• Title/Summary/Keyword: Iron Sulfate

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Behavior of the High Temperature Oxygen Pressure Leaching of Chalcopyrite in Sulfuric Acid Solution (고온.산소가압하(高溫.酸素加壓下)에서의 황동광(黃銅鑛)의 황산침출 거동 고찰)

  • Eom, Hyoung-Choon;Yoon, Ho-Sung;Yoo, Kyoung-Keun;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.16 no.3 s.77
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    • pp.44-49
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    • 2007
  • In the present work, the high temperature oxygen pressure leaching behavior of chalcopyrite was studied in sulfuric acid solution. The influence of leaching time, temperature and oxygen partial pressure on leaching process were examined. Leaching rate of copper increased significantly with increasing leaching temperature. Copper recovery reached 87.1% within 2 hours at 200C and 10 atm oxygen pressure, while most of the solubilized iron readily re-precipitates as hematite(Fe2O3). It was confirmed that e main leach reaction of chalcopyrite occurred through oxidation with oxygen under oxygen pressure and high temperature(above 150C). Because sulfur was oxidized entirely to sulfate, passivating elemental sulfur layer was not formed.

Glutathione Reductase from Oryza sativa Increases Acquired Tolerance to Abiotic Stresses in a Genetically Modified Saccharomyces cerevisiae Strain

  • Kim, Il-Sup;Kim, Young-Saeng;Yoon, Ho-Sung
    • Journal of Microbiology and Biotechnology
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    • v.22 no.11
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    • pp.1557-1567
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    • 2012
  • Glutathione reductase (GR, E.C. 1.6.4.2) is an important enzyme that reduces glutathione disulfide (GSSG) to a sulfydryl form (GSH) in the presence of an NADPH-dependent system. This is a critical antioxidant mechanism. Owing to the significance of GR, this enzyme has been examined in a number of animals, plants, and microbes. We performed a study to evaluate the molecular properties of GR (OsGR) from rice (Oryza sativa). To determine whether heterologous expression of OsGR can reduce the deleterious effects of unfavorable abiotic conditions, we constructed a transgenic Saccharomyces cerevisiae strain expressing the GR gene cloned into the yeast expression vector p426GPD. OsGR expression was confirmed by a semiquantitative reverse transcriptase polymerase chain reaction (semiquantitative RT-PCR) assay, Western-blotting, and a test for enzyme activity. OsGR expression increased the ability of the yeast cells to adapt and recover from H2O2-induced oxidative stress and various stimuli including heat shock and exposure to menadione, heavy metals (iron, zinc, copper, and cadmium), sodium dodecyl sulfate (SDS), ethanol, and sulfuric acid. However, augmented OsGR expression did not affect the yeast fermentation capacity owing to reduction of OsGR by multiple factors produced during the fermentation process. These results suggest that ectopic OsGR expression conferred acquired tolerance by improving cellular homeostasis and resistance against different stresses in the genetically modified yeast strain, but did not affect fermentation ability.

Synthesis and Phosphorus Adsorption Characteristics of Zirconium Magnetic Adsorbent Having Magnetic Separation Capability (자기분리가 가능한 지르코늄 자성 흡착제의 합성과 인 흡착 특성)

  • Lim, Dae-Seok;Kim, Yeon-Hyung;Kim, Dong-Rak;Lee, Tae-Gu;Lim, Hak-Sang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.431-442
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    • 2012
  • The purpose of this study, is to separate magnetic separation devices using permanent magnets by using magnetization characteristics remaining in treated water after adsorption and synthesizing phosphorus adsorbent capable of magnetic separation for efficient removal of phosphorus. The synthesis of the adsorbent which set Zirconium(Zr) having high friendly features for phosphorus as an element, and by synthesizing Iron Oxide(Fe3O4, another name of Fe3O4 is magnetite) being able to grant magnetism to Zirconium Sulfate(Zr(SO4)2), zirconium magnetic adsorbent(ZM) were manufactured. In order to consider the phosphorus adsorption characteristics of adsorbent ZM, batch adsorption experiment was performed, and based on the results, pH effect, adsorption isotherm, adsorption kinetics, and magnetic separation have been explore. As the experiment result, adsorbent ZM showed a tendency that the adsorption number was decreased rapidly at pH 13; however, it was showed a high amount of phosphorus removal in other range and it showed the highest amount of phosphorus removal in pH 6 of neutral range. In addtion, the Langmuir adsorption isotherm model is matched well, and D-R adsorption isotherm model is ranged 14.43kJ/mol indicating ion exchange mechanism. The result shown adsorption kinetics match well to the Pseudo-second-order kinetic model. The adsorbent ZM's capablility of regenerating NaOH and H2SO4, was high selectivity on the phosphorus without impacts on the other anions. The results of applying the treated water after adsorption of phosphorus to the magnetic separation device by using permanent magnets, shows that capture of the adsorbent by the magnetization filter was perfect. And they show the possibility of utilization on the phosphorus removal in water.

Loess Dyeing of Soybean Fabrics (대두직물의 황토염색)

  • Lee, Sol;Lee, Shin-Hee
    • The Korean Fashion and Textile Research Journal
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    • v.17 no.6
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    • pp.1004-1012
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    • 2015
  • The purpose of this study is to investigate the loess dyeability of soybean fabric using loess as colorants. Recent days, various textile products such as inner wears, sheets and interior goods are manufactured using materials dyed with loess emphasizing its improved metabolism, anti-bacterial, deodorizing properties, and far infrared ray emissions. Soybean fabric was dyed with loess solution according to concentration of loess, dyeing temperature and dyeing time. To improve washing fastness, soybean fabric and dyed soybean fabric with loess were mordanted by mordanting agents such as sodium chloride(NaCl), Acetic acid(CH3COOH) and Aluminium Potassium Sulfate(AlK(SO4)2·12H2O). Dyeability and color characteristics of dyed soybean fabric were obtained by CCM observation. Particle size distribution of loess, the dyeability(K/S) of soybean fabric, morphology and washing durability of loess dyed soybean fabric were investigated. The results obtained were as follows; Mean average diameter of loess was 1.08µm. The main components of loess used in this study were silicon dioxide(SiO2), aluminium oxide(Al2O3), and iron oxide(Fe2O3). The content of these three component was above 75 weight %. The dyeability of soybean fabric was increased gradually with increasing concentration of loess. The optimum dyeing temperature and dyeing time were 90℃ and 60minutes expectively. The fastness to washing according to concentration of loess and mordanting method indicated good grade result as more than 4 degree in all conditions.

A Study on the Assessment of the Contamination by Acid Mine Drainage in Abandoned Coal Mines (국내폐탄광의 산성폐수 오염도 평가에 관한 연구)

  • 최우진
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.31-38
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    • 1997
  • Temporal and spatial comparisons of acid mine drainage contaminated waters are difficult because of the complex physico-chemical nature of the pollutant. In the present study, an acid mine drainage index has been developed and evaluated for the assessment of surface waters. AMD index is calculated using a modified arithmetic weighted index using seven parameters which are most indicative of AMD contamination, i. e. pH value, sulphate, iron, zinc, aluminum, copper and manganese. Weighting is used to express the relative indicator value of each parameter. The proposed AMD index is used to quantify contamination from acid mine drainage over ten different old mine sites and assess the degree of impact on surface on surface waters. As a result of AMD evaluation, the Sukbong Mine located near the Moonkyung province showed lowest AMD value indicating the worst acid mine drainage quality. In overall, Youngdong mine sites showed higher contaimination compared to the other mine sites including Youngsuh, Choongbu, Suhbu and Nambu area.

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A Study for Conservation for the Wooden Coffin - Artificial Deterioration Using Fenton's Reagent - (녹나무목관 보존처리에 관한 연구 - Fenton 산화를 이용한 생재의 인공열화 연구 -)

  • Yang, Suk-Ja;Yang, Seok-Jin;Jeong, Ah-Reum
    • 보존과학연구
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    • s.30
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    • pp.203-215
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    • 2009
  • In the conservation treatment of wood remains, polymers, treatment methods, and treatment period can be varied, depending on the percentage of moisture content and species of trees. Thus, in order to apply the appropriate conservation treatment, a lot of information from the wood remains are required. Despite the information from the wood remains, testing a part of the wood remains is necessary to get information about the polymers. When the wooden coffin made of camphor trees was excavated, it was cracked in the section of radiation, and there were hairlines cracks. Therefore, without any conservation treatment, it is impossible to restore it. This experiment is for the conservation treatment of the wooden coffin excavated from Songhyun-dong tombs No 7, Changnyeong. For this experiment, I used camphor trees from Jejudo. The purpose of this experiment is to asses the possibility of preliminary testing materials before the conservation treatment on the wooden coffin. After the camphor trees from Jejudo are artificially aged by Fenton's reagent, they are As a result of oxidation by Fenton, the degree of oxidation is high in proportion to the amount of peroxide and iron sulfate. Among several samples, the sample 'na' made the most similar result to the wooden coffin from Songhyun-dong. If I use this condition to make the sample in polymer tests, it is very helpful to find the most suitable polymer for the conservation treatment of wooden coffin. After the same species of trees are oxidized by Fenton and they become the similar condition, we are able to find suitable methods of conservation treatment. The suitable methods reduce the demage of the remains and make us to get more information. Thus, we are able to carry out conservation treatment more exactly.

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Rainfall Harvesting as an Alternative Water Supply in Water Stressed Communities in Aguata-Awka Area of Southeastern Nigeria

  • Okpoko, Ephraim;Egboka, Boniface;Anike, Luke;Okoro, Elizabeth
    • Environmental Engineering Research
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    • v.18 no.2
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    • pp.95-101
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    • 2013
  • Alternative sources of water are sought in some water stressed communities in the study area. The study focuses on the Aguata-Awka area of southeastern Nigeria. Aquifers occur at great depths, and surface waters may be far from homesteads. The scarcity of water has necessitated the people to adopt various local technologies for harvesting rainfall. The local technology includes collecting rainwater from roofs and channeling the water into large underground tanks, shallow wells and surface reservoirs. Large concrete tanks of 6m×6m×4m dimensions are often built underground and can store 144m3 of water. Surface reservoirs built on 4 m concrete pillar supports having dimensions of 10m×10m×4m and have a storage capacity of 400m3. Water samples were collected at 3 different locations of Agulu, Ekwulobia, and Awka and were analyzed for their physical, chemical, and bacteriological parameters. Results indicate a range of values for pH, 5.9 to 7.1; turbidity, 0.9 to 2.7; total dissolved solids, 80 to 170 mg/L; total hardness, 4.5 to 6.4 mg/L; magnesium, 1.2 to 1.4 mg/L; bicarbonate, 19.4 to 83.6 mg/L; and sulfate, 3.6 to 6.4 mg/L. Bacteriological analysis results were negative for fecal and total coliform counts. All parameters, with the exception of pH where aluminum and galvanized iron roofs are used for collection, fall within the recommended guidelines for drinking water quality of the World Health Organization, and the Standard Organization of Nigeria, new Nigerian standards for drinking water quality. Magnesium is above the maximum permitted level for consumer acceptability of the Nigerian standards for drinking water quality. The water can be classified as fresh moderately hard and soft. The water can be described as a calcium and bicarbonate type.

Characterization of Uranium Removal and Mineralization by Bacteria in Deep Underground, Korea Atomic Energy Research Institute (KAERI) (한국원자력연구원 지하심부 미생물에 의한 용존우라늄 제거 및 광물화 특성)

  • Oh, Jong-Min;Lee, Seung-Yeop;Baik, Min-Hoon;Roh, Yul
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.2
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    • pp.107-115
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    • 2010
  • Removal and mineralization of dissolved uranium by bacteria in KURT (KAERI Underground Research Tunnel), Korea Atomic Energy Research Institute (KAERI) was investigated. Two different bacteria, IRB (iron-reducing bacteria) and SRB (sulfate-reducing bacteria) was used, and minerals formed by these bacteria were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Compared to uranyl ions, ferric ions were preferentially reduced by IRB, showing that there is no significant reduction and removal of uranium. However, uranium concentration considerably decreased by addition of Mn(II). Results show that a sulfide mineral such as mackinawite (FeS) is formed by SRB respiration through combination of Fe(II) and S without manganese sulfide formation. In the presence of Mn(II), however, uranium is removed effectively, suggesting that the sorption and incorporation of uranium could be affected by Mn(II) onto the sulide minerals.

Assessment of Monitored Natural Attenuation as Remediation Approach for a BTEX Contaminated Site in Uiwang City (의왕시내 BTEX 오염 부지에서의 자연 정화법 이용 적합성 고찰)

  • 이민효;윤정기;박종환;이문순;강진규;이석영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.04a
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    • pp.149-156
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    • 1999
  • In the United States (U.S.), the monitored natural attenuation (MNA) approach has been used as an alternative remedial option for organic and inorganic compounds retained in soil and dissolved in groundwater. The U.S. Environmental Protection Agency (EPA) defines the MNA as“in-situ naturally-occurring processes include biodegradation, diffusion, dilution, sorption, volatilization, and/or chemical and biochemical stabilization of contaminants and reduce contaminant toxicity, mobility or volume to the levels that are protective of human health and the environment”. The Department of Soil Environment. National Institute Environmental Research (NIER) is in the process for demonstrating the MNA approach as a potential remedial option for the BTEX contaminated site in Uiwang City. The project is charactering the research site in terms of the nature and extend of contamination, biological degradation rate, and geochemical and hydrological properties. The microbial-degradation rate and effectiveness of nutrient and redox supplements will be determined through laboratory batch and column tests. The geochemical process will be monitored for determining the concentration changes of chemical species involved in the electron transfer processes that include methanogenesis, sulfate and iron reduction, denitrification, and aerobic respiration. Through field works, critical soil and hydrogeologic parameters will be acquired to simulate the effects of dispersion, advection, sorption, and biodegradation on the fate and transport of the dissolved-phase BTEX plume using Bioplume III model. The objectives of this multi-years research project are (1) to evaluate the MNA approach using the BTEX contaminated site in Uiwang City, (2) to establish a standard protocol for future application of the approach, (3) to investigate applicability of the passive approach as a secondary treatment remedy after active treatments. In this presentation, the overall picture and philosophy behind the MNA approach will be reviewed. Detailed discussions of the site characterization/monitoring plans and risk-based decision-making processes for the demonstration site will be included.

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Protaetia brevitarsis extract ameliorates the severity of DSS-Induced Ulcerative Colitis in vivo (굼벵이 추출물의 DSS유도 궤양성 대장염 조절효능 탐색)

  • Park, Bog-Im;Jeon, Yong-Deok;Sim, Hyeon-Jae;Lee, Hoon-Yeon;Kim, Seong-Oh;kim, Dong-Keun;Jo, Mi-Na;Cho, Yong-Jin;Kim, Chong-Tai;Kim, Tae-Eun;Jin, Jong-Sik
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.04a
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    • pp.122-122
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    • 2019
  • Protaetia brevitarsis (PB) extracts has been traditionally used as medicinal stuff to treat blood stasis, occlusion of menstruation, tetanus and liver cancer in Asian countries (Korea, Japan, China, Taiwan, India and Myanmar). Especially, Donguibogam, which is traditional korean medicinal book, described the PB extracts as traditional medicine to treat hepatic diseases and vascular disorders. The PB extracts has been considered as highly nutritional food. The major constituents of PB extracts are rich in protein, healthy fats, iron, calcium. Recent studies announced that PB extracts has hepatoprotective effect and anti-microbacterial effect. However, the effect of PB on ulcerative colitis has not been uncovered yet. The aim of this study was to examine the anti-inflammatory effect of PB extracts in dextran sulfate sodium (DSS)-induced colitis mice model. Cytotoxicity of PB was determined by MTT assay and the antiinflammatory effect of PB extract was investigated by measuring nitric oxide (NO) production. PB extracts did not show any cytotoxicity. AIso, PB extracts supressed NO production in LPS-stimulated mice peritoneal macrophages. To determine whether PB could be an effective treatment on ulcerative colitis, DSS was administered in BALB/c mice for 10 days. PB extract significantly improved the clinical signs of DSS-induced UC, including body weight loss, colon length shortening, and disease activity index increase, with histological markers of colon injury. These findings indicated the possibility of PB as a therapeutic agent on ulcerative colitis.

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