• 제목/요약/키워드: Ion diffusion

Search Result 768, Processing Time 0.024 seconds

Properties of Latex Modified Concrete by Binder Content and Effect on Chloride Ion Diffusion (라텍스 개질 콘크리트(LMC)의 결합재량에 따른 배합 및 염화물 이온 확산 특성)

  • Park, Sung-Gi;Won, Jong-Pil;Park, Chan-Gi;Lee, Sang-Woo;Sung, Sang-Kyoung
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.949-952
    • /
    • 2008
  • The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. But it is added in LMC manufacture, which is a high price compares with different material and there is a weak point where the construction expense is very high. So, this study are decided mix proportion from the scope where the security strong point of LMC is possible and reduced the material expense by control the latex contents. and these mix proportions are estimated the chloride ion diffusion. The results of study appear that it can reduced the latex content until the $5{\sim}10$% of cements, and these mixtures are very low chloride ion diffusion.

  • PDF

A Study of Semiconductor Process Simulator with User Friendly Framework (사용자 친숙형 반도체 공정 시뮬레이터의 구성에 관한 연구)

  • 이준하;이흥주
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.5 no.4
    • /
    • pp.331-335
    • /
    • 2004
  • In this paper, we modeling the oxidation, diffusion, and ion-implantation for semiconductor process simulation, and construct the integrated framework for efficient execution and continuous process simulation. For oxidation process, to predict the accurate LOCOS shape and stress distributions, stress-dependent viscous model was performed using SVP algorithm. For diffusion process, predeposition and OED simulation was performed using point defect theory. For ion implantation, Monte-Carlo method based on TRIM simulation was performed with various process conditions. For input to each unit process, we used the dialog boxes which are windows application's standards. This dialog box allows us to verify and minimize input error at input steps. Using the combination of compiler's function and windows's API function, simulation was done with small memory size.

  • PDF

The Effect of Mo Addition on Oxygen Vacancies in the Oxide Scale of Ferritic Stainless Steel for SOFC Interconnects

  • Dae Won Yun;Hi Won Jeong;Seong Moon Seo;Hyung Soo Lee;Young Soo Yoo
    • Corrosion Science and Technology
    • /
    • v.23 no.1
    • /
    • pp.33-40
    • /
    • 2024
  • The concentration and diffusion coefficient of oxide ion vacancies in the oxide scale formed on Fe-22Cr-0.5Mn ferritic stainless steel with and without molybdenum (Mo) was measured at 800℃ by the electrochemical polarization method. After pre-oxidation for 100 h in ambient air at 800 ℃, the oxide scale on one side was completely removed with sandpaper. A YSZ plate was placed on the side where the oxide scale remained. Platinum (Pt) meshes were attached on the top of the YSZ plate and the side where the oxide scale was removed. Changes in electrical current were measured after applying an electrical potential through Pt wires welded to the Pt meshes. The results were interpreted by solving the diffusion equation. The diffusion coefficient and concentration of oxide ion vacancy decreased by 30% and 70% in the specimen with Mo, respectively, compared to the specimen without Mo. The oxide ion vacancy concentration of chromia decreased due to the addition of Mo.

Oxidation Mechanism of $Si_3N_4$ ($Si_3N_4$의 산화반응 기구)

  • 이홍림;최태운;김종우
    • Journal of the Korean Ceramic Society
    • /
    • v.17 no.4
    • /
    • pp.197-202
    • /
    • 1980
  • The oxidation mechanism of the not sintered pellets and sintered bodies of $Si_3N_4$ was investigated. in air over the temperature range of 800~130$0^{\circ}C$. The $\beta$-cristobalite was instantaneously formed and covered the particles of powder packed in the not sintered and weakly sintered porous $Si_3N_4$ bodies by molecular diffusion of oxygen through the porous Si3N4 bodies and an immediate oxidation. The diffusion of oxygen ion through the formed $\beta$-cristobalite surface layer is assumed to control the further oxidation of the $Si_3N_4$ particles of the porous $Si_3N_4$ bodies. The diffusion coefficients and activation energies of oxygen ion through the $\beta$-cristobalite layer were obtained by the use of a derived equation.

  • PDF

Estimation on the Durability of High-Performance Concrete Using Metakaolin (Metakaolin 혼합 고강도 콘크리트의 내구특성 평가)

  • Moon Han Young;Yum Jun Hwan;Moon Su Dong;Lee Sang Ho
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2004.05a
    • /
    • pp.196-199
    • /
    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we tested the compressive strength of concrete according to the substitute ratio of metakaolin, silica-fume. And we did the durability test such as chloride ion diffusion and chemical attack. In the compressive strength test, the result shows that $10\%$ substitute of metakaolin & silica-fume for binder is optimum. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the durability test, we recognized that metakaolin is able to used as a substitute for silica-fume.

  • PDF

A Study on the Flame Structure and NOx Distribution In Coaxial Diffusion Combustor (동축확산연소기 화염구조와 NOx 분포에 관한 연구)

  • Kim, K.S.;Lee, W.S.;Kang, I.G.;Lee, D.H.
    • Journal of the Korean Society of Combustion
    • /
    • v.4 no.2
    • /
    • pp.35-41
    • /
    • 1999
  • The purpose of this study is to establish the flame structure and NOx emission characteristics of the swirl flow coaxial diffusion combustion in the model gas turbine combustor. The mean temperature, ion currents and NOx emission measurement technique showed the effect of equivalence ratio into flame length and flame stability. As a result of this study, NOx emission was increased by increasing the equivalence ratio, and the peak value of the NOx was appeared near the flame front.

  • PDF

Experimental Study of Chlorides Ion Diffusion Characteristics under Combined Condition of Chlorides and Sulfates (염해 및 황산염의 복합작용에 따른 염소이온 확산특성의 실험적 연구)

  • 오병환;김선우;정상화;서정문
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2000.10a
    • /
    • pp.413-418
    • /
    • 2000
  • The test results on the deterioration process of concrete under single and combined action of chloride penetration have been obtained. Within the test period of 15 weeks, it is seen that the internally penetrated chloride ion contents are slightly less in the combined action of NaCI and $Na_2SO_4$ than the single action of NaCI. Also the theoretical prediction of chloride penetration based on measured diffusion coefficient agress well with the test data of single deterioration process but disagress with that of combined process. Therefore it should be needed that improved chloride diffusion model for the combined deterioration process.

  • PDF

Kinetic Monte Carlo Simulations for Defects Diffusion in Ion-implanted Crystalline

  • Jihyun Seo;Hwang, Ok-Chi;Ohseob Kwon;Kim, Kidong;Taeyoung Won
    • Proceedings of the IEEK Conference
    • /
    • 2003.07b
    • /
    • pp.731-734
    • /
    • 2003
  • An atomistic process modeling, Kinetic Monte Carlo simulation, has the advantage of being both conceptually simple and extremely powerful. Instead of diffusion equations, it is based on the definitions of the interactions between individual atoms and defects. Those interactions can be derived either directly from molecular dynamics, first principles calculations, or from experiment. In this paper, as a simple illustration of the kinetic Monte Carlo we simulate defects (self-interstitials and vacancies) diffusion after ion implantation in Si crystalline.

  • PDF

Low Temperature diffusion by Ion Collisions (이온 충돌에 의한 저온 확산)

  • 이희용
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.11 no.1
    • /
    • pp.33-39
    • /
    • 1974
  • A method of dopant implantation by low temperatme diffusion with ion collisions as well as the mechanism of its apparatus is to be introduced. The implantillg function is mainly based on the Principle of radiation enhanced diffusion due to the collisions of low energy Particles and the preheating of the substrate in an environment of rarefied air plasma. The implanted results of various dopants into semicondctors by the Implanter are also presented.

  • PDF

Electrogravimetric and Electrochemical Ac Response of Polypyrrole Films

  • Yang, Haesik;Lee, Hochun;Kwak, Juhyoun
    • Analytical Science and Technology
    • /
    • v.8 no.4
    • /
    • pp.663-668
    • /
    • 1995
  • Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.

  • PDF