• Title/Summary/Keyword: Ion components

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An Analysis of Long-term Trends in Precipitation Acidity of Seoul, Korea (서울지역 강수 산성도의 장기적인 경향분석)

  • 강공언;임재현;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.1
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    • pp.9-18
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    • 1997
  • Precipitation samples were collected by the wet- only event sampling method from Seoul during September 1991 to April 1995. These samples were analyzed for the concentrations of the major ionic components (N $O_3$$^{[-10]}$ , N $O_2$$^{[-10]}$ , S $O_4$$^{2-}$, C $l^{[-10]}$ , $F^{[-10]}$ , N $a^{+}$, $K^{+}$, $Ca^{2+}$, $Mg^{2+}$, and N $H_4$$^{+}$), pH, and electric conductivity. During the study period, a total of 182 samples were collected, but only 163 samples were used for the data analysis via quality assurance of precipitation chemistry data. The volume-weighted pH was found to be 4.7. The major acidifying species from our precipitation studies were identified to be non-seasalt sulfate (84$\pm$9 $\mu$eq/L) and nitrate (24$\pm$2 $\mu$eq/L) except for chloride. Because the Cl/Na ratio in the precipitation was close to the ratio in seawater. If all of the non-seasalt sulfate and nitrate were in the form of sulfuric and nitric acids, the mean pH in the precipitation could have been as low as 3.7 lower than the computed value. Consequently, the difference between two pH values indicate that the acidity of precipitation was neutralized by alkaline species. The equivalent concentration ratio of sulfate to nitrate was 3.5, indicating that sulfuric and nitric acids can comprise 78% and 22% of the precipitation acidity, respectively. Analysis of temporal trend in the measured acidity and ionic components were also performed using the linear regression method. The precipitation acidity generally showed a significantly decreasing trend, which was compatible with the pattern of the ratio (N $H_4$$^{+}$+C $a^{2+}$)/ (nss-S $O_4$$^{2-}$+N $O_3$$^{[-10]}$ ).).

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Soil Components and Elution Characteristics of Heavy Metals in Sediments of Andong and Imha Reservoir (안동・임하호 저니토의 토양 성분과 중금속 용출 특성)

  • Seo, Eulwon;Kim, Younjung;Baek, Seungcheol
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.4
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    • pp.47-52
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    • 2008
  • In this study, it was analyzed the soil components and elution characteristics of heavy metal ions in sediment samples to examine the effect of sediments embedded in Andong and Imha reservoirs on water quality. Major elements of sediments were shown to be Al, Si, K, and Fe by EDS analysis and major soil components of the collected 6 different sediments were illite (I), kaolinite (Ka), quartz (Q) and feldspar (F). And especially quartz took up a considerable part of sediments by XRD analysis. The total concentrations of Zn, As, Cr, Cu and Pb in sediments of Andong reservoir were relatively higher than those of Imha reservoir. The elution property of heavy metal from sediments had various aspects according to pH. Among the heavy metals in Andong reservoir sediments, As and Zn were significantly eluted at pH 6 compared with the other heavy metals. In the case of the adsorption tests using the sediments, the adsorptive capacities of Zn, Cd and Cu were very weak, on the while those of Pb and Cr were high.

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Characteristics of the inward current and its changes following fertilization in hamster eggs (햄스터 난자에서 관찰되는 내향전류의 성상과 수정후의 변화)

  • Han, Jae-hee;Hong, Seong-geun
    • Korean Journal of Veterinary Research
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    • v.38 no.2
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    • pp.280-289
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    • 1998
  • Voltage-sensitive ion channels contribute to establishment of the cell excitablity and the generation of the cellular function. At hamster oocytes in the primitive stage during developing process, an inward current elicited by voltage pulses was found to be carried mainly by $Ca^{2+}$. Even at present, $Ca^{2+}$ channels serve as the most probable route to pass this inward current but there is no evidence of the presence of this channels in eggs. To date, both the characteristic properties and the physiological role in the early stage of development remain unclear. Here we examined the characteristic properties of the inward current and changes in this currents at unfertilized oocytes, fertilized zygotes and two-cell embryos using whole-cell voltage clamp technique. The inward current carried reportedly by $Ca^{2+}$ was remained following removing external $Ca^{2+}$ but completely abolished by further replacement of impermeants such as tetramethylammonium ion ($TMA^+$) or $choline^+$ instead of $[Na^+]_0$. Tetrodotoxin did not affect on this inward current remained at $[Ca^{2+}]_0$-free condition. Removal of $Na^+$ ion out of the experimental solution clearly decreased the current. After adding 2mM $Ca^{2+}$ to the $Na^+$-free media, the inward current was restored. Interestingly, this current carried by either $Ca^{2+}$ or $Na^+$ was decreased by the reduction of intracellular $Cl^-$ concentration, or by $Cl^-$ channel blockers such as niflumic acid, DIDS and SITS. When $Cl^-$ concentration was lowered without changes in other ionic components, this inward current was reduced. At fertilized oocytes and two-cell embryos, the inward current carried by $Ca^{2+}$ and $Na^+$ was severely reduced. Also $Cl^-$ component could not be observed. From these results, the inward current is composed of $Ca^{2+}$, $Na^+$ and $Cl^-$ component, suggesting that the channel carrying this inward current is not selective specifically to $Ca^{2+}$. During early stage of development, the voltage-sensitive ion current seems not to contribute essentially to the cell cleavage and differentiation. The loss of $Cl^-$ component after fertilization suggests that $Cl^-$ may play a role in maintaining the viability of unfertilized ova.

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Deposition Characteristics of Water-soluble Inorganic Ions in the Iksan Ambient Air during Fall, 2004 (가을철 대기환경 중 수용성 이온성분의 침적특성)

  • Kang, Gong-Unn;Kim, Nam-Song;Jeon, Seon-Bok
    • Journal of Environmental Health Sciences
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    • v.32 no.4 s.91
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    • pp.359-372
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    • 2006
  • In order to investigate the daily deposition characteristics of water-soluble inorganic components in airborne deposit on the Iksan, deposition samples were collected using a deposition gauge from October 16 to November 1, 2004. Deposition samples were collected using two different sampling gauges, a dry gauge and a wet gauge, respectively. To get wet the bottom of wet gauge during the sampling period, the volume of $30{\sim}50ml$ distilled ionized water was added in a wet gauge before the beginning of each deposition sampling. Deposition samples were collected twice a day and analyzed for inorganic water-soluble anions ($Cl^-,\;{NO_3}^-,\;{SO_4}^{2-}$) and cations (${NH_4}^+,\;Na^+,\;K^+,\;Mg^{2+},\;Ca^{2+}$) using ion chromatography. Qualify control and quality assurance of analytical data were checked by the data obtained from reinjection of standard solution, Dionex cross check standard solutions, and random several deposition samples, and measured data was estimated to be reliable. Considering the deposition sample volume, the sampling time, the surface area of sampling container, and the ion concentration measured, the daily deposition amounts for measured ions were calculated in $mg/m^2$. The total daily deposition amounts of all measured ions for dry and wet gauge were $7.5{\pm}2.8$ and $17.7{\pm}4.2mg/m^2$, respectively. A significant increase in deposition amount during rainfall days was observed for both wet gauge and dry gauge, having no difference of deposition amount between in wet gauge and in dry gauge. The mean deposition of all ions measured in this study were higher in wet gauge than in dry gauge because of the surface difference of the sampling container, especially for ${NH_4}^+\;and\;{SO_4}^{2-}$. The mean deposition amounts of ${NH_4}^+\;and\;{SO_4}^{2-}$ in wet gauge were found to be about 10 times and 3 times higher than those in dry gauge, while the rest of the chemical species were equal or a little higher in wet gauge than in dry gauge. Dominant species in dry gauge were ${NO_3}^-\;and\;Ca^{2+}$, accounting for 21% and 28% of the total ion deposition, whereas those in wet gauge were ${SO_4}^{2-}\;and\;{NH_4}^+$, accounting for 19% and 41% of the total ion deposition, respectively.

Behavior Characteristics of Fluoride with pH, Ion Type and Concentration, and Sediment Characteristics in River (pH, 이온종류 및 농도, 퇴적물의 성분에 따른 하천 내 불소의 거동특성)

  • LEE, Dong Min;Joo, Kwang Jin;Choi, ISong;Chang, Kwang Hyeon;Oh, Jong Min
    • Ecology and Resilient Infrastructure
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    • v.5 no.1
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    • pp.19-24
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    • 2018
  • Water quality is affected by the pollutants flowing into rivers since the interaction between water bodies and sediments in various environmental conditions. Especially, accumulation of sediments increases in the stagnant water areas due to a relative long hydrological retention time in the water bodies. Therefore, it is an important factor of water quality to understand characterization of the material behavior in water bodies and sediments. In this study, the objective of the conditional experiments was small and medium sized streams located in Gyeonggi-do. To estimate how the changes of fluoride behavior, depending on the pH, ion type, concentration, and clay contents. The pH results showed a trend that adsorption amount of fluorine decreased and the dissolution of fluorine increased following by pH increasing. The concentration and type of ions results showed that $Cl^-$ and $SO{_4}^{2-}$ ions had no significant effect on the adsorption ability of fluorine, the amount of dissolution was increased because $OH^-$ ion had active competition with fluorine in the reaction. The ingredient of sediment results showed that the amounts of fluoride adsorption and dissolution were reduced in samples, which contain relatively large amounts of Silt and Clay components. This means that the environmental conditions of water bodies greatly affect the adsorption and dissolution of fluoride in the sediments, so that proper management of fluoride in the sediments must precede an understanding of the environmental conditions of the water bodies.

Studies on the Optimum Fermenting Conditions of Dongchimi for Production of Ion Beverage (이온음료 제조를 위한 동치미의 최적 담금 조건에 관한 연구)

  • Ko, Eun-Jung;Hur, Sang-Sun;Park, Man;Choi, Yong-Hee
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.1
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    • pp.141-146
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    • 1995
  • The study was conducted for optimum fermenting conditions of Dongchimi(pony tailed chinese radish kimchi) in production of ion beverage. The changes of pH and total acidity were increased as the temperature increased. Non-volatile organic acids, such as lactic acid, citric acid, malic acid and succinic acid were produced in Dongchimi fermentation. The amount of lactic acid was increased higher, followed by citric acid and malic acid. However succininc acid was produced a little of amount at $0^{\circ}C$. Lactic acid producing bacteria number increased in initial period and then decreased in last period of fermentation. During lactic acid producing bacteria was increased, the amouont of lactic acid was increased. The flavor components were tentatively identified as methyl pentane, ethyl thioethene 2, 3-diazaindolizine, dimethyl disulfide. The optimum fermenting conditions of Dongchimi for production of ion beverage were 24~29 days at $0^{\circ}C$, 9~12dyas at $5^{\circ}C$ and 16~22days at $10^{\circ}C$, respectively.

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A study on breakthrough characteristics of ion exchange bed with H- and ETAH-form resins for cation exchange in NH3 and ETA solution including trace NaCl (미량의 NaCl을 포함하는 NH3 및 ETA 용액에서 H 및 ETAH 형 수지에 대한 이온교환 파과 특성 연구)

  • Ahn, Hyun-Kyoung;Kim, Youn-Su;Park, Byung-Gi;Rhee, In-Hyoung
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.533-544
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    • 2021
  • Ion exchange (IX) performance on the exchanger bed is essentially evaluated for the generation of ultrapure water in electronics and chemical industries and for the corrosion control in nuclear power plants. The breakthrough characteristics of IX bed with multi-component were investigated with both cation- and mixed-IX beds of H- and ETAH-form for four kinds of cation exchange resins by using the combined solution of ethanolamine (ETA) and ammonia (NH3) at trace NaCl. Unlike major components (ETAH+ and NH4+ ), the phenomena of breakthrough and overshooting at bed outlet were not observed by Na+ over the test period (> 3 times theoretical exchange capacity of IX bed). The breakthrough from H-form resin bed was sequentially reached by ETAH+ and NH4+, while the overshooting was observed for ETAH+ at the breakthrough of NH4+. NH4+ was 51.5% higher than ETAH+ in terms of the relative selectivity determined with the width of breakthrough zone. At the increased concentration of Na+ at bed inlet, the selectivity and the overshooting were decreased and increased, respectively. Na+ leakage was higher from ETAH-form resin bed and was not identical for four kinds of cation-exchange resins, which may be reduced by improving the intrinsic property of IX resin.

Pre-leaching of Lithium and Individual Separation/Recovery of Phosphorus and Iron from Waste Lithium Iron Phosphate Cathode Materials (폐리튬인산철 양극재로부터 리튬의 선침출 및 인과 철의 개별적 분리 회수 연구)

  • Hee-Seon Kim;Boram Kim;Dae-Weon Kim
    • Clean Technology
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    • v.30 no.1
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    • pp.28-36
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    • 2024
  • As demand for electric vehicles increases, the market for lithium-ion batteries is also rapidly increasing. The battery life of lithium-ion batteries is limited, so waste lithium-ion batteries are inevitably generated. Accordingly, lithium was selectively preleached from waste lithium iron phosphate (LiFePO4, hereafter referred to as the LFP) cathode material powder among lithium ion batteries, and iron phosphate (FePO4) powder was recovered. The recovered iron phosphate powder was mixed with alkaline sodium carbonate (Na2CO3) powder and heat treated to confirm its crystalline phase. The heat treatment temperature was set as a variable, and then the leaching rate and powder characteristics of each ingredient were compared after water leaching using Di-water. In this study, lithium showed a leaching rate of approximately 100%, and in the case of powder heat-treated at 800 ℃, phosphorus was leached by approximately 99%, and the leaching residue was confirmed to be a single crystal phase of Fe2O3. Therefore, in this study, lithium, phosphorus, and iron components were individually separated and recovered from waste LFP powder.

Studies on Constituents of the Higher Fungi of Korea (XLVI) -Antitumor Components Extracted from the Cultured Mycelia of Lyophyllum decastes-

  • Kim, Hye-Ryoung;Shim, Mi-Ja;Kim, Jung-Woo;Kim, Ha-Won;Lee, Chong-Ock;Choi, Eung-Chil;Kim, Byong-Kak
    • Korean Journal of Pharmacognosy
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    • v.15 no.2
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    • pp.61-73
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    • 1984
  • To investigate antitumor component of Lyophyllum decastes, the aqueous extract of its shake-cultured mycelia was subjected to antitumor test against sarcoma 180 cells implanted in ICR mice. The extract showed an inhibition ratio of 65.4% and was found to consist of a polysaccharide moiety and a protein moiety. After purification with DEAE-Sephadex A-50 ion exchange chromatography, Fraction D showed the highest inhibition ratio of 75.7%. The antitumor constituent was examined for immunoaccelerating activity and was found to increase macrophage accumulation in the peritoneal cavity and plaque forming cells of the spleen cells. It was named lyophyllan after the genus name.

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The Hypersensitive Response. A Cell Death during Disease Resistance

  • Park, Jeong-Mee
    • The Plant Pathology Journal
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    • v.21 no.2
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    • pp.99-101
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    • 2005
  • Host cell death occurs during many, but not all, interactions between plants and the pathogens that infect them. This cell death can be associated with disease resistance or susceptibility, depending on the nature of the pathogen. The most well-known cell death response in plants is the hypersensitive response (HR) associated with a resistance response. HR is commonly regulated by direct or indirect interactions between avirulence proteins from pathogen and resistance proteins from plant and it can be the result of multiple signaling pathways. Ion fluxes and the generation of reactive oxygen species commonly precede cell death, but a direct involvement of the latter seems to vary with the plant-pathogen combination. Exciting advances have been made in the identification of cellular protective components and cell death suppressors that might operate in HR. In this review, recent progress in the mechanisms by which plant programmed cell death (PCD) occurs during disease resistance will be discussed.