• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.814-817
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• 2015

A new ionic mass transfer correlation is derived for the fluid-saturated, horizontal porous layer. Darcy-Forchheimer model is used to explain characteristics of fluid motion. Based on the microscales of turbulence a backbone mass transfer relation is derived as a function of the Darcy-Rayleigh number, $Ra_D$ and the porous medium Schmidt number, $Sc_p$. For the Darcy's limit of $Sc_p{\gg}Ra_D$, the Sherwood number, Sh is a function of $Ra_D$ only. However, for the region of high $Ra_D$, Sh can be related with $Ra_DSc_p$. Based on the present backbone equation and the electrochemical mass transfer experiments which are electro plating or electroless plating, the new ionic mass transfer correlation is suggested in the porous media.

• Journal of Mechanical Science and Technology
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• v.14 no.12
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• pp.1396-1402
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• 2000

Here is investigated the characteristics of double-diffusive convection in thermally-stable stratified horizontal fluid layer. By employing an electrochemical technique, and adopting aqueous CuSO$_4$-H$_2$SO$_4$solution as electrolyte, experiments on ionic mass transfer have been conducted systematically. And, also a new mass transfer correlation in double-diffusive situations has been derived by extending the model of micro-scales of turbulence, which was proposed by Arpaci. The resulting correlation of the Sherwood number as a function of the thermal Rayleigh number was in good agreement with the present experimental results. The present study provides plausible understanding in controlling both mass and heat transfer rates for practical situations including double-diffusive convection.

• Journal of the Korean Electrochemical Society
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• v.2 no.2
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• pp.98-105
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• 1999

In the present study, buoyant force and its stabilizing effects in an electrostatic field were examined systematically in order to reduce the effect of natural convection with thermal stratification in a horizontal fluid-saturated porous layer. The correlation of ionic mass transport induced by double-diffusive convection in a horizontal porous layer has been derived theoretically. And the theoretical model was examined by electrochemical experiments. The theoretical correlation for mass transport which is satisfying Forchheimer's flow equation and based on the micro-turbulence model is derived as a function of soltual Darcy-Rayleigh number, thermal Darcy-Rayleigh number and Lewis number. In the experiment, the mass transport of copper ions in $CuSO_4-H_2SO_4$ solution is measured by electrochemical technique. By assembling theoretical correlation and experimental results, the mass transport correlation induced by double-diffusive convection is proposed as $$Sh=\frac{0.03054(Rs_D-LeRa_D)^{1/2}}{1-3.8788(Rs_D-LeRa_D)^{-1/10}}$$ The present correlation looks flirty reasonable with comparing experimental results, and very promising for the applications of its prototype into various systems involving heat transfer as well as mass transfer, in order to control the effects of natural convection effectively.