• Title/Summary/Keyword: Ion balance

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Water Soluble Ionic Components in Precipitation at ChungNam West-Coast Area (충남 서해안지역 강수 중 수용성 이온 성분의 변화특성)

  • 정진도;이천호
    • Journal of Environmental Science International
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    • v.12 no.12
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    • pp.1285-1292
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    • 2003
  • This study was compared each ingredient's local/seasonal change characteristics by analyzing anions and cations, watersoluble ionic components, from the precipitation of Dangjin and Anmyeon-do areas. The samples were collected for 8 months from both spots between the period of April 1, 2002 to November 31, 2002. The precipitation samples were collected continuously through the entire duration of precipitation by using the wet-only automatic samplers. When rain continues to fall over 24 hours or occasionally, we considered those collected from 9 o'clock in the morning for 24 hours as the day's samples. As a method to verify for the reliability of the analyzed data is concerned, we use the ion balance method and the electricity conductance method, was used widely as a way of watching the atmosphere by the WMO(World Meteorological Organization)/GAW (Global Atmosphere Watch). Also, Dangjin and Anmyun-do area confirmed that contains artificial pollutants by analysis of ion concentration data.

Chemical Composition of Respirable PM2.5 and Inhalable PM10 in Iksan City during Fall, 2004 (익산지역 가을철 대기 중 호흡성 및 흡입성 먼지입자의 화학조성)

  • Kang, Gong-Unn
    • Journal of Environmental Health Sciences
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    • v.36 no.1
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    • pp.61-71
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    • 2010
  • Intensive measurements of airborne respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were conducted in the downtown area of Iksan city. The $PM_{2.5}$ and $PM_{2.5}$ samples were collected twice a day in the Iksan city of Korea from October 17 to November 1, 2004. The purpose of the study was to determine the inorganic water-soluble components and trace elements of $PM_{2.5}$ and $PM_{2.5}$ in the atmospheric environment and estimate the contribution rate of major chemical components from a mass balance of all measured particulate species. The chemical analysis for PM samples was conducted for water-soluble inorganic ions using ion chromatography and trace elements using PIXE analysis. The mean concentrations of respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were $51.4{\pm}29.7$ and $79.5{\pm}39.6\;{\mu}g/m^3$, respectively, and the ratio was 0.62. The ion species of $NO_3$, $SO_4^2$, and $NH_4^+$ were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These components predominated in respirable $PM_{2.5}$ fraction, while $Na^+$, $Mg^{2+}$, $Ca^{2+}$ mostly existed in coarse particle mode. Elemental components of S, Cl, K, and Si were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These elements, except for Si, were considered to be emitted from anthropogenic sources, while Si, Al, Fe, Ca existed mainly in coarse particle mode and were considered to be emitted from crustal materials. The averaged mass balance analysis showed that ammonium nitrate, ammonium sulfate, crustal component, and other trace elements were composed of 18.4%, 13.2%, 4.8%, 3.5% for PM2.5 and 17.0%, 11.6%, 13.7%, 4.4% for $PM_{2.5}$, respectively.

Variation Characteristics of TSP Ionic Compositions by Meteorological Phenomena in Jeju Island (기상현상에 따른 제주지역 TSP의 이온조성 변화 특성)

  • Ko, Hee-Jung;Kim, Won-Hyung;Lee, Seung-Hoon;Bu, Jun-Oh;Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.723-733
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    • 2011
  • The ionic compositions were analyzed from the TSP samples collected at Gosan site in Jeju Island between 2000 and 2008, in order to examine the characteristics of atmospheric aerosols in accordance with the meteorological conditions. For the Asian Dust influence on the ionic compositions, the concentration ratios of $NH_4{^+}$, nss-${SO_4}^{2-}$, $NO_3{^-}$, and $K^+$ were about 1.2~2.3 during Asian Dust over Non-Asian Dust periods, noticeably that of nss-$Ca^{2+}$ was 6.8. Meanwhile the concentrations of nss-${SO_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ have increased as 1.8~4.4 times during the haze event periods, and 1.0~1.6 times during the fog and mist events. The ion balance has resulted that the anionic concentrations are relatively lower than the cationic concentrations, and the discrepancy appears more decidedly as a strong Asian Dust effect. The ammonium ion balance has shown that it exists as a mixture of $NH_4HSO_4$ and $(NH_4)_2SO_4$. The concentration ratios of nss-${SO_4}^{2-}/NO_3{^-}$ for Asian Dust, haze, fog-mist, and non-event periods were respectively 1.8, 5.9, 4.6, and 2.9, which were higher values compared to those in urban areas of China as well as other domestic regions. Especially, the high ratios of sulfur oxides could be presumed by the fact that the longrange transport of air pollutants from Asia continent might affect the atmospheric aerosols of Jeju Island.

Development of a Fast Charging System Utilizing Charge Profile and Cell Balance Control Technology for Large Capacity Lithium-ion Batteries (충전 프로파일 및 셀 밸런스 제어기술을 활용한 대용량 리튬이온 배터리 고속충전시스템 개발)

  • Yunana, Gani Dogara;Ahn, Jae Young;Park, Chan Won
    • Journal of Industrial Technology
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    • v.40 no.1
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    • pp.7-12
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    • 2020
  • Lithium-ion cells have become the go-to energy source across all applications; however, dendritic growth remains an issue to tackle. While there have been various research conducted and possible solutions offered, there is yet to be one that efficiently rules out the problem without, however, introducing another. This paper seeks to present a fast charging method and system to which lithium-ion batteries are charged while maintaining their lifetime. In the proposed method, various lithium cells are charged under multiple profiles. The parameters of charge profiles that inflict damage to the cell's electrodes are obtained and used as thresholds. Thus, during charging, voltage, current, and temperature are actively controlled under these thresholds. In this way, dendrite formation suppressed charging is achieved, and battery life is maintained. The fast-charging system designed, comprises of a 1.5kW charger, an inbuilt 600W battery pack, and an intelligent BMS with cell balancing technology. The system was also designed to respond to the aging of the battery to provide adequate threshold values. Among other tests conducted by KCTL, the cycle test result showed a capacity drop of only 0.68% after 500 cycles, thereby proving the life maintaining capability of the proposed method and system.

Miniature planar stack using the flexible Printed Circuit Board as current collectors (연성 기판을 전류 집전체로 사용한 평판형 연료전지 스택)

  • Kim, Sung-Han;Cha, Hye-Yeon;Miesse, Craig M.;Cha, Suk-Won;Jang, Jae-Hyuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.1-4
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    • 2008
  • Fuel cells have the potential of providing several times higher energy storage densities than those possible using current state-of-the-art lithium-ion batteries, but current energy density of fuel cell system is not better than that of lithium-ion batteries. To achieve the high energy density, volume and weight of fuel cell system need to be reduced by miniaturizing system components such as stack, fuel tank, and balance-of-plant. In this paper, the thin flexible PCB (Printed circuit board) is used as a current collector to reduce the stack volume. Two end plates are made from light weight aluminum alloy plate. The plate surface is wholly oxidized through the anodizing treatment for electrical insulation. The opening rate of cathode plate hole is optimized through unit cell performance measurement of various opening rates. The performances are measured at room temperature and ambient pressure condition without any repulsive air supply. The active area of MEA is 10.08 $cm^2$ and active area per a unit cell is 1.68 $cm^2$. The peak power density is about 210 mW/$cm^2$ and the air-breathing planar stack of 2 Wis achieved as a small volume of 18 cc.

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Biological Characterization of the Chemical Structures of Naturally Occurring Substances with Cytotoxicity

  • Park, Hee-Juhn;Jung, Hyun-Ju;Lee, Kyung-Tae;Choi, Jong-Won
    • Natural Product Sciences
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    • v.12 no.4
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    • pp.175-192
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    • 2006
  • Screening for the cytotoxicity from plant origin is the first stage for anti-cancer drug development. A variety of terpenoids with exomethylene, epoxide, allyl, $\alpha,\beta-unsaturated$ carbonyl, acetylenes, and $\alpha-methylene-\gamma-lactone$ induces apoptosis and/or differentiation as well as cytotoxicity through the ROS signal transduction pathways. These are found among monoterpenes, sesquiterpenes, triterpenes, flavonoids, coumarins, diarylheptanoids, and even organosulfuric compounds. The most essential characteristics of natural cytotoxic substances is to possess the strong electrophilicity that is susceptible to nucleophilic biomolecules in the cell. Thiol-reductants and superoxide dismutase can block or delay apoptosis. Thus, ROS and the resulting cellular redox-potential changes can be parts of the signal transduction pathway during apoptosis. Disturbance of the balance of oxireduction by the pigment of natural quinones also caused the induction of the differentiation and apoptosis. Saponins with the cytotoxicity are restricted to their monodesmosides, rather than to bisdesmosides. Those saponins exhibited calcium ion-mediated apoptosis in addition to cytotoxicity whereas they showed also differentiation without extracellular calcium ion. The properties on cytotoxicity, apoptosis, and differentiation were assumed to depend on resultant oxidative stress to the cells. In this review, we describe a spectrum of cytotoxic compounds with various action mechanisms.

Characteristics of Ionic Composition of Rainwater in Suwon (수원지역 빗물의 이온 조성)

  • Lee, Jong-Sik;Jung, Goo-Bok;Kim, Jin-Ho;Kim, Won-Il;Lee, Jeong-Taek
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.2
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    • pp.151-155
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    • 2007
  • The issue of acid precipitation and related environmental problems in East Asia have been emerging. To evaluate the acidity and chemical characteristics of rainwater in Korea, its chemical properties during crop cultivation season from April to October were investigated at Suwon, Korea. Also, to estimate the contribution of ions on its acidity, ion composition characteristics and neutralization effects by cation ions were determined. Ion balance and electrical conductivity balance between the measured and estimated values showed high correlation. Rainwater had distributed highly in the range of pH 4.5~5.6. The pH of rainwater was relatively high at June as compared with other monitoring periods. $Na^+$ was the main cation followed by $NH_4{^+}$, $Ca^{2+}$, $H^+$ > $K^+$ > $Mg^{2+}$. Among these, $Na^+$, $NH_4{^+}$, $Ca^{2+}$ and $H^+$ covered over 93% of total cations. About 86% of anion in rainwater was composed of $SO{_4}^{2-}$ and $NO_3{^-}$. In rainwater samples, $NH_4{^+}$ and $Ca^{2+}$ contributed greatly to neutralization of the rain acidity. Also, 88% of soluble sulfate in rainwater was nss-$SO{_4}^{2-}$(non-sea salt sulfate).

Effects of Dietary Electrolyte Balance on Growth Performance, Nitrogen Metabolism and Some Blood Biochemical Parameters of Growing Rabbits

  • Li, J.W.;Wang, X.P.;Wang, C.Y.;Zhu, Y.L.;Li, F.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.12
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    • pp.1726-1731
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    • 2013
  • The effects of different dietary electrolyte balance (DEB) on growth performance, nitrogen (N) metabolism and some blood biochemical parameters were investigated in 2 to 3 months old growing rabbits. A total of 150 growing rabbits of 2 months age were randomly divided into five groups according to average body weight, with 30 rabbits in each group. The DEB levels of the five experimental diets were -154, -3.16, +201, +347, and +500 meq/kg of dry matter (DM), respectively. There was a 7-d adaptation period and a 23-d experimental period. The results showed that the DEB levels had a quadratic affect on the average daily feed intake (ADFI) (p<0.001). The greatest ADFI was achieved when the DEB level was +201 meq/kg DM. Fecal N (FN) content linearly decreased (0.047), while digestible N (DN), retained N (RN), efficiency of intake N converted into digestible N (DN/IN) and the efficiency of intake N converted into retained N (RN/IN) linearly increased with the DEB increase (0.020, 0.004, 0.021, and 0.049, respectively). Serum phosphorus (P) ion content linearly increased with the DEB increase (p = 0.036). The DEB had a quadratic relationship with serum anion gap (AG) (p = 0.002) and serum parathyroid hormone (PTH) content (p = 0.016). The DEB levels quadratically affected base excess (BE) in the plasma (p<0.001). In conclusion, the DEB unaffected growth performance but affected feed intake, N metabolism and some blood biochemical parameters of growing rabbits.

Development of Low-Cost and Low-Power Picosatellite Electrical Power Subsystem (저비용/저전력의 초소형위성 전력계의 개발)

  • Park, Je-Hong;Kim, Young-Hyun;Moon, Byoung-Young;Chang, Young-Keun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.7
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    • pp.105-116
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    • 2004
  • The design of pico-/nano-satellites is particularly challenging due to constraints in mass, volume, power, and surface area. An efficient low-cost picosatellite HAUSAT-1 Electrical Power Subsystem (EPS) is developed to supply the power for various loads during the full mission life. This paper addresses design and analysis results of solar arrays, batteries, power conditioning and distribution units. The component selection, manufacturing and test results are presented by considering appropriate development cost and performance. The simulation results of power system are also illustrated, according to operational modes, through energy balance analysis. Finally, the EFS design feasibility is verified by comparing analysis results with functional and environmental test results at the system and component levels, respectively.

A Modified Process for the Separation of Fe(III) and Cu(II) from the Sulfuric Acid Leaching Solution of Metallic Alloys of Reduction Smelted Spent Lithium-ion Batteries (폐리튬이온전지의 용융환원된 금속합금상의 황산침출액에서 철(III)과 구리(II)의 분리를 위한 공정 개선)

  • Nguyen, Thi Thu Huong;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.1
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    • pp.12-20
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    • 2022
  • The smelting reduction of spent lithium-ion batteries results in metallic alloys containing Co, Cu, Fe, Mn, Ni, and Si. A process to separate metal ions from the sulfuric acid leaching solution of these metallic alloys has been reported. In this process, ionic liquids are employed to separate Fe(III) and Cu(II). In this study, D2EHPA and Cyanex 301 were employed to replace these ionic liquids. Fe(III) and Cu(II) from the sulfate solution were sequentially extracted using 0.5 M D2EHPA with three stages of cross-current and 0.3 M Cyanex 301. The stripping of Fe(III) and Cu(II) from the loaded phases was performed using 50% (v/v) and 60% (v/v) aqua regia solutions, respectively. The mass balance results from this process indicated that the recovery and purity percentages of the metals were greater than 99%.