• Title/Summary/Keyword: Iptycene

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Synthesis of Fluorescent Thiophene-derivatized Pentytiptycenes and Their Aggregate Behaviors

  • Song, Jinwoo
    • Journal of Integrative Natural Science
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    • v.3 no.1
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    • pp.28-32
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    • 2010
  • Thiophene-derivatized pentiptycenes were synthesized and characterized by NMR and UV-Vis spectroscopy. Aggregation behavior of thiophene-derivatized pentiptycenes was monitored by the measurement of fluorescence. Fluorescence intensities for the thiophene-derivatized pentiptycenes and thiophene-derivatized pentiptycenes aggregates were compared. There is no shift in the maximum of the emission wavelength. In the range of water fraction between 20% and 40%, the emission intensity of thiophene-derivatized pentiptycene aggregates remains almost identical. Fluorescence efficiency incresaed by about 5 times higher when the thiophene-derivatized pentiptycenes forms the aggregates in solution.