• Title/Summary/Keyword: Interfacial area

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Mo-Mn Metallizing on Sintered Alumina and It합s Bond Strength (소결 알루미나의 금속접합 및 접합강도에 관한 연구)

  • Lee, Joon;Kim, Young-Tai;Jang, Sung-Do;Son, Yong-Bae
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.58-70
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    • 1985
  • The bond strength of metal to ceramic sealing in Mo-Mn metallizing was investigated by examining the effects of flux composition in alumina ceramics particle size of molybdenum metal powder wet hydrogen atmosphere and temperature in metallizing. The maximum bond strength was obtained when the glass phase filled almost all the microstructural cavities around the interfacial area with few micropores. Such a favorable microstrcutre waas formed and maximum bond strength was observed between 130$0^{\circ}C$. Also the metal to ceramic bond strength was increased using finer molybdenum metal powder than coarse powder. When content of $SiO_2$ in the flux of alumina ceramics was constant metal to ceramic bond strength was improved with increasing the ratio of CaO to MgO in the flux.

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New Polymer Electrolytes for Solid State Dye-Sensitized Solar Cells (고분자 전해질을 이용한 고체형 염료감응 태양전지)

  • Kang, Yong-Soo;Lee, Yong-Gun;Kang, Moon-Sung;Kim, Jong-Hak;Char, Kook-Chen
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.231-234
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    • 2007
  • The solid state dye-sensitized saolrc cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5% at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the effciency has also been investigated.

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High Durability of Stack for Automobile (차량용 스택 고출력 내구성능)

  • Kim, Young-Min;Lee, Jong-Hyun;Yoon, Jong-Jin;Cho, Jang-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.557-560
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    • 2007
  • The durability of 80 kW class stack module was tested in hydrogen recirculation and non-recirculation systems with the condition of 300Amps (constant current mode) and hydrogen pulse purging (10 seconds close/0.8 seconds open). A localized membrane failure in the interfacial area between membrane and sub-gasket, carbon corrosion in cathode electrode, and Pt dissolution/extraction have been found through the post mortem analysis such as CV, Impedance, SEM, and so on. The main reason of these mechanisms will be discussed in this study.

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Solid State Dye-Sensitized Solar Cells Employing Polymer Electrolytes : Oligomer Approach

  • Kang, Yong-Soo;Lee, Yong-Gun;Kang, Moon-Sung;Kim, Jong-Hak;Char, Kook-Choen
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.63-64
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    • 2006
  • The solid state dye-sensitized solar cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5 % at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs: "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the efficiency has also been investigated.

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Preparation of Quasi-ordered Hollow $SnO_2$ Hemispheres Using Colloidal Templating Route and Its Application to Gas Sensors (콜로이달 템플레이팅 기술을 통한 준정렬된 다공성 반구구조의 $SnO_2$ 제작과 가스 센서로의 응용)

  • Chang, Young-Eun;Yang, Dae-Jin;Kim, Dong-Hoon;Cho, Nam-Gyu;Kim, Ho-Gi;Kim, Il-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.282-282
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    • 2008
  • Quasi-ordered arrays of hollow $SnO_2$ hemispheres were prepared by utilizing the colloidal templating route and RF-sputtering methods. Hollow $SnO_2$ hemispheres with shell thickness of 20nm exhibited an uniform continuity and open porosity, resulting in high gas sensitivity due to enhanced surface area as well as reduced interfacial effects. Multilayered hollow $SnO_2$ hemispheres and hollow $SnO_2$ hemispheres with controlled wall thickness were fabricated by controlling processing steps.

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Modeling Heterogeneous Wall Nucleation in Flashing Flow of Initially Subcooled Water

  • Park, Jong-Woon
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.241-246
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    • 1996
  • An analytical model to calculate rate of vapor generation due to heterogeneous wall nucleation in flashing flow is developed. In the present model, an important parameter of the vapor generation term, i.e. nucleation site density is calculated by integrating its probability distribution function with respect to active cavity radius. The limits of integration are minimum and maximum active cavity radii, and these are formulated using an active cavity model for nucleate boiling. This formulation, therefore. can statistically account for the effect of surface specific thermo-physical and geometric conditions on the vapor generation rate and flashing inception. For verifying the adequacy of the present model, steady state two-fluid and the bubble transport equations are solved with applicable constitutive equations. The applicable region of the bubble transport equation is also extended to churn-turbulent flow regime to predict interfacial area concentration at high void fraction. Predicted results in terms of axial pressure and void fraction profiles along the channels are compared with experimental data of Super Moby Dick and BNL Reasonable agreements have been achieved and this shows the applicability of the present model to flashing flow analysis.

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Measurement of thermal contact resistance at Cu-Cu interface

  • Kim, Myung Su;Choi, Yeon Suk
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.2
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    • pp.48-51
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    • 2013
  • The thermal contact resistance (TCR) is one of the important components in the cryogenic systems. Especially, cryogenic measurement devices using a cryocooler can be affected by TCR because the systems have to consist of several metal components in contact with each other for heat transferring to the specimen without cryogen. Therefore, accurate measurement and understanding of TCR is necessary for the design of cryogenic measurement device using a cryocooler. The TCR occurs at the interface between metals and it can be affected by variable factors, such as roughness of metal surface, contact area and contact pressure. In this study, we designed TCR measurement system at various temperatures using a cryocooler as a heat sink and used steady state method to measure the TCR between metals. The copper is selected as a specimen in the experiment because it is widely used as a heat transfer medium in the cryogenic measurement devices. The TCR between Cu and Cu is measured for various temperatures and contact pressures. The effect of the interfacial materials on the TCR is also investigated.

Structures and Physical Properties of in situ composite based on Liquid Crystalline Polymer and Poly(ethylene 2,6-naphthalate) Blends

  • Yoo, Hyun-Oh;Kim, Seong-Hun;Hong, Soon-Man;Hwang, Seung-Sang
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.236-239
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    • 1998
  • The in situ composites based on poly(ethylene 2,6-naphthalate) and thermotropic liquid crystalline polymer (LCP) have been an area of increasing interest and study, since LCP exhibits high chemical stabilities and excellent thermo mechanical properties such as high strength and modulus. In a binary, however, poor compatibility and interfacial adhesions between two phases frequently results in deteriorated mechanical properties. (omitted)

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Spreading Kinetics of Poly(diisobutylene maleic acid) at the Air-water Interface

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.661-668
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    • 2015
  • The surface rheological properties of polymer monolayer show complicated non-linear viscoelastic flow phenomena when they are subjected to spreading flow. These spreading flow properties are controlled by the characteristics of flow units. The kinetics of the formation of an interfacial film obtained after spreading poly(diisobutylene maleic acid) at air-water interface were studied by measuring of the surface pressure with time. The experimental data were analyzed theoretically according to a nonlinear surface viscoelastic model. The values of dynamic modulus, static modulus, surface viscosities and rheological parameters in various area/ monomer were obtained by appling experimental data to the equation of nonlinear surface viscoelastic model.

Creep-Rupture and Fatigue Properties of Transient Liquid Phase Bonded Joints of Ni-Base Single Crystal Superalloy (액상확산접합한 Ni기 단결정 초내열합금의 크리프 파단 및 피로특성)

  • 김대업
    • Journal of Welding and Joining
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    • v.19 no.1
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    • pp.82-87
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    • 2001
  • The creep-rupture and low cycle fatigue properties of transient liquid phase bonded joints of Ni-base single crystal superalloy, CMSX-2 was investigated using MBF-80 insert metal. The (100) orientation of bonded specimen was aligned perpendicular to the joint interface. CMSX-2 was bonded at 1523K for 1.8ks in vacuum, optimum bonding condition. The creep rupture strength and rupture lives of the joints were the almost identical to ones of the base metal. SEM observation of the fracture surfaces of joints after creep rupture test revealed that the fracture surfaces classified three types of region, ductile fracture surface, cleavage fracture surface and interfacial fracture surface. The low cycle fatigue properties of the joints were also the same level as those of base metal. The elongation and reduction of area values of joints were comparable to those of base metal while fell down on creep rupture condition of high temperature.

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