• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회B
• /
• pp.2850-2855
• /
• 2008

Very High Temperature Reactor (VHTR) has been selected as a high energy heat source for a nuclear hydrogen generation. The VHTR heat is transferred to a thermo-chemical hydrogen production process through an intermediate loop. Both Process Heat Exchanger and sulfuric acid evaporator provide the coupled components between the VHTR intermediate loop and hydrogen production module. A small scaled Compact Nuclear Hydrogen Coupled Components test loop is developed to simulate the VHTR intermediate loop and hydrogen production module. Main objective of the loop is to screening the candidates of NHDD (Nuclear Hydrogen Development and Demonstration) coupled components. The operating condition of the gas loop is a temperature up to $950^{\circ}C$ and a pressure up to 6.0MPa. The thermal and fluid dynamic design of the loop is dependent on the structures that enclose the gas flow, especially primary side that has fast gas velocity. We designed and constructed a small scale sulfuric acid experimental system which can simulate a part of the hydrogen production module also.

• 한국압력기기공학회 논문집
• /
• 제5권1호
• /
• pp.1-8
• /
• 2009

본 논문에서는 국제적으로 개발 중인 초고온가스로와 연계하여 대량의 수소를 생산하기 위한 방안의 일환으로 국내에서 개발 중인 고온증기전기분해 시스템에 사용될 열교환기 재료의 고온증기 부식실험에 대해 소개하였다. 이를 위해 관련된 국내외 연구현황을 조사분석한 결과를 요약하여 소개하였으며 마지막으로 현재 수행중인 고온증기부식 연구의 실험조건 및 계획을 제시하였다. 실험 및 연구결과는 초고온가스로와 연계된 고온전기분해를 이용한 수소생산시스템의 개발에 활용될 예정이다.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2009년도 춘계학술발표대회
• /
• pp.56.1-56.1
• /
• 2009

The intermediate operating temperature of solid oxide fuel cells (IT-SOFCs) have achieved considerable importance in the area of power fabrication. This is because to improve materials compatibility, their long-term stability and cost saving potential. However, to conserve rational cell performance at reduced-temperature regime, cathode performance should be obtained without negotiating the internal resistance and the electrode kinetics of the cell. Recently, double perovskite structure cathodes have been studied with great attention as a potential material for IT-SOFCs. In this study, double-perovskite structured cathodes of $GdBaCoCuO_{5+\delta}$, $GdBaCo_{2/3}Cu_{2/3}Fe_{2/3}O_{5+\delta}$ compositions and $(1-x)GdBaCo_2O_{5+\delta}+xCe_{0.9}Gd_{0.1}O_{1.95}$ (x = 10, 20, 30 and 40 wt.%) composites were evaluated as the cathode for intermediate temperature solid oxide fuel cells(IT-SOFCs). Electrical conductivity of the cathodes were measured by DC 4-probe method, and the thermal expansion coefficient of each sample was measured up to $900^{\circ}C$ by a dilatometer study. Area specific resistances(ASR) of the $GdBaCo_{2/3}Cu_{2/3}Fe_{2/3}O_{5+\delta}$ cathode and 70 wt.% $GdBaCo_2O5+\delta$ + 30wt.% Ce0.9Gd0.1O1.95 composite cathode on CGO electrolyte substrate were analyzed using AC 3-probe impedance study. The obtained results demonstrate that double perovskite-based compositions are promising cathode materials for IT-SOFCs.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2006년도 추계학술대회
• /
• pp.368-371
• /
• 2006

[ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2011년도 추계학술대회 초록집
• /
• pp.84.1-84.1
• /
• 2011

Typical solid oxide fuel cells (SOFCs) have limited applications because they operate at high temperature due to low ionic conductivity of electrolyte. Thin film solid oxide fuel cell with yttria stabilized zirconia (YSZ) electrolyte is developed to decrease operating temperature. Pt/YSZ/Pt thin film SOFC was fabricated on anodic aluminum oxide (AAO). The crystalline structure of YSZ electrolyte by sputter is heavily depends on the roughness of porous Pt layer, which results in pinholes. To deposit YSZ electrolyte without pinholes and electrical shortage, it is necessary to deposit smoother and denser layer between Pt anode layer and YSZ layer by sputter. Atomic Layer Deposition (ALD) technique is used to deposit pre-YSZ layer, and it improved electrolyte quality. 300nm thick Bi-layered YSZ electrolyte was successfully deposited without electrical shortage.

• Nuclear Engineering and Technology
• /
• 제39권2호
• /
• pp.95-102
• /
• 2007

The conceptual design of the MIT modular pebble bed reactor is described. This reactor plant is a 250 Mwth, 120 Mwe indirect cycle plant that is designed to be deployed in the near term using demonstrated helium system components. The primary system is a conventional pebble bed reactor with a dynamic central column with an outlet temperature of 900 C providing helium to an intermediate helium to helium heat exchanger (IHX). The outlet of the IHX is input to a three shaft horizontal Brayton Cycle power conversion system. The design constraint used in sizing the plant is based on a factory modularity principle which allows the plant to be assembled 'Lego' style instead of constructed piece by piece. This principle employs space frames which contain the power conversion system that permits the Lego-like modules to be shipped by truck or train to sites. This paper also describes the research that has been conducted at MIT since 1998 on fuel modeling, silver leakage from coated fuel particles, dynamic simulation, MCNP reactor physics modeling and air ingress analysis.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2005년도 춘계학술대회 논문집
• /
• pp.1390-1393
• /
• 2005

The hardening model based on the dislocation mechanics is employed to study the experimentally observed high tensile elongations of NiAl along the [110] orientation at intermediate temperatures. In the hardening model proposed, a mobility of dislocation is assumed to be restricted to glide through the slip plane by forest dislocation and thermally activated cross-slip event. Overall deformation behavior of NiAl was greatly influenced by temperature-dependent dislocation mobility that both experimental and simulated yield stresses decreased as temperature increased. The results of simulation showed anomalous hardening behaviors analogous to those of experiment at certain circumstances. This behavior occurred due to the hardening contributions generated by cross-slip events that disable the dislocation motion in the primary slip systems. By comparing simulation results with experiments, it is confirmed that the proposed hardening model can represent anomalous tensile elongations due to the hardening by forest dislocations and cross-slip events.

• 전기학회논문지
• /
• 제57권1호
• /
• pp.78-81
• /
• 2008

A hollow cathode which has extremely stable discharge characteristic has been developed. This is composed of the two separated lanthanum hexaboride(LaB6) of a disk type in the tube as the electron emitters. The way of design is of great advantage to extend the surface discharge area of the LaB6, which is also useful for optimal fixing of the LaB6. The hollow cathode is capable of producing 30 kW(100 V, 300 A) of power continuously. Because the generated plasma beam with the high temperature(above $3000^{\circ}C$) from the hollow cathode passes through the center hole of the two intermediate electrodes, it is designed with the high temperature material of the tungsten and the suitable structure of the water cooling. The combinations of the hollow cathode and the two intermediate electrodes are practically useful for the ion plating plasma beam source.

• 대한수의학회지
• /
• 제31권4호
• /
• pp.515-518
• /
• 1991

A field study of Lymnaea viridis, the intermediate host of Fasciola hepatica, was carried out in the eastern Chonnam area. The snail was distributed all over the place. Their major habitats were rice paddies (60.8%), followed by brooks (23.2%), irrigation canals (8.6%), and drains (5.6%). Other minor habitats included natural ponds (1.5%), lakes (0.4%), and rivers (0.1%). L. viridis was living in wet clay soil, occasionally entering water. The snails discharged egg masses when the temperature was $15{\sim}20^{\circ}C$, and the number of the snails was the highest late in October. At $9^{\circ}C$ the snails were not found on the mud: they were present deep in water or at the base of rice stubbles. These hibernation sites were discussed with the epidemiology of fascioliasis.

• 상하수도학회지
• /
• 제29권1호
• /
• pp.39-46
• /
• 2015

The degradation characteristics of perchloroethylene by ferrate(VI) oxidation have been studied. The degradation efficiency of perchloroethylene in aqueous solution was investigated at various values of ferrate(VI) dosage, pH, initial concentration of perchloroethylene and aqueous solution temperature. GC-ECD has been used to analyze the changes of perchloroethylene concentration. The optimum conditions of perchloroethylene degradation were obtained at pH 7.0 and $25^{\circ}C$ of aqueous solution temperature. Also, the experimental results showed that perchloroethylene removal efficiency increased with the decrease of initial concentration of perchloroethylene. Lastly intermediate products were identified by GC-MS techniques. Trichloroethylene and chloroform were identified as reaction intermediates.