• Title/Summary/Keyword: Intra-molecular

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A Lattice Model for Intra-molecular and Inter-molecular Association in Mixture containing Surfactants (계면활성제를 함유한 혼합물에서 내외부 분자회합을 위한 격자모델)

  • Shin, Moon-Sam
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1768-1772
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    • 2010
  • Intra-molecular association is an important contribution to the overall hydrogen bonding in surfactant systems, especially in systems of colloidal and biological interest. Amphiphile systems, especially micelle and microemulsion systems, showed highly non-ideal behavior due to the intermolecular association and intra-molecular association. The objective of this research is to present a lattice fluid equation of state that combines the quasi-chemical nonrandom lattice fluid model with modified Veytsman statistics for intra + inter molecular association to calculate phase behavior for mixture containing surfactant systems. The lattice model could describe the literature data well for alkane and surfactant systems.

Synthesis, Photochemical and Photophysical Behavior of Vinyl Monomers with Donor/Acceptor Architectures and Their Polymers

  • Li, Zi-Chen;Du, Fu-Sheng;Li, Fu-Mian
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.106-107
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    • 2006
  • A series of vinyl monomers and their saturated model compounds containing different chromophores were synthesized. These monomers display strong intra-molecular fluorescence quenching, their fluorescence quantum yields and lifetimes are generally lower than those of their model compounds. It was found that the C=C bonds in these monomers played a key role in the intra-molecular quenching, which was confirmed by intermolecular fluorescence quenching and time-resolved fluorescence studies. On the basis of the intra-molecular quenching, a new fluorescence approach can be developed to monitor the process of the polymerization and curing of bismaleimides, which can directly reflect the C=C bond consumption during polymerization and curing.

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A Quasi-Chemical Inter and Intra Molecular Association Nonrandom Lattice Model for Surfactant Systems (계면활성제계를 위한 준화학 분자내외부 회합 비무질서도 격자모델)

  • Shin, Moon-Sam
    • Proceedings of the KAIS Fall Conference
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    • 2011.05a
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    • pp.485-488
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    • 2011
  • Intramolecular association is an important contribution to the overall hydrogen bonding in supercritical fluid systems, especially in systems of colloidal and biological interest. Amphiphile systems, especially micelle and microemulsion systems, showed highly non-ideal behavior due to the intermolecular association and intramolecular association. The objective of this research is to present a lattice fluid equation of state that combines the quasi-chemical nonrandom lattice fluid model with modified Veytsman statistics for intra + inter molecular association to calculate phase behavior for mixture containing surfactant systems. The present EOS could correlate the literature data well for mixtures containing nonionic surfactant systems.

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Utilization of Molecular Markers in Plant Genetics and Breeding (식물유전 및 육종학 연구에서의 분자생물학적 마커기술의 이용)

  • 이주경
    • Korean Journal of Plant Resources
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    • v.10 no.2
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    • pp.200-210
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    • 1997
  • The understanding on the plant genome is accelerated with the fast advance of molecular biological techniques. The molecular dissecting of the plant genome has made possible the precise genotyping the plants, which can be utilized for molecular breeding program. As well, the molecular cloning of genes interested can facilitate the process of gene transfer between intra-and inter-generic taxa. Moreover, the manipulation of the agronomically important QTL genes, which can be rarely performed by the conventional genetic methods, is also possible by the utilization of molecular markers. In addition to these genetical applications, molecular markers are useful in the areas of plant taxonomy and management of germplasm by fingerprinting analysis. This paper describes the theoretical aspects marker technologies and practical applications of each marker technique.

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Development of an Enzyme-linked Immunosorbent Assay Using Vitellin for Vitellogenin Measurement in the Pale Chub, Zacco platypus

  • Lim, Eun-Suk;Lee, Eun Hee;Kim, Myung Hee;Han, Chang-Hee;Lee, Sung-Kyu;Kim, Jiwon
    • Environmental Analysis Health and Toxicology
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    • v.28
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    • pp.16.1-16.8
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    • 2013
  • Objectives Fish vitellogenin (VTG) is produced in the female liver during oogenesis through the estradiol cycle and produced in the male liver by endocrine disrupting chemicals (EDCs) such as alkylphenols. In this study, we propose that the VTG concentration in the pale chub could be detected using monoclonal antibodies and polyclonal antibodies against vitellin (Vn) in a VTG enzyme-linked immunosorbent assay (ELISA) system. Methods Monoclonal antibodies and polyclonal antibodies were produced using the Vn extracted from the matured ovum of the ovary. The VTG was extracted from the plasma of the male pale chub. The Vn and VTG were confirmed by measuring the molecular weight of their proteins using sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) and the specificity of the antibodies was checked through western blotting methods. The assay system was validated with respect to optimal assay concentrations, specificity, recovery, and intra- and inter-assay variations. Results The Vn consisted of two protein bands with apparent molecular weights of 64 and 37 kDa. The SDS-PAGE indicated protein weights of 146 and 77 kDa in the VTG. The assay range was 15.6 ng/mL to 2,000 ng/mL, and the value of the intra- and inter-assay variations were within 10.0% and 14.7%, respectively. The recovery rate was $99.5{\pm}5.5%$. Conclusions A sandwich ELISA was developed that could be used to qualify the VTG of pale chub in screening for EDCs. Pale chub is an ideal species for observing estrogen activity in the environment because of its extensive habitat and extensive food chain. The ELISA developed here would be more favorable than those for other species for determining the effect of long-term food chain accumulation of EDCs in aquatic environments.

Deformation of Polymer Resist in NIL Process by Molecular Dynamic Simulation (분자동역학기법을 이용한 나노 임프린트 리소그래피 공정에서의 고분자 변형모사)

  • Woo, Young-Seok;Lee, Woo-Il
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.337-342
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    • 2007
  • In this study, molecular dynamics simulation of nano imprint lithography in which patterned stamp is pressed onto amorphous polyethylene(PE) surface are performed to study the behaviour of polymer. Force fields including bond, angle, torsion, and Lennard Jones potential are used to describe the inter-molecular and intra-molecular force of PE molecules and stamp, substrate. Periodic boundary condition is used in horizontal direction and canonical NVT ensemble is used to control the system temperature. As the simulation results, the behaviour of polymer is investigated during the imprinting process. The mechanism of polymer deformation is studied by means of inspecting the surface shape, volume, density, atom distribution. Deformation of the polymer resist was found for various of the stamp geometry and the alignment state of the polymer molecules.

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MOLECULAR GAS PROPERTIES UNDER ICM PRESSURE IN THE CLUSTER ENVIRONMENT

  • LEE, BUMHYUN;CHUNG, AEREE
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.491-494
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    • 2015
  • We present 12CO (2-1) data for four spiral galaxies (NGC 4330, NGC 4402, NGC 4522, NGC 4569) in the Virgo cluster that are undergoing different ram pressure stages. The goal is to probe the detailed molecular gas properties under strong intra-cluster medium (ICM) pressure using high-resolution millimeter data taken with the Submillimeter Array (SMA). Combining this with Institut de RadioAstronomie $Millim{\acute{e}}trique$ (IRAM) data, we also study spatially resolved temperature and density distributions of the molecular gas. Comparing with multi-wavelength data (optical, $H\small{I}$, UV, $H{\alpha}$), we discuss how molecular gas properties and star formation activity change when a galaxy experiences $H\small{I}$ stripping. This study suggests that ICM pressure can modify the physical and chemical properties of the molecular gas significantly even if stripping does not take place. We discuss how this affects the star formation rate and galaxy evolution in the cluster environment.

Interplay Between Intra- and Extracellular Calcium Ions

  • Lee, Eun Hui;Kim, Do Han;Allen, Paul D.
    • Molecules and Cells
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    • v.21 no.3
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    • pp.315-329
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    • 2006
  • Two, well characterized cationic channels, the ryanodine receptor (RyR) and the canonical transient receptor potential cation channel (TRPC) are briefly reviewed with a particular attention on recent developments related to the interplay between the two channel families.

Molecular Dynamics Simulation for the Mechanical Properties of CNT/Polymer Nanocomposites (분자동역학 시뮬레이션을 이용한 나노튜브/고분자 나노복합재의 물성 해석)

  • Yang, Seung-Hwa;Cho, Maeg-Hyo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.2 s.257
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    • pp.237-244
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    • 2007
  • In order to obtain mechanical properties of CNT/Polymer nano-composites, molecular dynamics simulation is performed. Overall system was modeled as a flexible unit cell in which carbon nanotubes are embedded into a polyethylene matrix for N $\sigma$ T ensemble simulation. COMPASS force field was chosen to describe inter and intra molecular potential and bulk effect was achieved via periodic boundary conditions. In CNT-polymer interface, only Lennard-Jones non-bond potential was considered. Using Parrinello-Rahman fluctuation method, mechanical properties of orthotropic nano-composites under various temperatures were successfully obtained. Also, we investigated thermal behavior of the short CNT reinforced nanocomposites system with predicting glass transition temperature.