• Journal of Soil and Groundwater Environment
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• v.17 no.1
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• pp.13-21
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• 2012

This study reports a surfactant-enhanced in-situ remediation treatment at a test site which is located in a hilly terrain. The leakage oils from a storage tank situated on the top of the hill contaminated soils and groundwater in the lower elevation. Sixteen vertical injection wells (11 m deep) were installed at the top of the hill to introduce 0.1-0.5 vol.% of non-ionic Tween-80 surfactant. The contaminated area that required remediation treatment was about $1,650\;m^2$. Two cycles of injecting surfactant solution followed by water were repeated over approximately 7.5 months: first cycle with 0.5 month of surfactant injection followed by 3 months of water injection, and second cycle with 1 month of surfactant followed by 3 months of water injection. The seasonal fluctuation in groundwater table was also considered in the selection of periods for surfactant and water injection. The results showed that the initial Total Petroleum Hydrocarbon (TPH) concentration of 1,041 mg/kg (maximum 3,605 mg/kg) was reduced significantly down to 76.6 mg/kg in average. After 2nd surfactant injection process finished, average TPH concentration of soils was reduced to 7.5% compared to initial concentration. Also, average BTEX concentration of soils was reduced to 10.8%. This resultes show that the surfactant enhanced in-situ remediation processes can be applicable to LNAPL contaminated site in field scale.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.111.1-111.1
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• 2012

Interest in flexible transparent conducting films (TCFs) has been growing recently mainly due to the demand for electrodes incorporated in flexible or wearable displays in the future. Indium tin oxide (ITO) thin films, which have been traditionally used as the TCFs, have a serious obstacle in TCFs applications. SWNTs are the most appropriate materials for conductive films for displays due to their excellent high mechanical strength and electrical conductivity. In this work, the fabrication by the spraying process of transparent SWNT films and reduction of its sheet resistance on PET substrates is researched Arc-discharge SWNTs were dispersed in deionized water by adding sodium dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWNT was spray-coated on PET substrate and dried on a hotplate. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then was doped with Au-ionic doping treatment, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. This was confirmed and discussed on the XPS and UPS studies. We show that 87 ${\Omega}/{\Box}$ sheet resistances with 81% transmittance at the wavelength of 550nm. The changes in electrical and optical conductivity of SWNT film before and after Au-ionic doping treatments were discussed. The effect of Au-ion treatment on the electronic structure change of SWNT films was investigated by Raman and XPS.

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.597-604
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• 2003

In the soil washing process, the contaminants are usually removed by abrasion from soil particles using mechanical energy and water However, organic contaminants with low water solubility like polycyclic aromatic hydrocarbons (PAH) are remained on soil particles. Previous studies have shown that surfactant possessing amphipathic activity enhances the solubility of organic materials. For this reason solutions with surfactants have been used to improve removal of organic contaminants on soil washing process. But, in this manner, many problems were found like complete loss of surfactants and additional contamination by surfactant. The remediation method using microemulsion has been introduced to overcome these disadvantages. In this case, surfactants are recycled by phase separation of microemulsion after remediation. In microemulsion process, the surfactant will be recycled by phase separation of the microemulsion into a surfactant-rich aqueous phase and an oil phase after extraction. That is why remediation concept applying microemulsion as washing media has been Introduced. Suitable microemulsion have to be used in order to have the chance of refilling the soil after decontamination and to avoid any risk due to toxicity. The purpose of this research is to evaluate effect of microemulsion to remediation of contaminated soil. We performed test with various organic contaminants like Pyrene and BTEX, also compared efficiency of remediation in microemulsion process with soil washing

• Fire Science and Engineering
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• v.16 no.3
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• pp.61-70
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• 2002

A fire extinguishing agent containing non-ionic surfactant which is environmentally friendly and low cost was prepared and tested its characteristics and fire fighting performance. Ethoxylated sorbitol septaoleate, containing 40 moles of ethylene oxide as the primary surfactant, linear ethoxylated secondary alcohol, containing 7-11 moles ethylene oxide as the secondary surfactant, and ethoxylated sorbitol trioleate, containing 40-50 moles of ethylene oxide were used in the agent. It is demonstrated that the water solution containing 6 wt％ agent is capable to extinguish gasoline fire when it is put into the fire four times as much as gasoline. According to the field test of class B fire with a unit 1, it is found that the fire fighting performance is directly proportional to the concentration of surfactant in the agent.

• Journal of the Korean Chemical Society
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• v.58 no.4
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• pp.351-358
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• 2014

Anionic (sodium lauryl sulphate, NaLS) cationic (cetyl ammonium bromide, CTAB) and non-ionic (Tween-80) surfactants have been found to inhibit the rate of oxiadation L-proline and L-methionine by alkaline $KMnO_4$. A first order dependence of rate of oxidation was observed with respect to $MnO_4{^-}$. The order of reaction in substrate and alkali was found to be fractional nearby 0.65 and 0.55 in Aminoacid and $OH^-$, respectively. An aggregation/association between $MnO_4{^-}$ and surfactant has been confirmed spectrophotometrically. A mechanism, involving kinetically inactive [$MnO_4{^-}$ surfactant] aggregate and consistent with kinetic data, has been proposed. The effect of surfactants has been discussed in terms of hydrophobic and electrostatic interactions.

• KSBB Journal
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• v.16 no.3
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• pp.241-245
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• 2001

Mass transfer rates have been measured for the extraction of enzyme from aqueous solution into a reverse-micelle phase at $25^{\circ}C$. The 420 mL vessel was carefully designed to maintain a planar interface between the aqueous and solvent phases, so allowing precise measurement of interfacial area, has been investigated. Sodium di-2-ethylhexyl sulfosuccinate(AOT) was the surfactant used. Factors varied included: agitator speed, pH, ionic strength and surfactant concentration. Samples were taken from the solvent phase at 15min intervals, and the amount of enzyme extracted was measured by UV absorption at 280 nm. The observed Sherwood numbers for the aqueous phase $Sh_1$were correlated interms of the aqueous phase Reynolds number $Re_1$, and modified Schmidt number $Sc_1$. $Sh_1=0.664Re_1^{0.5}Sc_1^{0.33}$

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2000.10a
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• pp.653-655
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• 2000

Alumina-surfactant mesostructures have been synthesized with the $Al_{13}$-Keggin cation prepared by Al(N $O_3$)$_3$.9$H_2O$ solution with NaOH solution in the presence of a non-ionic surfactant at room temperature. The synthesized samples had the hexagonal structure similar to MCM-41 type materials. These samples have been characterized by X-ray diffraction and thermal analysis(TG). The samples prepared from OH/Al ratio 1.5 and 2.0 were well-crystalline mesostructures, but the sample from OH/Al ratio 2.5 was not. Also, The d$_{100}$ value decreased slightly from 38 to 36 according to the OH/Al mole ratio. These results could be explained that Keggin ion depended on the OH/Al molar ratio and pHpH

• Proceedings of the KSEEG Conference
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• 2007.04a
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• pp.497-497
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• 2007

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• Fashion & Textile Research Journal
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• v.11 no.3
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• pp.469-473
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• 2009

Recently, eco-friendly processing has been focused in the textile industry in order to reduce environmental pollutions. Applications of enzyme technology to the textile industry are an example of more environmentally compatible processes. However, there is not enough quantity of referring to denim fabric subjected to enzymatic treatment. In this study, depending on pH, temperature, cellulase concentration, and treatment time, the weight loss of denim fabrics was examined. Characteristics of enzyme-treated fabrics were measured by tearing strength, stiffness, and K/S values. The effect of a non-ionic surfactant (Triton X-100) on characteristics of the enzyme-treated fabrics was evaluated. The cellulase treatment condition on the cotton fabric were optimized to pH 6.0, $50^{\circ}C$, 1%(o.w.f.), and 60minutes. Characteristics of denim fabrics by cellulase treatment in the presence of Triton X-100 did not improve because Triton-X inhibited the activity of enzyme.

• Journal of Pharmaceutical Investigation
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• v.28 no.1
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• pp.43-50
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• 1998

Niosomes are vesicles formed from synthetic non-ionic surfactants, offering an alternative to chemically unstable and expensive liposomes as a drug carrier. Non-ionic surfactant and cholesterol mixture film leads to the formation of vesicular system by hydration with sonication method. The formation of niosome was ascertained by negative staining of TEM. The entrapment efficiency of niosomal suspension was gradually increased with increasing the ratio of cholesterol to surfactant. It was found that the niosome with 6 : 4 (polyoxyethylene 2-cetyl ether: cholesterol) ratio was more stable than those with other ratios. The topical application of acyclovir(ACV) in the treatment of herpes simplex virus type 1(HSV-1) skin disease has a long history. There are an increasing number of reports, however, in which topical ACV therapy is not as effective as oral administration. Lack of efficacy with topical ACV has been hypothesized to reflect the inadequate delivery of drug to the skin. We investigated the permeation of niosome containing $[^{3}H]ACV$ in hairless mouse skin using Franz diffusion cell model. Permeation coefficient(P) of aqueous ACV was $6.7{\times}10^{-4}\;(cm/hr)$ and that of ACV in niosome was $23.4{\times}10^{-4}\;(cm/hr)$, suggesting about 3.5 times increase in the transdermal permeation.