• 제목/요약/키워드: Ion core

검색결과 165건 처리시간 0.028초

CdTe/CdHgTe 코어쉘 나노입자를 이용한 P채널 전계효과박막트렌지스터의 전기적특성 (Electrical characteristics of Field Effect Thin Film Transistors with p-channels of CdTe/CdHgTe Core-Shell Nanocrystals)

  • 김동원;조경아;김현석;김상식
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
    • /
    • pp.1341-1342
    • /
    • 2006
  • Electrical characteristics of field-effect thin film transistors (TFTs) with p-channels of CdTe/CdHgTe core-shell nanocrystals are investigated in this paper. For the fabrication of bottom- and top-gate TFTs, CdTe/CrHgTe nanocrystals synthesized by colloidal method are first dispersed on oxidized p+ Si substrates by spin-coating, the dispersed nanoparticles are sintered at $150^{\circ}C$ to form the channels for the TFTs, and $Al_{2}O_{3}$ layers are deposited on the channels. A representative bottom-gate field-effect TFT with a bottom-gate $SiO_2$ layer exhibits a mobility of $0.21cm^2$/ Vs and an Ion/Ioff ratio of $1.5{\times}10^2$ and a representative top-gate field-effect TFT with a top-gate $Al_{2}O_{3}$ layer provides a field-effect mobility of $0.026cm^2$/ Vs and an Ion/Ioff ratio of $2.5{\times}10^2$. $Al_{2}O_{3}$ was deposited for passivation of CdTe/CdHgTe core-shell nanocrystal layer, resulting in enhanced hole mobility, Ior/Ioff ratio by 0.25, $3{\times}10^3$, respectively. The CdTe/CdHgTe nanocrystal-based TFTs with bottom- and top gate geometries are compared in this paper.

  • PDF

수평원통 관에서 선회유동의 공기동 발생에 관한 실험적 연구 (An Experimental Study on the Generation of Air-core with Swirl Flow in a Horizontal Circular Tube)

  • 장태현
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제28권6호
    • /
    • pp.922-930
    • /
    • 2004
  • An experimental investigation was performed to study on the generation of air bubble and air core with swirling flow in a horizontal cicular tube. To determine some characteristics of the flow, 2D PIV technique is employed for velocity measurement in water. The experimental rig is manufactured from an acryl tube. The test tube diameter of 80mm, and a length of 3000mm. The used algorithm is the gray leve cross-correlation method(Kimura et al. 1986). An Ar-ion laser is used and the light from the laser(500mW) passes through a probe to make two-dimensional light sheet. In order to make coded images of the tracer particles on one frame, an AOM(Acoustic-Optical Modulator) is used. The maximum axial velocities showed near the test tube wall at y/D =0.1 and y/D =0.9 along the test tube. The higher Reynolds number increase, the lower axial velocities are showed in the center of the test tube. The air bubbles are generated from Re =10,000 and developed into air core from the recirculating water pump rpm equal 30Hz. The pressure and temperature are measured across the test tube at X/D=3.33.

샌드위치패널심재로 활용한 St/BA 개질 다공성 경량 콘크리트의 특성 (Properties of St/BA Modified Cellular Lightweight Concrete as Sandwich Panel Core)

  • 강내민;노정식;도정윤;문경주;소양섭
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2003년도 학술.기술논문발표회
    • /
    • pp.31-34
    • /
    • 2003
  • Sandwich panel is composed of the facing sheets which support the external load, the cellular core with the low thermal conductivity and the adhesive agent to bond them. The cellular core was produced by binding lightweight cellular aggregates with cement and two types of acrylic base St/BA emulsion were added with a view to improving the workability ion due to high absorption of light weight aggregate and to develope more strength, respectively. This investigation is to comprehend the effect of the addition of two types of St/BA on thermal conductivity, calorific value and exhaustion content of noxious gas in addition re compressive and flexural strength. Flexural strength of the specimen made with St/BA-2 ranged 20kgf/cm2 to 25kgf/cm2 and was about 50% to 100% as high as that of the non-fiber specimen. Thermal conductivity was recorded from 2.0 to 3.0 kcal/mh$^{\circ}C$ and calorific value of St/BA modified specimen was much lower than that of commercial sandwich panel core of EPS and urethane. Careful caution has to be taken because generation of noxious gas such as CO, NO and SO2 tend to increase with addition of polymer cement ratio.

  • PDF

SnO2-CoO/carbon-coated CoO core/shell 나노선 복합체의 합성 및 구조분석 (Synthesis and Characterization of SnO2-CoO/carbon-coated CoO Core/shell Nanowire Composites)

  • 이유진;구본율;안효진
    • 한국분말재료학회지
    • /
    • 제21권5호
    • /
    • pp.360-365
    • /
    • 2014
  • $SnO_2-CoO$/carbon-coated CoO core/shell nanowire composites were synthesized by using electrospinning and hydrothermal methods. In order to obtain $SnO_2-CoO$/carbon-coated CoO core/shell nanowire composites, $SnO_2-Co_3O_4$ nanowire composites and $SnO_2-Co_3O_4$/polygonal $Co_3O_4$ core/shell nanowire composites are also synthesized. To demonstrate their structural, chemical bonding, and morphological properties, field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were carried out. These results indicated that the morphologies and structures of the samples were changed from $SnO_2-Co_3O_4$ nanowires having cylindrical structures to $SnO_2-Co_3O_4/Co_3O_4$ core/shell nanowires having polygonal structures after a hydrothermal process. At last, $SnO_2-CoO$/carbon-coated CoO core/shell nanowire composites having irregular and high surface area are formed after carbon coating using a polypyrrole (PPy). Also, there occur phases transformation of cobalt phases from $Co_3O_4$ to CoO during carbon coating using a PPy under a argon atmosphere.

Designing of a Novel Core-Shell-Structured Co-free Cathode Material with Enhanced Thermal and Structural Stability for Lithium Ion Batteries

  • Shin, Ji-Woong;Nam, Yun-Chae;Son, Jong-Tae
    • 전기화학회지
    • /
    • 제22권4호
    • /
    • pp.172-176
    • /
    • 2019
  • The first commercialized cathode material, $LiCoO_2$, suffers from disadvantages such as high cost and toxicity and also possesses safety problems. The nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material, used as an alternative to $LiCoO_2$, has highly reversible capacity and high energy density. So, the nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material is widely used as an alternative to $LiCoO_2$ due to its highly reversible capacity and high energy density. However, $LiNi_{0.9}Mn_{0.1}O_2$ has several disadvantages as well, such as poor cycle performance and poor thermal instability. To address these problems, we synthesized a new material, $LiNi_{0.5}Mn_{0.5}O_2$, as a shell on the surface of a core to suppress the surface degradation. The new material showed high structural and thermal stabilities and could also maintain a high capacity. The capacity retention of the core-shell cathode (87.7%) was better than that of the core cathode (76.9%) after 50 cycles. Analysis using differential scanning calorimetry revealed that the heat generation in the core-shell cathode ($65.9Jg^{-1}$) was lower than that in the core cathode ($559.7Jg^{-1}$).

융액인상법에 의한 $Y_3Al_5O_{12}$및 Nd : $Y_3Al_5O_{12}$ 단결정육성 (Crystal Growth of $Y_3Al_5O_{12}$ and Nd : $Y_3Al_5O_{12}$ by Czochralski. Technique)

  • 유영문;이영국;박로학
    • 한국결정학회지
    • /
    • 제5권2호
    • /
    • pp.51-66
    • /
    • 1994
  • 융액인상법으로 Y3Al5O12 및 Nd: Y3Al5O12단결정을 육성하였다. 인상속도, 회전속도 및 Nd3+이온의 주입농도가 결정의 품질에 미치는 영향을 분석하였다. 광탄성효과및 화학부식 법을 이용하여 여러가지 종류의 결함을 검출하 고, 육성된 결정의 분광학적 성질과 레이저 기능성을 조사하였다. 양질의 단결정을 육성하기 위한 인상속도는 Nd3+이온의 주입농도에 따라 달라진다. Y3Al5O12단결정은 2∼4mm/hr, Nd3+이온 주입농도가 3.0∼3.5a/o 일때 0.6∼0.5mm/hr,4.Oa/o 이상일 때 04mm/hr 이하가 적당하였다. 회전속도가 27∼60rpm 일때 볼록하고, 80∼100rpm 일 때 오목한 고액계면을 형성하였다. 육성된 결정은 <111> 방위로 성장되었으며 격자상수는 12.Ol7A로 측정되었다. 결함으로서 core, (211)facet 줄무의, 금속입자 함유물, 전위 및 광학적 불균질상이 검출되었다. Y3AlO12단결정에 대한 Nd3+이온의 4준위 레이저 천이과정을 확인하고, 육성된 결정으로부터 직경 4.0mm 길이 63mm크기의 레이저 발진봉을 제조한 후 레이저 공진한 결과 lasing threshould 1.8lJ, slope efficiency 0.49%로 측정되었다.

  • PDF

구형 SiO2@Y2O3: Eu 코어-쉘 복합체 형광체 합성 및 특성 (Synthesis and Characterization of Spherical SiO2@Y2O3 : Eu Core-Shell Composite Phosphors)

  • 송우석;양희선
    • 한국세라믹학회지
    • /
    • 제48권5호
    • /
    • pp.447-453
    • /
    • 2011
  • The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

Ab initio and Vibrational Predissociation Studies on Methylammonium-(Water)4 Complex: Evidence for Multiple Cyclic and Non-cyclic Hydrogen-bonded Structures

  • Kim, Kwang-Yon;Han, Woon-Hui;Cho, Ung-In;Lee, Yuan T.;Boo, Doo-Wan
    • Bulletin of the Korean Chemical Society
    • /
    • 제27권12호
    • /
    • pp.2028-2036
    • /
    • 2006
  • The combined ab initio and vibrational predissociation (VP) spectroscopic studies on methylammonium-$(water)_4$ complex aimed at understanding the hydration behavior of an amphiphilic ion core are described. The ab initio calculations predicted eleven low-energy isomers forming cyclic, tripod, chain, and caged structures, and their relative stabilities, total hydration energies and thermodynamic functions at 298 K and 150 K. The excellent correlation between the observed VP spectra and ab initio spectra for bonded N-H, bonded O-H and free O-H stretches suggested co-existence of five cyclic isomers and two non-cyclic isomers in ion beam at 150 K, consistent with the trends of calculated Gibbs free energies.

Determination of Acetyl-L-carnitine in human plasma by LC-ESI/MS/MS

  • Jang, Moon-Sun;Park, Chang-Hun;Kim, Ho-Hyun;Chang, Kyu-Young;Lee, Ye-Rie;Lee, Hee-Joo
    • 대한약학회:학술대회논문집
    • /
    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
    • /
    • pp.217.3-217.3
    • /
    • 2003
  • Acetyl-L-carnitine, a physiological component of the L-carnitine family, has been proposed for treating Alzheimer's disease in pharmacological doses. Acetyl-L-carnitine and d3-acetylcarnitine (internal standard) were analyzed by electrospray ionization / tandem mass spectrometry (ESI/MS/MS) after derivatization to their butylesters through treatment with butanolic hydrogen chloride. Acetyl-L-carnitine produced a protonated precursor ion at m/z 260 and a corresponding product ion of m/z 85. Analytes were separated on a Capcell Pak C18 (2.0${\times}$150mm, 5 mm). (omitted)

  • PDF

아크방전으로 제조된 나노입자를 이용한 리튬이온전지 음극재료의 연구 (The Research on the Nanoparticles Prepared by Arc-Discharge Method as Anode Materials for Lithium Ion Batteries)

  • 김형조;;김형진;박원조
    • 동력기계공학회지
    • /
    • 제17권1호
    • /
    • pp.104-109
    • /
    • 2013
  • Tin and Tinoxide nanoparticles were prepared by arc-discharge nanopowder process. The negative electrode were fabricated using Tin and Tinoxide nanopower. The microstructure and electrochemistry properties were investigated and compared between Tin and Tinoxide. The oxidation film has microstructure of core/shell type and the shell which was attached around Tin nanoparticle consisted of amorphous $SnO_2$. The shape of Tinoxide nanoparticles was formed with irregular shape in comparison with Tin particle. Initial discharge capcity of Tinoxide electrode possesed about 1000mAh/g, which is about 320mAh/g higher than Tin electrode. Irreversible capacity of Tin electrode is much higher than Tinoxide. The cycle performance of Tinoxide electrode was indicated that is batter than Tin. The Tin negative electrode lost most of capacity after 4 cycle but Tinoxide electrode still retained the capacity. The Tinoxide does show some promise as Li-ion battery anode due to their large reversible capacity at low potentials.