• 제목/요약/키워드: Interfacial area

검색결과 194건 처리시간 0.026초

모세관 모델을 이용한 불포화토양의 물-가스 접촉면적 및 가스공극 크기분포의 계산 및 검증 (Capillary Bundle Model for the Estimation of Air-water Interfacial Area and the Gas-filled Pore Size Distribution in Unsaturated Soil)

  • 김헌기
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권1호
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    • pp.1-7
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    • 2021
  • Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

DEVELOPMENT OF INTERFACIAL AREA TRANSPORT EQUATION

  • ISHII MAMORU;KIM SEUNGJIN;KELLY JOSEPH
    • Nuclear Engineering and Technology
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    • 제37권6호
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    • pp.525-536
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    • 2005
  • The interfacial area transport equation dynamically models the changes in interfacial structures along the flow field by mechanistically modeling the creation and destruction of dispersed phase. Hence, when employed in the numerical thermal-hydraulic system analysis codes, it eliminates artificial bifurcations stemming from the use of the static flow regime transition criteria. Accounting for the substantial differences in the transport mechanism for various sizes of bubbles, the transport equation is formulated for two characteristic groups of bubbles. The group 1 equation describes the transport of small-dispersed bubbles, whereas the group 2 equation describes the transport of large cap, slug or chum-turbulent bubbles. To evaluate the feasibility and reliability of interfacial area transport equation available at present, it is benchmarked by an extensive database established in various two-phase flow configurations spanning from bubbly to chum-turbulent flow regimes. The geometrical effect in interfacial area transport is examined by the data acquired in vertical fir-water two-phase flow through round pipes of various sizes and a confined flow duct, and by those acquired In vertical co-current downward air-water two-phase flow through round pipes of two different sizes.

평면 교반조에서의 $CO_2$ 기체흡수에서 교반속도에 따른 기-액 계면 면적에 관한 연구 (A Study on Gas-Liquid Interfacial Areas with the Stirrer Spends for A$CO_2$bsorption in Agitated Vessel)

  • 박문기;문영수
    • 한국환경과학회지
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    • 제3권4호
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    • pp.403-408
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    • 1994
  • Catalytic slurry reactors, in which a solid maintained in the rom of fine particles suspended in a liquid, are frequently used in chemical and biochemical and industries. In these processes the particle loading is normally low so that the effects of particles on the liquid-film mass transfer coefacent and the gas-liquid interface area are assumed to be negligible. But it is known from the works, amongst others, that the finely powdered activated carbon can increase the gas-liquid mass transfer significantly in surface-aerated reactors. The stirred cell (13.2cm inside diameter) contained four baffles and at the stirring speeds range of 80 ∼ 300ppm, the gas-liquid interfacial area could be considered as that of the cross section of the vessel (that is, 130.1cm2). When the stirrer speeds were increased, the effective interfacial area was slightly higher than the geometric area and was obtained experimentally from the Danckwerts plots. Key Words : gas-liquid interfacial area, Duckwert's Plot stirred dell. mass transfer coefficient.

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Characteristics of Gas-liquid Mass Transfer and Interfacial Area in a Bubble Column

  • Lim, Dae Ho;Yoo, Dong Jun;Kang, Yong
    • Korean Chemical Engineering Research
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    • 제53권3호
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    • pp.315-320
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    • 2015
  • Characteristics of gas-liquid mass transfer and interfacial area were investigated in a bubble column of diameter and height of 0.102 m and 2.5 m, respectively. Effects of gas and liquid velocities on the volumetric gas-liquid mass transfer coefficient ($k_La$), interfacial area (a) and liquid side true mass transfer coefficient ($k_L$) were examined. The interfacial area and volumetric gas-liquid mass transfer coefficient were determined directly by adopting the simultaneous physical desorption of $O_2$ and chemical absorption of $CO_2$ in the column. The values of $k_La$ and a increased with increasing gas velocity but decreased with increasing liquid velocity in the bubble column which was operated in the churn turbulent flow regime. The value of $k_L$ increased with increasing gas velocity but did not change considerably with increasing liquid velocity. The liquid side mass transfer was found to be related closely to the liquid circulation as well as the effective contacting frequency between the bubbles and liquid phases.

Span 20과 Tween계 계면활성제의 물/공기 계면에서의 분자면적과 계면장력 거동 (Molecular Area and Interfacial Tension Behavior of Span 20 and Tween series surfactants at water/air interface)

  • 김천희
    • 한국의류학회지
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    • 제24권7호
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    • pp.1065-1072
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    • 2000
  • The molecular areas and the interfacial tension behavior of ten nonionic surfactants, i.e., Span 20 and Tween 20, 40, 60. 80, 21, 61, 81, 65, & 85 are tested to assay their effects on the wetting and liquid retention properties of hydrophilic and hydrophobic fibrous materials. The molecular areas at water/air interface are derived from Gibbs’adsorption equations. The following conclusions are drawn from the results: 1) Span 20 is efficient in lowering the interfacial tension and effective in adsorption at the water/air interface, resulting in the low interfacial tension at critical micelle concentration (${\gamma}$$_{CMC}$) and a small molecular area($\omega$), 2) when the hydrophiles of the surfactants are constant, $\omega$’s increase as hydrophobe carbon numbers of the surfactants increase, 3) when the hydrophobes are constant, ${\gamma}$$_{CMC}$’s and $\omega$’s increase as the hydrophile ethylene oxide units increase, indicating effectiveness and efficiency is parallel in this case, 4) the ethylene oxide unit length as a hydrophile has greater influence on u than the hydrophobe chain length.han the hydrophobe chain length.gth.

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표면 코팅 유무에 따른 경량골재의 EIS 특징 (EIS Properties of Lightweght Aggregate According to Surface Coating)

  • 편명장;정수미;김주성;김호진;박선규
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2022년도 가을 학술논문 발표대회
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    • pp.107-108
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    • 2022
  • In recent years, the construction industry has a tendency to increase of high-rise builidngs. High rise buildings can use limited space efficiently. But High rise buildings have problem that have extremely heavy weight. Various studies are being conducted to reduce the weight of buildings. Although lightweight aggregate is a meterial that can effectively reduce the weight of buildings, the strength of the aggregate itself is weak and the absorption rate is high, so the strength of the ITZ(Interfacial Transition Zone) area is weak. Therefore, it is essential to improve the interfacial area when using lightweight aggregates. In this study, an experiment was conducted to improve the adhesion between the aggregate and cement paste and to strengthen the interfacial area by coating the surface of the lighteight aggregate with Blast Furnace Slag. To confirm the improvement, compressive strength and EIS(Electrochemical Impedance Spectroscopy) measurements were perfromed. Using EIS, the change in electrical resistance of the cement hardened body was confirmed. As a result, it was confirmed that the lightweight aggregate coated on the surface showed highter compressive strength and electrical resistance than the non-coated lightweight aggregate, and that the coating material was filled in the interfacial area and inside the aggregate that helped to strengthen the compresssive strength and higher electrical resistance.

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인장전단시험을 이용한 TRIP1180강의 계면파단특성 평가 (Evaluation of Resistance Spot Weld Interfacial Fractures in Tensile-Shear Tests of TRIP 1180 Steels)

  • 박상순;최영민;남대근;김영석;유지훈;박영도
    • Journal of Welding and Joining
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    • 제26권6호
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    • pp.81-91
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    • 2008
  • The weldability of resistance spot welding of TRIP1180 steels for automobile components investigated enhance in order to achieve understanding of weld fracture during tensile-shear strength (TSS) test. The main failure modes for spot welds of TRIP1180 steels were nugget pullout and interfacial fracture. The peak load to cause a weld interfacial failure was found to be related to fracture toughness of the weld and the weld diameter. Although interfacial fracture occurred in the spot welded samples, the load-carrying capacity of the weld was high and not significantly affected by the fracture mode. Substantial part of the weld exhibits the characteristic dimple (or elongated dimple) fractures on interfacial fractured surface also, dimple fracture areas were drawmatically increased with heat input which is propotional to the applied weld current. In spite of the high hardness values associated with the martensite microstructures due to high cooling rate. The high load-carrying ability of the weld is directly associated with the area of ductile fracture occurred in weld. Therefore, the judgment of the quality of resistance spot welds in TRIP1180 steels, the load-carrying capacity of the weld should be considered as an important factor than fracture mode.

계면면적 수송방정식을 적용한 이상유동 해석코드 개발 (CFD Code Development for a Two-phase Flow with an Interfacial Area Transport Equation)

  • 배병언;윤한영;어동진;송철화;박군�x
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2696-2701
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    • 2007
  • For the analysis of a two-phase flow, the interaction between two phases such as the interfacial momentum or heat transfer is proportional to the interfacial area. So the interfacial area concentration (IAC) is one of the most important parameters governing the behavior of each phase. This study focuses on the development of a computational fluid dynamics (CFD) code for investigating a boiling flow with a one-group IAC transport equation. It was based on the two-fluid model and governing equations were calculated by SMAC algorithm. For checking the robustness of the developed code, the experiment of a subcooled boiling in a vertical annulus channel was analyzed to validate the capability of the IAC transport equation. As the results, the developed code was confirmed to have the capability in predicting multi-dimensional phenomena of vapor generation and propagation in a subcooled boiling.

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Porous Ceramic Fibers: Materials and Applications

  • 김일두
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.4-4
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    • 2011
  • Extensive research efforts are directed toward the development of highly sensitive gas sensors using novel nanostructured materials. Among the different strategies for producing sensor devices based on nanosized building blocks, polymeric fiber templating approach which is combined by chemical and physical synthesis routes was attracted much attention. This unique morphology increases the surface area and reduces the interfacial area between film and substrate. Consequently, the surface activity is markedly enhanced while deleterious interfacial effects between film and substrate are significantly reduced. Both effects are highly advantageous for gas sensing applications. In this presentation, facile synthesis of hollow and porous metal oxide nanostructures and their applications in chemical sensors will be discussed.

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Development of the Interfacial Area Concentration Measurement Method Using a Five Sensor Conductivity Probe

  • Euh, Dong-Jin;Yun, Byong-Jo;Song, Chul-Hwa;Kwon, Tae-Soon;Chung, Moon-Ki;Lee, Un-Chul
    • Nuclear Engineering and Technology
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    • 제32권5호
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    • pp.433-445
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    • 2000
  • The interfacial area concentration (IAC) is one of the most important parameters in the two-fluid model for two-phase flow analysis. The IAC can be measured by a local conductivity probe method that uses the difference of conductivity between water and air/steam. The number of sensors in the conductivity probe may be differently chosen by considering the flow regime of two-phase flow. The four sensor conductivity probe method predicts the IAC without any assumptions of the bubble shape. The local IAC can be obtained by measuring the three dimensional velocity vector elements at the measuring point, and the directional cosines of the sensors. The five sensor conductivity probe method proposed in this study is based on the four sensor probe method. With the five sensor probe, the local IAC for a given referred measuring area of the probe can be predicted more exactly than the four sensor probe. In this paper, the mathematical approach of the five sensor probe method for measuring the IAC is described, and a numerical simulation is carried out for ideal cap bubbles of which the sizes and locations are determined by a random number generator.

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