relatively easy to compare material properties and structures can be highly applicable to the research on cultural heritage with the limited amount of samples.

• Journal of Conservation Science
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• v.30 no.4
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• pp.335-343
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• 2014

This study classified the result of non-metallic inclusion analysis and result of microstructure investigation on the ironware excavated in the Baekje region into Han River, Geum River, and Yeongsan River to estimate the iron making temperature and study the characteristics of regional and temporal characteristics of the heat treatment technology and steel making technology. Regardless of era, bloom iron and sponge iron are judged to be the major method for making as a directreduction process in all three regions. The result of the reinterpretation of the non-metallic inclusion by the oxide ternary constitutional diagram suggest that the temperature inside of the furnace is estimated to be between $1,100{\sim}1,300^{\circ}C$ while making the steel. The magnetic iron ores are the major raw material of steel ore and irons with high $TiO_2$ are estimated to use iron sands. Ironware with $CaO/SiO_2$ rate higher than 0.4% are considered to have artificially added the flux of calcareous materials. It was found that the iron making method is the solid caburizing-steel which caburizes low-carbon steels by the CO gas and $CO_2$ gas created when heating the forging furnace with charcoal. Also, the ironware manufacturers in the Baekje during 3rd century recognized the heat treatment technology as they performed carburizing process and quenching to intentionally increase the strength of necessary parts.

• Journal of the Korean Society of Costume
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• v.65 no.3
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• pp.76-90
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• 2015

This is a basic study of the two remaining armors (artifacts number K2366, K2368) from the late Joseon dynasty that is part of the Korean costume collection, which is preserved in the Mission Museum of Saint Ottilien in Germany. The armor No. 1 (artifacts number K2366) is a coat-styled armor with brass studs. It has a U-shaped neckline with the non-overlapping collars and sleeve straight-lined inseam. The armor No. 1 has the Mu to the sides and is not back slit. Both its inner and outer material are padded with cotton. Leather mails are attached on the inner lining, and studs are attached on the outer lining to match the leather mails. For this reason, the armor No. 1 can be named MyeonPiGab (brass studded armor consisting of a cotton coat with internal leather mails). The outer material is faded to have the natural white, or antique white look and the patterns on it are indigo blue. The inner material is blue, but the original color is unknown since it is faded. The lotus blossoms and vine patterns are dyed on the surface of the outer material and a name is written on the inner material. The armor No. 1 was worn between the late 17th century and the 19th century. It is estimated that it was worn by military officers who were above the mid-rank in the end of the Joseon dynasty. The armor No. 2 (artifacts number K2368) is a coat-styled armor with brass studs and a low-cut U-shaped neckline. The armor No. 2 has a slit on the left armpit and a string around it. Studs are evenly attached on the armor. The iron mails are attached to the left chest area on its inner lining. It seems that it was designed with both formality and functionality in mind. The outer material is red flannel, the inner material is blue satin and the pads are cheesecloth. The side of its collars, cuffs, front lines, sidelines, back slit, and bottom lines are trimmed with fur. There are armors called "JeonCheolGap (brass studded armor consisting of a felt coat with internal iron mails)," which is similar to the armor No. 2, however, the similarities are limited because they are not made of the same material nor do they follow the same principle of nomenclature.

• Conservation Science in Museum
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• v.25
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• pp.85-94
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• 2021

Conservation treatment of metallic artifacts contaminated with corrosion and foreign substances requires changes in the shape, characteristics, weight and thickness of the artifacts. Thus far, recording the changes after conservation treatment has mainly been performed through visual observation and photography, which lacks any quantitative description of the changes. In this study, the processes of removing foreign substances, joining cracks, and restoring an affected area were recorded using 3D scanning and then quantitatively analyzed to identify changes in form due to conservation treatment. The volume change after the conservation process was calculated based on the results of the 3D scanning, and numerical data on the changes to the form was analyzed. It was revealed that the foreign or corroded substances removed after the conservation accounted for 18.1 cm³, which is approximately 52% of the total volume of the ring pommel, and those substances were removed from about 98% of the surface of the ring pommel. This study confirmed that 3D form analysis was useful for recording the processes of conservation treatment and analyzing the results. It is therefore believed that this methodology can be applicable to not only metal artifacts, but to cultural heritage items in a range of materials.

• Conservation Science in Museum
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• v.11
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• pp.1-8
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• 2010

Conservation re-treatment of dagger and scabbard in Gyeongju National Museum, which were excavated from Gyerim-ro Tomb No. 14 (Treasure No. 635) was carried out after a wide-scale dissembling in order for publishing a report and holding a special exhibition. The interior shape of the iron dagger which was disclosed by ornament plates was confirmed by X-ray investigation. The results of XRF analysis which was used to analyse compositions of the golden ornament plates reveal that having more than 3% of copper distinguishes it from other Silla gold artifacts. The conservation treatment progressed in a way that surface contaminants were removed and insecure areas were consolidated. The original shape of the iron dagger and scabbard was found after adhering and restoration. With the ornament plates staying on the iron dagger, a stand in acrylic for display and storage was made, which is able to place the dagger and scabbard in the safest way.

• Conservation Science in Museum
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• v.1
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• pp.15-26
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• 1999

More than 200 objects selected for the newly-opened Kimhae National Museum were treated for conservation. The objects which represent ancient Kaya culture, were mainly composed of metallic such as gilt bronze, silver, copper alloy and iron. The corrosion products on gilt bronze and copper alloy objects were preserved or removed according to their stability. Minimum treatment was done for preserving the original state of the objects. For silver objects and iron objects with silver-plate decorations, silver surfaces were revealed after treatment of corrosion products and treatments to prevent corrosion of silver and iron were done emphatically. For iron objects, which were stabilized, the original shape of objects was restored and acrylic coating was applied to prevent further corrosion. For the objects which were being corroded, 2-step de-chloride treatments were undertaken. The first step was immersing the objects in a solution of 0.3M sodium hydroxide and the second was the pressure de-chloride treatment using borax-distilled water. The main purpose of those treatments was to get rid of the causes of corrosion. Besides, conservation treatments for potteries, making of special mounting board for exhibition and amendment of various modeling were done too.

• Journal of Conservation Science
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• v.36 no.5
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• pp.368-382
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• 2020

It was confirmed that a white porcelain figurine in underglaze iron was damaged after exhibition. This study analyzes the current state of salt damage on the artifact and identifies the factors contributing to its deterioration by examining the material characteristics of the artifact and exhibition environment. The analysis will thus assist in preparing a conservation scheme for artifacts. The crystallized carbonate on the surface of the white porcelain figurine is a water-soluble alkali salt with high hygroscopicity and high solubility in water. This solubility increases as the temperature increases. The figurine was low-fired at approximately 1000℃. A lead glaze was applied, and thin cracks were formed on the glazed surface, indicating poor surface properties. Our analysis suggested that the showcase used in the exhibition likely created a moist environment resulting from condensation, as it was exposed to high temperature and relative humidity, particularly in comparison to the exhibition room where the temperature was regulated using an air conditioner. In addition, the artifacts in the showcase were exposed to sudden changes in temperature and relative humidity as the air conditioner was repeatedly turned on and off. Therefore, it can be deduced that the soluble salt remaining on the white porcelain figurine moved toward the surface of the relatively weak glaze as a result of the temperature, and the crystallized salt exacerbated surface damage as the moisture evaporated in a dry environment.

• Journal of architectural history
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• v.15 no.2
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• pp.55-76
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• 2006

History of architecture technology is the area where further studies are the most needed in Korean architecture history. This present study deals with architectural tools and woodworking of Baekje as a first step in exploration of Korean architecture technology history especially, that of Baekje dynasty. Based on the study of real artifacts and archeological sites showing the trace of tool use, function and forms of architectural tools were classified, characteristics of tools investigated, and woodworking technology analyzed. The main tools of analysis include Square, Black Inkpot, Hatchet, Saw, Chisel, Wood Hammer, Axe, and Plane. It is assumed that architectural technology during Baekje dynasty might have leapt into the new stage thanks to the regular use of iron tools. Compared to those of previous eras, iron tools of Baekje are more elaboratedly-designed and well-defined in function. In addition, wooden architectural tools from Baekje demonstrate the superiority of its woodworking technology Historical record also shows the fact that craftsman from Baekje participated in construction of temples of Shilla and Japan. Precise assessment of Baeje architecture technology is difficult because no Baekje wooden architecture is still remaining. The facts mentioned above, however, surely prove the excellence of architecture technology of Baekje.

• Korean Journal of Heritage: History & Science
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• v.53 no.2
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• pp.4-23
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• 2020

The purpose of this study was to explore the diversity of Korea's iron casting technology and to examine various casting methods. The study involved a literature review, analysis of artifacts, local investigation of production tools and technology, and scientific analysis of casting and cast materials. Bellows technology, or Bulmi technology, is a form of iron casting technology that uses bellows to melt cast iron before the molten iron is poured into a clay cast. This technology, handed down only in Jeju Island, relies on use of a clay cast instead of the sand cast that is more common in mainland Korea. Casting methods for cast iron pots can be broadly divided into two: sand mold casting and porcelain casting. The former uses a sand cast made from mixing seokbire (clay mixed with soft stones), sand and clay, while the latter uses a clay cast, formed by mixing clay with rice straw and reed. The five steps in the sand mold casting method for iron pot are cast making, filling, melting iron into molten iron, pouring the molten iron into the cast mold, and refining the final product. The six steps in the porcelain clay casting method are cast making, cast firing, spreading jilmeok, melting iron into molten iron, pouring the molten iron, and refining the final product. The two casting methods differ in terms of materials, cast firing, and spreading of jilmeok. This study provided insight into Korea's unique iron casting technology by examining the scientific principles behind the materials and tools used in each stage of iron pot casting: collecting and kneading mud, producing a cast, biscuit firing, hwajeokmosal (building sand on the heated cast) and spreading jilmeok, drying and biyaljil (spreading jilmeok evenly on the cast), hapjang (combining two half-sized casts to make one complete cast), producing a smelting furnace, roasting twice, smelting, pouring molten iron into a cast, and refining the final product. Scientific analysis of the final product and materials involved in porcelain clay casting showed that the main components were mud and sand (SiO₂, Al₂O₃, and Fe₂O₃). The release agent was found to be graphite, containing SiO₂, Al₂O₃, Fe₂O₃, and K₂O. The completed cast iron pot had the structure of white cast iron, comprised of cementite (Fe₃C) and pearlite (a layered structure of ferrite and cementite).

• Korean Journal of Heritage: History & Science
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• v.52 no.3
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• pp.160-171
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• 2019

The sword with a ring pommel, which was excavated from the first stone chamber of the ancient tombs of Jeongchon Village in Naju, is a sword with a pentagon undecorated ring pommel consisting of a mother sword and two child swords. The sword with an undecorated ring pommel of Jeongchon comprises a ring pommel, a hilt, a knife, and a knife end decoration. This sword was coated with lacquer. The ring pommel is an iron frame covered with silver plate; however the silver tarnished into a light purple due to silver chloride corrosion, and iron corrosion originated from the inside is visible on the surface. Silver chloride corrosion is produced when silver objects are exposed to water, dissolved salts, and dissolved chloride ions when in a buried state. It changes objects into powder, making it difficult to preserve original shapes. The other silver artifacts found in the Jeongchon ancient tombs show similar signs of corrosion. The results of X-ray irradiation and a CT analysis showed that the sword had a ring at the end of the handle, a T-shaped hilt, and was probably connected to the handle end of a knife. If the shape of the mother sword can be inferred from the child swords, the mother sword had a ring pommel, decorations of the handle, covered with silver plate, and a gold ring and a silver line wound around the handle. It is assumed that the ring pommel was connected to the knife by welding because no holes were observed. The end decoration of the knife was made by using an iron plate formed into a shape, half covered by silk, and the other half decorated with silver plate and a gold ring. The sword with an undecorated ring pommel excavated from the ancient tombs of Jeongchon Village comprises the metals of gold, silver, and iron, and includes features of Baekje, Silla, and Gaya, which highlights the influence of surrounding historic sites and various cultures.