• Title/Summary/Keyword: Intermediate temperature

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Ce0.8Sm0.2O2 Sol-gel Modification on La0.8Sr0.2Mn0.8Cu0.2O3 Cathode for Intermediate Temperature Solid Oxide Fuel Cell

  • Lee, Seung Jin;Kang, Choon-Hyoung;Chung, Chang-Bock;Yun, Jeong Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.4
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    • pp.77-82
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    • 2015
  • To increase the performance of solid oxide fuel cell operating at intermediate temperature ($600^{\circ}C{\sim}800^{\circ}C$), $Sm_{0.2}Ce_{0.8}O_2$ (SDC) thin layer was applied to the $La_{0.8}Sr_{0.2}Mn_{0.8}Cu_{0.2}O_3$ (LSMCu) cathode by sol-gel coating method. The SDC was employed as a diffusion barrier layer on the yttria-stabilized zirconia(YSZ) to prevent the interlayer by-product formation of $SrZrO_3$ or $La_2Zr_2O_7$. The by-products were hardly formed at the electrolyte-cathode interlayer resulting to reduce the cathode polarization resistance. Moreover, SDC thin film was coated on the cathode pore wall surface to extend the triple phase boundary (TPB) area.

Characterization of Glass Melts Containing Simulated Low and Intermediate Level Radioactive Waste

  • Jung, Hyun-Su;Kim, Ki-Dong;Lee, Seung-Heon;Kwon, Sung-Ku;Kim, Cheon-Woo;Park, Jong-Kil;Hwang, Tae-Won;Ahn, Zou-Sam
    • Journal of the Korean Ceramic Society
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    • v.43 no.3 s.286
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    • pp.148-151
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    • 2006
  • In order to examine the process parameters for the vitrification of Low and Intermediate Level radioactive Waste (LILW) generated from nuclear power plants, measurements of several melt properties was performed for four selected glasses containing simulated waste. Electrical conductivity and viscosity were determined at temperatures ranging from 1123 to $1673^{\circ}C$. The temperature dependences of both properties in the molten state showed a similar behavior in which their values decrease as the temperature increases. The values of the electrical conductivity and viscosity at a temperature of 1423K adopted in an induction cold crucible melter process were $0.27{\sim}0.42$ S/cm and $9.8{\sim}42$ dPas, respectively.

Synthesis and characterization of AlN nanopowder by the microwave assisted carbothermal reduction and nitridation (CRN)

  • Chun, Seung-Yeop;Chun, Myoung-Pyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.5
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    • pp.223-228
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    • 2017
  • Aluminum nitride (AlN) powder was successfully synthesized at low temperature via carbothermal reduction and nitridation (CRN) assisted by microwave heating. The synthesis processes of AlN powder were investigated with X-ray diffraction, FE-SEM, FT-IR and TGA/DSC. Aluminum nitrate was used as an oxidizer and aluminum source, urea as fuel, and glucose as carbon source. These starting materials were mixed with D.I water and reacted in a flask at $100^{\circ}C$ for 20 minutes. After the reaction was finished, black foamy intermediate product was formed, which was considered to be an amorphous $Al_2O_3$ particles through intermediate product obtained by solution combustion synthesis (SCS) at the results of X-ray diffraction patterns and FT-IR. This intermediate product was nitridated at temperatures of $1300^{\circ}C$ and $1400^{\circ}C$ in $N_2$ atmosphere by a microwave heating furnace and then decarbonated at $600^{\circ}C$ for 2 hours in air. It should be noticed from FE-SEM images that as nitridated particles, identified as AlN from X-ray diffraction patterns, are covered with carbon residues. After decarbonating the nitridated powders, the spherical pure AlN powders were obtained without alumina and their particle sizes were dependent on the nitridating temperature with high temperature of $1400^{\circ}C$ giving large particles of around 70~100 nm.

A study on the strain rate sensitivity according to the temperature for steel sheets of an auto-body (차체용 강판의 온도에 따른 변형률 속도 민감도 연구)

  • Lee H. J.;Song J. H.;Cho S. S.;Kim S. B.;Huh H.;Park S. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.148-151
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    • 2005
  • This paper is concerned with the thermo-mechanical behavior and temperature dependent strain rate sensitivity of steel sheet for an auto-body. In order to Identify the temperature dependent strain rate sensitivity of SPRC35R and SPRC45E, uniaxial tension tests are performed with the variation of the strain rates from 0.001/sec to 200/sec, and the variation of environmental temperatures from $-40^{\circ}C\;to\;200^{\circ}C$. The thermo-mechanical response at the quasi-static state is obtained with the static tensile test and at the intermediate strain rate is from the high speed tensile test. The experimental results show that the strain rate sensitivity increases at low temperature and it decreases at high temperature. It means that as the strain rate getting increasing, the variation of flow stress is more sensitive on the temperature. The results also indicates that the material properties of SPRC35R is more depend on the changes of strain rates and temperature than those of SPRC45E.

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Dynamic Constitutive Equations of Auto-Body Steel Sheets with the Variation of Temperature (I) - Dynamic Material Characteristics with the Variation of Temperature - (차체용 강판의 온도에 따른 동적 구성방정식에 관한 연구 (I) - 온도에 따른 동적 물성 특성 -)

  • Lee, Hee-Jong;Song, Jung-Han;Park, Sung-Ho;Huh, Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.2 s.257
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    • pp.174-181
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    • 2007
  • This paper is concerned with the thermo-mechanical behavior of steel sheet for an auto-body including temperature dependent strain rate sensitivity. In order to identify the temperature-dependent strain rate sensitivity of SPRC35R, SPRC45E and TRIP60, uniaxial tensile tests are performed with the variation of the strain rates from 0.001/sec to 200/sec and the variation of environmental temperatures from $-40^{\circ}C$ to $200^{\circ}C$. The thermo-mechanical response at the quasi-static state is obtained from the static tensile test and that at the intermediate strain rate is obtained from the high speed tensile test. Experimental results show that the variation of the flow stress and fracture elongation becomes sensitive to the temperature as the strain rate increases. It is observed that the dynamic strain aging occurs with TRIP60 at the temperature above $150^{\circ}C$. Results also indicate that the flow stress and tincture elongation of SPRC35R are more dependent on the changes of strain rates and temperature than those of SPRC45E and TRIP60.

Accuracy and Stability of Temperature and Salinity from Autonomous Profiling CTD Floats (ARGO Float) (자동 수직물성관측 뜰개(ARGO Float)로 얻은 수온과 염분의 정확도와 안정도)

  • 오경희;박영규;석문식
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.9 no.4
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    • pp.204-211
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    • 2004
  • Autonomous profiling CTD floats are a useful tool for observing the oceans. We, however, cannot perform post-deployment calibration of the CTD's attached to the floats, and the assessment of the accuracy and stability of the profile data from the floats is one of the important issues in the delayed mode quality control of the profiles. Variations in salinity in the intermediate level of East Sea is comparable to the accuracy of salinity data required by the international Argo Program, which is 0.01. Therefore, we can assess the credibility of salinity data from the floats deployed in the East Sea using three independent methods while considering the East Sea as a salinity calibration bath. The methods utilized here are 1) comparison of high quality CTD data and float data obtained at similar locations at similar time, 2) comparison of float data obtained at similar locations at similar time, and 3) investigation of long term stability and accuracy of salinity data from parking depths. All three methods show that without any calibration, the salinity data satisfy the accuracy criterion by the Argo Program. While assuming that the intermediate level temperature in the East Sea is as homogeneous as the salinity, we have applied the three methods to temperature data. We found that the accuracy of temperature reading is 0.01$^{\circ}C$, which is about twice larger than the requirement by the Argo Program, 0.005$^{\circ}C$. This does not mean that the temperature readings are inaccurate, because the intermediate level temperature does vary spacially and temporally more than the accuracy interval required by the Argo Program. If we take into account the variation in the intermediate level temperature, the accuracy of temperature data from the floats is not significantly different from that proposed by the Argo Program. Therefore, one could use both temperature and salinity profiles from the floats assessed in this study without calibration.

A Study on the Strain-Rate Sensitivity According to the Temperature for Steel Sheets of an Auto-Body (차체용 강판의 온도에 따른 변형률속도 민감도 연구)

  • Lee, H.J.;Song, J.H.;Cho, S.S.;Park, S.H.;Huh, H.
    • Transactions of Materials Processing
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    • v.15 no.2 s.83
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    • pp.132-137
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    • 2006
  • This paper is concerned with the thermo-mechanical behavior including temperature dependent strain-rate sensitivity of steel sheet for an auto-body. In order to identify the temperature dependent strain-rate sensitivity of SPRC35R and SPRC45E, uniaxial tension tests are performed with the variation of the strain-rates from 0.001 /sec to 200 /sec at environmental temperatures varied from $-40^{\circ}C\;to\;200^{\circ}C$. The thermo-mechanical response at the quasi-static state is obtained with the static tensile test and at the intermediate strain-rate is from the high speed tensile test. Experimental results show that the strain-rate sensitivity increases at low temperature. It represents that as the strain-rate increases, the variation of flow stress becomes sensitive on the temperature. The results indicate that the flow stress of SPRC35R is more dependent on the changes of strain-rate and temperature than those of SPRC45E.

Effects of Intermediate Layer in DLC Thin Film on Al2O3 for Improvement of High Temperature Strength

  • Ok, Chul-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.125-130
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    • 2007
  • DLC coating on ceramics is very useful for manufacturing the materials with hardness and low friction. Adhesion of DLC thin film on ceramics, on the other hand, is usually very weak. Adhesion of DLC film depends on many parameters such as contamination and chemical bonding between thin film and substrate. In this study, adhesion of DLC film on ceramics was improved by the intermediate layer when the plasma immersion ion deposition (PIID) technique was applied. It is found that the chemical composition and the thickness of intermediate layer have significantly an effect on the adhesion of DLC thin film on $Al_2O_3$.

Preliminary Design of Current Lead for 21T Superconducting Magnet (21T 초전도자석을 위한 전류도입선 예비설계)

  • Choi, Y.S.;Kim, D.L.;Yang, H.S.;Lee, B.S.;Painter, Thomas A.
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.3
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    • pp.43-46
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    • 2008
  • Design of current lead for 21T superconducting magnets is presented. The current lead is composed of a normal metal element, conducting the current from room temperature to intermediate temperature, and an HTS element, conducting the current down to liquid helium temperature. The metal element is disengaged from the HTS element without breaking vacuum after excitation. The optimization of the lead is performed to minimize the thermal heat load when carrying operational current with some margin. In order to confirm the feasibility of our new design, the intermediate joint between a normal metal and HTS element is fabricated and the reliability is tested during engage and disengage performance. The effects of vacuum level and performance cycle on the electrical contact resistance are also investigated.

Mode Change of Deep Water Formation Deduced from Slow Variation of Thermal Structure: One-dimensional Model Study (열적 수직 구조의 장기 변화로부터 유추한 동해 심층수 형성 모드의 변환: 1차원 모델 연구)

  • Chae, Yeong-Ki;Seung, Young-Ho;Kang, Sok-Kuh
    • Ocean and Polar Research
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    • v.27 no.2
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    • pp.115-123
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    • 2005
  • Recently, it has been observed in the East Sea that temperature increases below the thermocline, and dissolved oxygen increase in the intermediate layer but decrease below it. The layer of minimum dissolved oxygen deepens and the bottom homogeneous layer in oxygen becomes thinner. It emerges very probably that these changes are induced by the mode change of deep water formation associated with global warming. To further support this hypothesis, a one-dimensional model experiment is performed. First, a thermal profile is obtained by injecting a cold and high oxygen deep water into the bottom layer, say the bottom mode. Then, two thermal profiles are obtained from the bottom mode profile by assuming that either all the deep water introduce into the intermediate layer has been initiated, say the intermediate mode, or that only a part of the deep water has been initiated into the intermediate layer, say the intermediate-bottom mode. The results, from the intermediate-bottom mode experiment are closest to the observed results. They show quite well the tendency for oxygen to increase in the intermediate layer and the simultaneous thinning of the bottom homogeneous layer in oxygen. Therefore, it can be said that the recently observed slow variation of the thermal structure might be associated with changes in the deep water formation from the bottom mode to the intermediate-bottom mode.