• 한국자기공명학회논문지
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• 제13권1호
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• pp.35-55
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• 2009

The two correlation times previously obtained in our coupled $^{13}C$ relaxation measurement for the methyl group in 2,6-dichlorotoluene may be used as a criterion for evaluating the reorientation dynamics of an internal rotor. We numerically tested an extended diffusion model and the Smoluchowski diffusion equation to see how the rotational inertial effect and jump character contribute to the internal correlation time ratio of the internal rotor. We also analytically solved the general jump model with three different rate constants in a sixfold symmetric potential barrier. By assuming that the internal rotation of the methyl group in 2,6-dichlorotoluene can be described in terms of jumps among sixfold harmonic potential wells, we can conclude that the jump model satisfactorily reproduce the experimental data and the rate for sixfold jump is at least 1.53 times as great as that of a threefold jump.

• 한국안전학회지
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• 제31권4호
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• pp.75-81
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• 2016

This study presents the effect of urea and sulfur admixture on compressive strength, chloride diffusion coefficient, and internal void distribution of concrete. Compressive strength of concretes with urea admixture by 5% increased by 5% relative to Control. However, that of concretes with urea admixture over 10% decreased. Chloride diffusion coefficient of concrete with urea and sulfur admixture decreased by 40% relative to Control. Additionally, the volume of internal void of concrete with urea and sulfur admixture decreased by 20% relative to Control. Therefore, it can be mentioned from test results that the use of adequate urea and sulfur admixture improves the mechanical properties and durability of concrete.

• 통합자연과학논문집
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• 제4권2호
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• pp.130-136
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• 2011

This study investigated the adsorption characteristics of nickel, zinc and cadmium ions from the aqueous solution onto the alginate bead. Adsorption equilibrium capacities of the heavy metal ions increased with increasing initial pH of the solution. The adsorption equilibrium isotherm of the heavy metal ions was well represented by Langmuir equation. The magnitude of adsorption capacity of the heavy metal ions onto alginate bead was the order of cadmium > zinc > nickel. Kinetic parameters were measured in a batch adsorber to analyze the adsorption rates of the heavy metal ions. The internal diffusion coefficient of the heavy metal ions in the intraparticle were determined by comparing the experimental concentration curves with those predicted from the surface diffusion model (SDM) and pore diffusion model (PDM). The internal diffusion of the heavy metal ions in the intraparticles was explained by PDM.

• 한국컴퓨터정보학회논문지
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• 제15권9호
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• pp.155-164
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• 2010

지금까지 EDI의 연구는 EDI 도입과 성과에 초점이 맞추어져 왔다. 그러나 최근 EDI의 확산에 관한 연구가 증가하고 있다. 이 연구의 목적은 첫째, EDI 확산의 여러 요인을 찾고, 두 번째 EDI 확산 요인과 EDI 확산 정도와의 관계를 밝혀보고자 한다. 이러한 목적을 달성하기 위해 본 연구에서 채택된 두가지 방법론은 첫째, 선행연구들을 폭넓게 분석하여 모델을 구축하는 것이며, 둘째 EDI 확산요인을 탐색하는 실험적 연구방법이다. 본 연구가설을 검증한 결과 첫째, EDI 내부확산에 영향을 미치는 중요한 변수들은 최고경영자의 지원, 업무범위, 정보기반, 적합성, 복잡성, 상대적 이익, 경쟁정도, 거래상대방 압력을 들 수 있고, 둘째 EDI의 외부확산에 영향을 미치는 주요 변수들은 최고 경영자의 지원, 업무범위, 정보기반, 적합성, 상대적 이익, 경쟁정도, 거래상대방 압력 이다. 최고경영자의 지원, 업무 범위, 정보기반, 적합성, 상대적 이익, 경쟁 정도 그리고 거래상대방 압력이 EDI 내부확산과 외부확산에 동시에 영향을 미치는 것을 알 수 있다.

• 한국정보시스템학회지:정보시스템연구
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• 제7권1호
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• pp.77-98
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• 1998

Electronic Data Interchange(EDI) is a relatively new technique around the world and enables the firm more competitive because of transmitting computer-generated documents directly to a firm's trading partner's computer across a telecommunication network. This study investigates the relationship among the organizational characteristics and information systems(IS) maturity, and the extent of internal and external diffusion of Electronic Data Interchange (EDI) in Korean firms. The data for this study were collected from 131 firms that have implemented EDI. The results of t-test show that subgroups classified by industry, the extent of decentralization and formalization, and IS maturity, except the size of organization, are not different in the extent EDI diffusion. Also, the results of multiple regression analysis show that the size of organization is the major predictor of internal diffusion, and IS maturity and the size of organization are the major predictors in external diffusion of EDI. This study implies that the size of organization among organization characteristics and IS maturity should be considered as important variables for the diffusion of EDI system.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 Proceedings of 2004 Korea-Japan Joint Seminar on Particle Image Velocimetry
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• pp.91-110
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• 2004

A comprehensive three-dimensional nano-particle tracking technique in micro- and nano-scale spatial resolution using the Total Internal Reflection Fluorescence Microscope (TIRFM) is discussed. Evanescent waves from the total internal reflection of a 488nm argon-ion laser are used to measure the hindered Brownian diffusion within few hundred nanometers of a glass-water interface. 200-nm fluorescence-coated polystyrene spheres are used as tracers to achieve three-dimensional tracking within the near-wall penetration depth. A novel ratiometric imaging technique coupled with a neural network model is used to tag and track the tracer particles. This technique allows for the determination of the relative depth wise locations of the particles. This analysis, to our knowledge is the first such three-dimensional ratiometric nano-particle tracking velocimetry technique to be applied for measuring Brownian diffusion close to the wall.

• Korean Chemical Engineering Research
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• 제52권1호
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• pp.133-140
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• 2014

본 연구의 목적은 국내 화력발전소에서 사용중인 인도네시아 석탄촤의 연소반응율을 연구하는 것이다. 석탄촤의 반응율은 External, Internal effectiveness factor를 고려하여 입자 내부 및 외부확산을 정량적으로 정리하였으며, Random pore model을 사용하여 탄소변환율에 따른 입자내부비표면적의 변화를 반영하였다. 가열 및 측정이 가능한 WHR(Wire Heating Reactor)를 활용하여 반응시간을 측정함으로써 석탄촤의 반응율을 도출하였고 BET(Brunauer-Emmett-Teller) 및 TGA(Thermo-Gravimetric Analysis) 장비를 활용하여 석탄촤의 물리적인 특성인 내부비표면적과 Random pore model의 구조변수(${\Psi}$)를 측정하였다. 석탄 종에 따른 활성화에너지 및 빈도인자를 도출하기 위해 아역청탄인 BARAMULTI, ENERGYMAN, AGM탄을 사용하였다. 본 연구 결과에서 External, Internal effectiveness factors를 통해 확산에 따른 kinetics를 비교한 결과 외부 확산 보다 내부 확산의 영향이 지배적임을 확인하였다. 최종적으로 내부 및 외부 확산에 대한 영향을 고려한 3종의 석탄촤 Intrinsic kinetics의 활성화에너지는 110~118 kJ/mol의 값을 보였다.

• 디지털산업정보학회논문지
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• 제8권4호
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• pp.205-215
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• 2012

Due to a rapid change of business environment, many firms are eager to find the competitiveness by information technology adoption and diffusion. In this exploratory study, we examined the applicability of a previously proposed model to evaluate IT competitiveness based on the innovativeness and verified it's propriety with empirical data. As suggested by previous studies, the proposed model considers a variety of corporate and market characteristics concerned with IT adoption, and it consists of several internal and external impacting factors, which have influence on technology diffusion and its performance. For the empirical analysis, the survey data of domestic ERP adoption cases were adopted from 128 small and medium-sized enterprises(: SMEs) in IT and electrical engineering industry, and analyzed by partial least squares(: PLS) - a popular structural modeling and multivariate projection technique to latent variables. The results indicated positive supports for the research model of external and internal IT adoption factors' influences on innovativeness' performances. However, there are a couple of limitations not to show the reliability of selected measurement items and the generality of model proposed in this exploratory study.

• Journal of the Korean Wood Science and Technology
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• 제20권2호
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• pp.73-80
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• 1992

The effect of presteaming on native oak specimens(Quercus serrata) of 2.5cm thick were investigated by measuring specific gravities, internal moisture gradients, residual extractives, and transport rates of free and bound water. The specific gravities and internal moisture gradients of the presteamed samples did not much deviate from those of the controls, but after presteaming discrepancy in moisture content between specimens lessened. The amount of residual hot-water extractives of the presteamed samples were less than those of the controls by 25%. The transport rates of bound water were determined by measuring steady-state diffusion coefficients with a vapormeter cup. After presteaming the diffusion coefficients in radial direction increased by 35%, but decreased those in the tangential direction.

• 산업공학
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• 제25권2호
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• pp.255-263
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• 2012

In order to ensure the reliability and specialty of weapon system test results, a policy of extending certified testing service institutions has been driven by applying accreditation system of the ones in defense industry. Bass and Logistic models are used to apply the policy effectively and forecast the diffusion pattern of certified testing service institutions. The parameters for diffusion forecast are estimated using the diffusion pattern of certified testing service institutions in non-defense industry, and these are applied to forecast the diffusion of certified ones in defense industry. Coefficients of innovation and imitation of Bass model are analyzed to derive the factors influencing the early adoption and diffusion patterns. The more increasing the coefficients, the earlier adoption occurred. Diffusion pattern due to coefficient of imitation, internal factor, has larger effect on sensitivity of diffusion pattern. This means that the self recognition of necessity is more effectively worked than the policy or regulations driven by government.