• Title/Summary/Keyword: Ion Conductor

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Corona Cage Simulation on Environmental Characteristics Caused by the Ion flow of Candidated Conductor Bundles for HVDC Overhead Transmission (초고압 직류 가공송전 후보 도체방식의 이온류 환경특성 코로나 케이지 모의시험)

  • Ju, Mun-No;Yang, Kwang-Ho;Lee, Dong-Il;Shin, Koo-Yong
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.10
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    • pp.1791-1795
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    • 2007
  • Small ions generated at conductor corona sources remain in the atmosphere until they recombine with ions of opposite polarity, attach to aerosols, or make contact with an object. Ion current density is major factor to design conductor configuration of DC overhead transmission line. Several techniques have been used to measure the ion current of HVDC overhead transmission line. In this study, the ion current density was measured by a plate electrode made of a metal flat board at DC corona cage. The sensitivity of the plate electrode is $0.156uA/m^2/V$. To obtain an useful database on corona discharge, it is necessary to do corona test on several kinds of conductor bundles. Therefore, a number of experiments were conducted on several kinds of conductor bundles. To reliably analyze ion effects, corona cage test data were obtained over a long period of time under various weather conditions and expressed as a statistical distribution. Ion current density distribution in foul weather shows a significant increase in levels over the corresponding fair weather. Based on this results, we evaluated the environmental characteristic caused by ion flow of three candidated conductor bundles.

Preparation and Properties of Inorganic-organic Hybrid $Li^+$ Ion Conductor by Sol-gel Process

  • Nishio, Keishi;Miyazawa, Tsutomu;Watanabe, Yuichi;Tsuchiya, Toshio
    • The Korean Journal of Ceramics
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    • v.7 no.1
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    • pp.1-5
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    • 2001
  • Inorganic-organic hybrid Li$^+$ ion conductors were prepared by the sol-gel process. Tetramethyl orthosilicate (TMOS), polyethylene glycol 200 (PEG$_200$) and lithium bis (trifluoro-methylsulfony) imide were used as raw materials and $H_2O$ was used as a solvent. Hybrid Li$^+$ ion conductor prepared by the sol-gel process showed very high ion conductivities of log${\sigma}_R.T$(S/cm)=-3.73, log${\sigma}_60$(S/cm)=-3.00 at room temperature and $60^{\circ}C$, respectivery. Decomposition voltage was 3.1 V.

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Characterization of RF Sputter-deposited Sodium Phosphorous Oxynitride Thin Films as a Solid-state Sodium-ion Conductor

  • Chun, Sang-Eun
    • Journal of the Korean institute of surface engineering
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    • v.50 no.4
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    • pp.237-243
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    • 2017
  • We demonstrated the thin film deposition of sodium phosphorous oxynitride (NaPON) via RF magnetron sputtering of $Na_3PO_4$, as a solid-state Na-ion conductor similar to lithium phosphorous oxynitride (LiPON), which is a commonly used solid electrolyte. The deposited NaPON thin film was characterized by scanning electron microscopy, X-ray diffractometry, and electrochemical impedance spectroscopy, to investigate the feasibility of the solid-state electrolyte in several different cell configurations. The key properties of a solidstate electrolyte, i.e., ionic conductivity and activation energy, were estimated from the complex non-linear least square fitting of the measured impedance spectra at various temperatures in the range of $27-90^{\circ}C$. The ionic conductivity of the NaPON film was measured to be $8.73{\times}10^{-6}S\;cm^{-1}$ at $27^{\circ}C$, which was comparable to that of the LiPON film. The activation energy was estimated to be 0.164 eV, which was lower than that of the LiPON film (0.672 eV). The obtained values encourage the use of a NaPON thin film in the future as a reasonable solid-state electrolyte.

Ion Migration in Organic Metal Halide Perovskites (유기 금속 할라이드 페로브스카이트에서 이온 이동)

  • Oh, Ilwhan
    • Journal of the Korean Electrochemical Society
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    • v.21 no.2
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    • pp.21-27
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    • 2018
  • In this review, recent researches on ion transport phenomena in organic metal halide perovskite materials, which have been popular all over the world, are summarized. Although different results have been reported depending on the perovskite material composition and applied voltage, iodide seems to migrate under actual solar cell operating conditions, and occasionally methylammonium migration is observed. Perovskite is a so-called mixed conductor in which electrons and ions move simultaneously at room temperature, which greatly influences the hysteresis of the perovskite solar cell current-voltage curve and the performance degradation due to long-term operation.

Electronic Structure, Bonding and Kithium Migration Effects of the Mixed Conductor $\beta-LiAl$ (혼합 전도체 $\beta-LiAl$의 전자구조, 결합과 Li 이온 이동에 따른 영향)

  • Jang, Gun-Eik;I.M Curelaru
    • Journal of the Korean Vacuum Society
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    • v.5 no.3
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    • pp.194-198
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    • 1996
  • Detailed expermental studies of theelectronic structure of the valence and conduction bands of the mixed conductor $\beta$-LiAlindicate that a quasi-gap opens at the Fermi level, and the conduction states are highlylocalized, as opposed to the theoretical band structure calculations that predict predominant metallic behavior. Evidence for complex lithium migration effects involving the surface of Lial , induced by particle (electron or ion) bombardment and mechanical treatment , has been obtained as a byproduct of these experiments.

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Solid Electrochemical Method of Measuring Hydrogen Concentration with O2-/H+ Hetero-Ionic Junction

  • Chongook Park
    • Journal of Sensor Science and Technology
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    • v.33 no.2
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    • pp.63-69
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    • 2024
  • A novel method for measuring hydrogen concentration is introduced, along with its working principle and a novel detection algorithm. This configuration requires no additional reference compartment for potentiometric electrochemical measurements; therefore, it is the most suitable for measuring dissolved hydrogen in the liquid phase. The sensor's electromotive force saturates at a certain point, depending on the hydrogen concentration during the heating process of the sensor operation. This dynamic temperature scanning method provides higher sensitivity than the constant temperature measurement method.