• Title/Summary/Keyword: Intermediate temperature

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Photolysis of Diazotetracyanocyclopentadiene and Identification of Carbene Intermediate (디아오화합물의 광분해반응과 카르벤 중간체의 확인)

  • Kim, Min-Sik;Eom, Tae-Seop;Seong, Dae-Dong
    • The Korean Journal of Food And Nutrition
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    • v.7 no.1
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    • pp.29-35
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    • 1994
  • Photolysis of diazotetracyanocyclopentadiene has been investigated by means of IR and UV-vis spec troscopy in Ar matrix. Parent carbene is produced in low yield and could be detected by UV-vis spectroscopy and IR spectroscopy. The carbene produced from the diazo compound is very photolabile and also decay thermally at temperature as low as 10K. When the diazo compound is photolyzed the Arrhenius plots show a tunneling effect that is not shown as non linearity.

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Reflection and refraction of plane waves in layered nonlocal elastic and anisotropic thermoelastic medium

  • Lata, Parveen
    • Structural Engineering and Mechanics
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    • v.66 no.1
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    • pp.113-124
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    • 2018
  • In the present paper, we have considered a layered medium of two semi-infinite nonlocal elastic solids with intermediate transversely isotropic magnetothermoelastic solid. The intermediate slab is of uniform thickness with the effects of two temperature, rotation and Hall current and with and without energy dissipation. A plane longitudinal or transverse wave propagating through one of the nonlocal elastic solid half spaces, is made incident upon transversely isotropic slab and it results into various reflected and refracted waves. The amplitude ratios of various reflected and refracted waves are obtained by using appropriate boundary conditions. The effect of nonlocal parameter on the variation of various amplitude ratios with angle of incidence are depicted graphically. Some cases of interest are also deduced.

Physicochemical and Electrical Characterization of Polyaniline Induced by Crosslinking, Stretching, and Doping

  • 류광선;장순호;강성구;오응주;요철현
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.333-336
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    • 1999
  • The polyaniline films with various insoluble parts are fabricated. The oxidation state (1-y) of these polyaniline is 0.53 and 0.54, respectively. To control the interchain and intrachain interaction of the polymer, the polyaniline films are stretched with appropriate ratio. The insoluble part of polyaniline synthesized at room temperature (low molecular weight) is 12%-76% and that of polyaniline synthesized at 0 'IC (intermediate molecular weight) is 65%-89%. The low molecular weight polyaniline films with various drawing ratios have amorphous structure. In the intermediate weight polyaniline films, the crystallinity of films increases with drawing ratio as well as insoluble part. The difference of the insoluble part affects electrical conductivity which is increased dramatically with draw ratio. In particular, the higher insoluble part caused greater increase in electrical conductivity.

Numerical study on the post-earthquake fire behavior of intermediate steel moment frames

  • Parvizizadeh, Shayan;Kazemi, Mohammad Taghi
    • Earthquakes and Structures
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    • v.22 no.2
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    • pp.137-145
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    • 2022
  • As steel is highly sensitive to temperature variations, fire exposure is more destructive in the case of steel structures in comparison to the concrete ones. The performance of an intermediate three-story steel moment frame with 4 spans was studied under the service load, thermal load and post-earthquake fire in this paper. Also, the effects of passive fire-protection materials such as ordinary cement-based and fire-retardant coatings were investigated. To model and analyze the structure; Abaqus software is utilized. In order to apply the earthquake effect, the push-over analysis method is employed. Changes in the stories deflection, endurance time and growth of nonlinear regions due to losses in the steel stiffness and strength, are among the issues considered in this study. As an interesting finding, the beams protected by ordinary cement-based coating could sustain the fire exposure at least for 30 minutes in all cases. The mentioned time is increased by employing a new fire-retardant protection, which could prevent significant loss in the structure resistance against fire, even after 60 minutes of exposure to fire.

Study on Rate-Limiting Factors with a Heavy Loaded Biofilter

  • Son, Hyun-Keun
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.E2
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    • pp.74-81
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    • 2007
  • Feasibility test for a biofilter was performed to treat VOCs. The applied loading rate to the biofilter was calculated between 60 to $3,700\;kg\;COD/m^3$. Trimethyl-pentene and trimethyl-hexene were the two most dominant compounds and they occupy about 85 percent. During the acclimation period, it is desirable for a biofilter to receive relatively lower VOCs concentration and flow rate, until it can adjust to new substrate and operational environment. Temperature at various points inside the biofilter reactor was observed with more than 23 temperature sensors. With steam heating, temperatures of the top sections of the media were greater than those of bottom sections. Without steam heating, intermediate stages generally had higher temperature measurement than those of bottom and top stages. Because the pH values for different biofilter materials vary significantly, measurement of the pH for the mixture of different combinations of biofilter materials is necessary. Based on the types and brands of media, the measured pH ranged from 5.38 to 9.10. The range of measured pH of different mixtures with perlite, compost, saw dust, peat moss, limestone, vermiculite was 7.05 to 8.62.

Analysis of Temperature dependent Thermal Expansion Behavior in MMCs for Electronic packaging (전자 패키징용 금속복합재료의 온도에 따른 열팽창 특성)

  • 정성욱;남현욱;정창규;한경섭
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.73-76
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    • 2002
  • This study developed SiC/Al composites for electronic packaging to which reinforcements were added with the volume fractions of 49%, 56% and 63% by the squeeze casting method. 0.8 wt.% of the inorganic binder as well as the $Al_2O_3$ fiber and SiC particles with the volume fraction of 1:10 were added to the SiC/Al composites For the produced SiC/Al composites, the CTEs (coefficients of thermal expansion) were measured from 30 to $300^{\circ}C$ and compared with the FEM numerical simulation to analyze the temperature dependent properties. The experiment showed the CTEs of SiC/Al composites that were intermediate values of those of Rule of Mixture and Turner's Model. The CTEs were close to Turner's Model in the room temperature and approached the Rule of Mixture as the temperature increases. These properties analyzed from the difference of the average stress acting between the matrix and the reinforcements proposed in this study

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A New Method of HTS Material Synthesis by Combination of MCA and SHS

  • Korobova, N.;Soh, Dea-Wha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1270-1273
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    • 2004
  • The combination of methane-chemical activation and Self-propagating High-temperature synthesis (SHS) has widened the possibilities for both methods. For YBCO systems the investigation showed that a short-term mechano-chemical activation of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors of YBCO composition with a grain size d < $1{\mu}m$ is developed. The specific feature of the technique is formation of the $YBa_2Cu_3O_{7-x}$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors (HTS) are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples investigated.

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Laser Thomson Scattering for Measuring Plasma Temperature and Density in ICP

  • Seo, Byeong-Hun;Yu, Sin-Jae;Kim, Jeong-Hyeong;Jang, Hong-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.144-144
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    • 2011
  • Diagnostics of plasma density and temperature play an important role for monitoring plasma processing and Laser Thomson scattering is a one of the most accurate diagnostic technique for measuring plasma density and temperature because of none-perturbation to plasma among various diagnostic techniques invented to measure plasma density and temperature. I will briefly review Laser Thomson scattering experiment performed in KRISS and difficulties for measuring the electron velocity distribution such as Gaussian due to low signal-to-noise ratio with showing results that we got until now. This work is an intermediate step in a process that we will get a reliable data which shows physical phenomenon of plasma compared with other diagnostic techniques and results.

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A Numerical study on current density and temperature distributions of IT-SOFC (IT-SOFC의 전류밀도 및 온도분포에 관한 수치해석 연구)

  • Sohn, Sang-Ho;Lee, Kyu-Jin;Nam, Jin-Hyun;Kim, Charn-Jung
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3067-3072
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    • 2008
  • A two-dimensional model for anode-supported IT-SOFCs is proposed in order to accurately consider the heat and mass transport processes with a fully-developed axial velocity profile in channel flow. A comprehensive micro model is employed to describe the electrochemical reaction in anode and cathode of SOFCs. This paper investigates the effects of operational parameters (inlet temperature, the amount of flow rate, and air flow rate) including flow configurations (co-flow and counter-flow) on the current density and temperature distributions in the IT-SOFCs.

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Combination of MCA and SHS for Material Synthesis

  • Soh, Dea-Wha;N., Korobova
    • Journal of the Speleological Society of Korea
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    • no.78
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    • pp.1-8
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    • 2007
  • The combination of mechano-chemical activation (MCA)and Self-propagating High-temperature Synthesis (SHS) has widened the technical possibilities for both methods. For YBCO systems the investigation showed that a short-term MCA of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors (HTS) of YBCO composition with a grain size d <1m is developed using combination of MCA and SHS. The specific feature of the technique is formation of the $YBa_2Cu_3O_7-$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples.