• Korean Chemical Engineering Research
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• 제53권6호
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• pp.814-817
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• 2015

A new ionic mass transfer correlation is derived for the fluid-saturated, horizontal porous layer. Darcy-Forchheimer model is used to explain characteristics of fluid motion. Based on the microscales of turbulence a backbone mass transfer relation is derived as a function of the Darcy-Rayleigh number, $Ra_D$ and the porous medium Schmidt number, $Sc_p$. For the Darcy's limit of $Sc_p{\gg}Ra_D$, the Sherwood number, Sh is a function of $Ra_D$ only. However, for the region of high $Ra_D$, Sh can be related with $Ra_DSc_p$. Based on the present backbone equation and the electrochemical mass transfer experiments which are electro plating or electroless plating, the new ionic mass transfer correlation is suggested in the porous media.

• 한국기계가공학회지
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• 제7권4호
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• pp.24-30
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• 2008

The laminate IPMC actuator have been developed with a commercial Nafion film and platinum electrodes. Equivalent beam and equivalent bimorph beam models for IPMC(Ionic Polymer-Metal Composite) actuators are described. By using a beam equation with estimated physical properities and actuation displacements of a cantilevered IPMC actuator are estimated. And Finite element analysis(FEA) was done by ANSYS.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3709-3714
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• 2013

Based on the Debye-H$\ddot{u}$ckel equation, a semi-empirical equation for activity coefficients was derived through empirical and theoretical trial and error efforts. The obtained equation included two parameters: the proportional factor and the effective radius of an ionic sphere. These parameters were used in the empirical and regression parameter fitting of the calculated values to the experimental results. The activity coefficients calculated from the equation agreed with the data. Transforming to a semi-empirical form, the equation was expressed with one parameter, the ion radius. The ion radius, ${\alpha}$, was divided into three parameters, ${\alpha}_{cation}$, ${\alpha}_{anion}$ and ${\delta}_{cation}$, representing parameters for the cation, anion and combination, respectively. The advantage of this equation is the ability to propose a semi-empirical equation that can easily determine the activity coefficient with just one parameter, so the equation is expected to be used more widely in actual industry applications.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2203-2207
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• 2009

Chemical equilbria of nickel chloride in HCl solution at $25\;{^{\circ}C}$ were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. The necessary thermodynamic properties, such as the equilibrium constant for the formation of Ni$Cl^+$ at zero ionic strength and interaction parameter, were evaluated by applying Bromley equation to the stability constant data reported in the literature. It was found that most nickel exists as $Ni^{2+}$ in HCl solution up to 5 molality HCl. The pH values of Ni$Cl_2-HCl-H_2O$ system at $25\;{^{\circ}C}$ calculated in this study agreed well with the pH values measured by employing pH meter.

• Journal of the Korean Physical Society
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• 제73권12호
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• pp.1873-1878
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• 2018

We have investigated the ionic conductivity and dielectric relaxation in $Li_2B_4O_7$ (LBO) and $Li_2O-B_2O_3-Ta_2O_5$ (LBTO) glasses. The sample was synthesized by using the melt quenching method. The frequency dependence of the electrical data from the LBO and LBTO glasses has been analyzed in the frameworks of the impedance Cole-Cole formalism and the universal power-law representation driven by the modified fractional Rayleigh equation. The potential barriers in the LBO and the LBTO glasses turn out to be the same. Comparing with the dc and ac activation energies of the LBO glass, these energies of the LBTO glass decrease due to the increasing Coulomb interaction of inter-cationic interaction.

• Journal of Microbiology and Biotechnology
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• 제15권4호
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• pp.780-786
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• 2005

The biomass of the brown seaweed, Ecklonia, was used to remove Cr(VI) from wastewater. Previously, Cr(VI) was removed through its reduction to Cr(III) when brought into contact with the biomass. In this study, the effects of ionic strength, background electrolytes, and Cr(III), Ni(II), Zn(II), and Fe(III) on the Cr(VI) reduction were examined. An increased ionic strength inhibited the Cr(VI) reduction. The presence of other heavy metals, such as Cr(III), Ni(II), or Zn(II), only slightly affected the Cr(VI) reduction, while Fe(III) enhanced the reduction. Although the above various parameters could affect the reduction rate of Cr(VI) by Ecklonia biomass, these effects were relatively smaller than those of pH and temperature. In addition, the previously derived rate equation was found to be applicable over a range of ionic strengths and with different background electrolytes. In conclusion, Ecklonia, bioniass may be a good candidate as a biosorbent for the removal of Cr(VI) from wastewaters containing various other impurities, and scale-up to a practical process may be accomplished using the previously derived rate equation.

• 대한금속재료학회지
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• 제46권1호
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• pp.20-25
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• 2008

The ionic equilibira in mixed solutions of cuprous and cupric chloride were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. Required thermodynamic constants and interaction parameters were evaluated from the data reported in the literature. The effect of NaCl and CuCl concentrations on the pH and potential of the mixed solutions was explained in terms of the variation in the concentration of solutes and in the activity of hydrogen ion. The calculated pH values of the mixed solutions agreed well with the measured values. However, the calculated values for the potential of the mixed solutions were lower than the measured values, indicating the necessity of considering the complex formation between cuprous and chloride ion, such as $Cu^2Cl{_4}^{2-}$ and $Cu_3Cl{_6}^{3-}$.

• 한국토양비료학회지
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• 제34권3호
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• pp.213-236
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• 2001

토양용액의 이온조성은 작물의 양분흡수와 밀접한 관계를 가지고 있으며 양분의 이온조성을 추정하기 위하여 많은 모델이 개발되어 사용되고 있다. 토양용액 중 분석되는 양분의 몰농도는 insoluble 이온쌍과 평형을 이루고 있는 soluble 이온과 이온쌍 그리고 complex등의 농도로 간주하고, 양이온과 음이온을 동시에 고려한 양분의 이온조성을 추정하기 위하여 분석된 양분의 몰농도에 따른 선정된 평형식의 평형상수에 대한 conditional equilibrium constant를 구하여 모든 평형식이 만족되는 이온과 이온쌍의 몰농도를 구하는 모델을 설정하였다. 본 모델 이용시 기본적으로 필요한 성분은 pH, Eh, EC, 양이온 8종(K, Ca, Mg, Na, Fe, Mn, Al, $NH_4{^+}$, 음이온 6종(Si, 5, p Cl, $NO_3{^-}$, $HCO_3{^-}$)이며 다른 성분도 추가할 수 있도록 하였다. 토양과 토양용액이 평형조건인 경우 추정된 이온과 이온쌍의 조성과 이에 따른 존재 가능한 침전량과 mineral 종류별 함량을 계산하였다.

• Macromolecular Research
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• 제12권1호
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• pp.26-31
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• 2004

Using gravimetry, we have studied the diffusion of water into sulfonated polystyrene ionomers. Diffusion coefficients were calculated from Fick's equation. The water sorption was found to be dependent on the ion content (3.6-11 mol％) and the nature of the cation (H, Na, Li, or Zn). The sorption kinetics indicates a slight deviation from Fickian behavior. We used the analytical solution of Fick's equation to evaluate the concentration profiles, which are in good agreement with the experimental results.

• 한국환경농학회지
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• 제7권2호
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• pp.96-101
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• 1988

Ionic strength 및 공존(共存) 음(陰)Ion($Cl^-$, $SO^{2-}\;_4$, $ClO^-\;_4$)이 Zeolite에 의(依)한 중금속(重金屬)의 흡착(吸着)에 미치는 영향(影響)을 조사(調査)한 결과(結果)는 다음과 같다. Ionic strength별(別) Zeolite에 의(依)한 Cd, Cu 및 Zn의 흡착등온선(吸着等溫線)은 Freundlich 식(式)에 잘 부합(符合)되었다. Ionic strength가 증가(增加)할수록 중금속(重金屬)의 흡착량(吸着量)은 3종(種)의 서로 다른 음(陰)Ion이 공존(共存)하여도 모두 감소(減少)하는 경향(傾向)이었다. Background salt의 음(陰)Ion 종류별(種類別) 중금속(重金屬) 흡착량(吸着量)은 $ClO^-\;_4>SO^{2-}\;_4>Cl^-$의 순(順)이었으며 흡착평형용액내(吸着平衡溶液內)에서 음(陰)Ion은 Ligand로 작용(作用)하여 중금속(重金屬) Ion들과 Complex를 형성(形成)하는 능력(能力)에 차이(差異)가 있음이 인정(認定)되었다.