• Title/Summary/Keyword: Interfacial layer

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Bulk Heterojunction Organic Photovoltaics- Nano Morphology Control and Interfacial Layers

  • Kim, Gyeong-Gon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.59.2-59.2
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    • 2012
  • Polymer solar cells utilize bulk heterojunction (BHJ) type photo-active layer in which the electron donating polymer and electron accepting $C_{60}$ derivatives are blended. We found there is significant charge recombination at the interface between the BHJ active layer and electrode. The charge recombination at the interface was effectively reduced by inserting wide band gap inorganic interfacial layer, which resulted in efficiency and stability enhancement of BHJ polymer solar cell.

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Failure and Deformation Analyses of 3-ply Mg/Al/STS Clad-Metalin Bending (굽힘시험시의 Mg/Al/STS 3층 클래드재의 변형 및 파단특성 분석)

  • Kim, In-Kyu;Song, Jun-Young;Hwan, Oh-Ki;Hong, Sun Ig
    • Korean Journal of Metals and Materials
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    • v.50 no.5
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    • pp.345-351
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    • 2012
  • A three-point bending test was performed on roll-bonded Mg/Al/STS clad-metal plates under two different testing conditions (Mg layer in tension, or STS in tension) and their mechanical response and fracture behavior were investigated. Bending strength was found to be greater under the condition of Mg layer in tension. Heat treatment at $200^{\circ}C$ increased the bending formability, suggesting the interfacial strength increased at $200^{\circ}C$. Under the condition of Mg in tension, the clad heat-treated at $300^{\circ}C$ and $400^{\circ}C$ fractured in two steps, with the first step associated with the interfacial fracture between Mg and Al, and the second the fracture of the Mg layer. STS/Al layers were found to be bent without complete fracture. Under the condition of STS in tension, the clad heat-treated at $300^{\circ}C$ and $400^{\circ}C$ exhibited a very small load drop at the displacement, which is similar to that of the first load drop associated with the interfacial fracture under the condition of Mg in tension. In this case, no interfacial cracks were found and the complete cut-through fracture of clad was observed at low temperature heat treatment conditions, suggesting excellent interfacial strength. When the heat treatment temperature was higher than $300^{\circ}C$, interfacial cracks were observed. The local stress condition and the position of the interface with respect to the surface were found to have a great influence on the fracture behaviors of clad metals.

Interfacial Engineering of Polymer Light Emitting Diode

  • Chen, Show-An
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.165-167
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    • 2007
  • The performance of polymer light emitting diode can be improved significantly by interfacial engineering on anode and/or cathode through adjusting the charge injection barriers for holes and electrons. Studies involve CFx and SAM modifications on ITO, thickness and delay time to baking of PEDOT:PSS, and electron injection/hole blocking layer.

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Pore Size Control of a Highly Transparent Interfacial Layer via a Polymer-assisted Approach for Dye-sensitized Solar Cells

  • Lee, Chang Soo;Lee, Jae Hun;Park, Min Su;Kim, Jong Hak
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.392-399
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    • 2019
  • A highly transparent interfacial layer (HTIL) to enhance the performance of dye-sensitized solar cells (DSSCs) was prepared via a polymer-assisted (PA) approach. Poly(vinyl chloride)-graft-poly(oxyethylene methacrylate) (PVC-g-POEM) was synthesized via atom-transfer radical polymerization (ATRP) and was used as a sacrificial template. The PVC-g-POEM graft copolymer induced partial coordination of a hydrophilic titanium isopropoxide (TTIP) sol-gel solution with the POEM domain, resulting in microphase separation, and in turn, the generation of mesopores upon calcination. These phenomena were confirmed using Fourier-transform infrared (FT-IR) spectroscopy, UV-visible light transmittance spectroscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD) analysis. The DSSCs incorporating HTIL60/20 (consisting of a top layer with a pore size of 60 nm and a bottom layer with a pore size of 20 nm) exhibited the best overall conversion efficiency (6.36%) among the tested samples, which was 25.9% higher than that of a conventional blocking layer (BL). DSSC was further characterized using the Nyquist plot and incident-photon to electron conversion efficiency (IPCE) spectra.

Bond-slip constitutive model of concrete to cement-asphalt mortar interface for slab track structure

  • Su, Miao;Dai, Gonglian;Peng, Hui
    • Structural Engineering and Mechanics
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    • v.74 no.5
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    • pp.589-600
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    • 2020
  • The bonding interface of the concrete slab track and cement-asphalt mortar layer plays an important role in transferring load and restraining the track slab's deformation for slab track structures without concrete bollards in high-speed railway. However, the interfacial bond-slip behavior is seldom considered in the structural analysis; no credible constitutive model has been presented until now. Elaborating the field tests of concrete to cement-asphalt mortar interface subjected to longitudinal and transverse shear loads, this paper revealed its bond capacity and failure characteristics. Interfacial fractures all happen on the contact surface of the concrete track slab and mortar-layer in the experiments. Aiming at this failure mechanism, an interfacial mechanical model that employed the bilinear local bond-slip law was established. Then, the interfacial shear stresses of different loading stages and the load-displacement response were derived. By ensuring that the theoretical load-displacement curve is consistent with the experiment result, an interfacial bond-slip constitutive model including its the corresponding parameters was proposed in this paper. Additionally, a finite element model was used to validate this constitutive model further. The constitutive model presented in this paper can be used to describe the real interfacial bonding effect of slab track structures with similar materials under shear loads.

A Characteristic of Fe-Cu Interfacial Reaction in the Hydraulic Cylinder Block for Vehicle Parts (수송기기 유압 실린더 블록 재료의 Fe-Cu 계면반응 특성)

  • Kim, Hae-Ji;Kim, Nam-Kyung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.3 no.1
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    • pp.90-94
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    • 2004
  • Generally, a hydraulic cylinder block which is one of a vehicle parts that plays Important role in excavator power transmission, has copper alloy separation phenomenon by sliding motion between metals in high pressure condition. In this paper, to solve this problem, the interfacial reaction layer of Fe-Cu With SCM440 and copper alloy is studied through the melting method. As the result of this study, it is found that the interfacial reaction layer of $1{\mu}m$ created in the interface of Fe-Cu which has very strong physical bonding. It has been also confirmed that the melting method can improve life of the hydraulic cylinder block.

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Characteristics of the plume formed by the buoyant discharges from the river

  • Kim, Ki-Cheol;Kim, Sung-Bo
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.8
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    • pp.981-994
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    • 2014
  • Density currents formed by buoyancy discharges from rivers are numerically studied using non-dimensional two layer model including Coriolis acceleration, bottom stress, interfacial friction. Some typical numbers such as Froude number, densimetric Froude number and Kelvin number are obtained and some characteristic scales are defined as a result of non-dimensionalization of the governing equations. Besides the Coriolis effect, the configurations of bottom topography, bottom friction coefficient and interfacial friction are found to significantly affect the propagation of the warm water plume. Frontal position can fastly propagate in the case of large density difference between the two layers and small interfacial friction. Left side boundary current is easily formed under the small interfacial friction. With large Kelvin number, both right and left side boundary currents are formed. Wave-like disturbances and eddies are easily formed under the high Froude number.

Interfacial Magnetic Anisotropy of Co90Zr10 on Pt Layer

  • Gil, Jun-Pyo;Seo, Dong-Ik;Bae, Gi-Yeol;Park, Wan-Jun;Choe, Won-Jun;No, Jae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.356.2-356.2
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    • 2014
  • Spin Transfer Torque (STT) is of great interest in data writing scheme for the Magneto-resistive Random Access Memory (MRAM) using Magnetic Tunnel Junction (MTJ). Scalability for high density memory requires ferromagnetic electrodes having the perpendicular magnetic easy axis. We investigated CoZr as the ferromagnetic electrode. It is observed that interfacial magnetic anisotropy is preferred perpendicular to the plane with thickness dependence on the interfaces with Pt layer. The anisotropy energy (Ku) with thickness dependence shows a change of magnetic-easy-axis direction from perpendicular to in-plane around 1.2 nm of CoZr. The interfacial anisotropy (Ki) as the directly related parameters to switching and thermal stability, are estimated as $1.64erg/cm^2$ from CoZr/Pt multilayered system.

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Analysis of Interfacial Layer between Alumina and Silica/Silicon Substrate (알루미나와 실리카/실리콘 기판의 계면 분석)

  • 최일상;김영철;장영철
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.252-254
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    • 2002
  • Metal oxides with high dielectric constants have the potential to expend scaling of transistor gate capacitance beyond that of ultrathin silicon dioxide. However, during deposition of most metal oxides on silicon, an interfacial region of SiOx is formed and limits the specific capacitance of the gate structure. We deposisted aluminum oxide and examined the composition of the interfacial layer by employing high-resolution X-ray photoelectron spectroscopy and X-ray reflectivity. We find that the interfacial region is not pure SiO$_2$, but is composed of a complex depth-dependent ternary oxide of $AlSi_xO_y$ and the pure SiO$_2$.

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Evolution of Interfacial Microstructure in Alumina and Ag-Cu-Zr-Sn Brazing Alloy (알루미나/Ag-Cu-Zr-Sn 브레이징 합금계면의 미세조직)

  • Kim, Jong-Heon;Yoo, Yeon-Chul
    • Transactions of Materials Processing
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    • v.7 no.5
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    • pp.481-488
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    • 1998
  • The active metal brazing was applied to bond Alumina and Ni-Cr steel by Ag-Cu-Zr-Sn alloy and the interfacial microstructure and reaction mechanism were investigated. Polycrystalline monoclinic $ZrO_2$ with a very fine grain of 100-150 nm formed at the alumina grain boundary contacted with Zr segregation layer at the interface. The $ZrO_2$ layer containing the inclusions and cracks were developed at the boundary of inclusion/$ZrO_2$ due to the difference in specific volume. The development of $ZrO_2$ at the interface was successfully explained by the preferential penetration of $ZrO_2$ at the interface was successfully explained by the preferential penetration of Zr atoms a higher concentration of oxygen and a high diffusion rate of Al ions into molten brazing alloy.

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