• Journal of Information Display
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• v.3 no.1
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• pp.6-10
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• 2002

We have synthesized a new green Ir(III) complex fac-tris-(3-methyl-2-phenyl pyridine)iridium(III) $Ir(mpp)_3$ and fabricated phosphorescent polymer light-emitting device using it as a triplet emissive dopant in PVK. $Ir(mpp)_3$ showed absorption centered at 388 nm corresponding to the $^1MLCT$ transition as .evidenced by its extinction coefficient of the order of $10^3{\cdot}$ From the PL and EL spectra of the $Ir(mpp)_3$ doped PVK film, the emission maximum was observed at 523 nm, due to the radiative decay from the $^3MLCT$ state to the ground state, confirming a complete energy transfer from PVK to $Ir(mpp)_3$. The methyl substitution has probably caused a red shift in the absorption and emission spectrum compared to $Ir(mpp)_3$. The device consisting of a 2 % doped PVK furnished 4.5 % external quantum efficiency at 72 $cd/m^2$ (current density of 0.45 $mA/cm^2$ and drive voltage of 13.9 V) and a peak luminance of 25,000 $cd/m^2$ at 23.4 V (494 $mA/cm^2$). This work demonstrates the impact of the presence of a methyl substituent at the 3-position of the pyridyl ring of 2-phenylpyridine on the photophysical and electroluminescence properties.

• Bulletin of the Korean Chemical Society
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• v.24 no.10
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• pp.1521-1524
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• 2003

• Elastomers and Composites
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• v.36 no.3
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• pp.177-187
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• 2001

Polypropylene(PP)/polyurethane(PU) blends with reactive compatibilizers were prepared by the compositional quenching process. Maleic anhydride grafted PP(MPP) and hydroxyethyl maleimide grafted PP(HPP) were introduced as reactive compatibilizers. The formation of HPP and the reactions of compatibilizers with the PU components were confirmed by FT-IR spectroscopy. The morphology, tensile properties, thermal stability, and surface property were studied. The blends prepared by the compositional quenching showed better dispersed domain morphology than the melt blends. The PU domain size became more uniform and reduced in size with increasing the amount of compatibilizers. The blends with HPP showed sightly smaller domain sire than the blends with MPP. The blends with compatibilizers all showed improved tensile properties, surface property. and thermal stability due to the interfacial adhesion effect. The blends with MPP showed higher surface energy than the blends with HPP, but the latter showed better thermal stability compared to the former.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.293-294
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• 2012

백색 OLED 조명 분야에서 색 변환은 큰 이슈가 되고 있다. 하지만 청색 유기물의 발광 특성이 좋지 못하여 아직까지 정착이 되지 못하고 있는 것이 현실이다. 본 연구에서는 발광 효율이 낮은 청색 OLED 대신 청색 LED와 황색 OLED를 사용하여 색 변환을 통한 백색 발광 panel을 제조하고 전기 및 광학적 특성을 평가하였다. 먼저 OLED소자는 진공증착방법을 사용하여 ITO (150 nm)/KHI-001 (5 nm)/LG-101 (10 nm)/KHT-001 (25 nm)/ PGH-02 (25 nm): Ir (mpp) 3 (8%): PRD-003 (0.3%)/TMM-004 (10 nm)/LG-201 (20 nm): LiQ (50%)/Al (150 nm) 구조를 갖는 발광면적 $70{\times}70mm^2$의 황색 OLED panel을 제작하였다. CIE 1931색좌표는(0.49, 0.49)이고, 효율은 $41.61{\ell}m/W$이다. 그리고 LED는 청색 칩을 한 줄로 나열하여 LED bar를 만들었고 여기에 도광판, 리버스 프리즘시트, 확산시트 그리고 반사시트를 더하여 점광원을 면광원화 하였다. CIE 1931색좌표가 (0.15, 0.04)이며 효율은 $3.56{\ell}m/W$이다. 황색 OLED를 청색 LED 면광원 뒤에 붙여서 두 빛이 도광판 위쪽으로 나오게 하였다. 이렇게 hybrid된 빛은 인가 전류를 변화 시킴으로써 색온도 3,200 K의 warm white에서 7,800 K의 cool white까지 변환이 가능하였다. 그리고 순백의 hybrid 빛을 얻을 수 있었는데 이때의 색온도는 4200K이고 CIE 1931색좌표는(0.34, 0.33)이며 연색지수는 89였다.