• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.730-733
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• 2001

Separation of PET and PVC is a key technology to achieve effective plastics recycling but no efficient and economically feasible method has been developed yet. The application of flotation was investigated by many researchers but the causes of the selectivity were not clarified. This paper described the adsorption mechanism of wetting agents onto plastics, using the agents which have various polarity and hydrocarbon chain length. It was found that (1) hydrophobic interaction played a predominant role for the adsorption, (2) anionic wetting agents could be adsorbed onto negatively charged plastics with the polar radicals oriented outer part of the plastics, then often depressed plastics more effectively than cationic agents, and (3) PET and PVC could be separated with dodecyamine hydrochloride and sodium dodecyl- sulfonate in the concentration ranges of 1.0$\times$10$^{[-10]}$ $^{6}$ -5.0$\times$10$^{[-10]}$ $^{5}$ and 2.0$\times$10$^{[-10]}$ $^{6}$ -1.0$\times$10$^{[-10]}$ $^{5}$ mo1/1, respectively.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.5 no.4
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• pp.19-30
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• 2002

The stability of slope using root-pile like to the reinforcements is affected by the interaction behavior mechanism of soil-reinforcements. Through the studying on the interaction in joint of its, therefore, the control roles can be find out in installed slope. In study, the stress level ratio based on the insert angle of installed reinforcements in soil used to numerical analysis, which was results from the duty direct shear test in Lab. The maximum shear strain variation on the reinforcements was observed at insert angle, which was approximately similar to the calculated angle based on the equation proposed by the Jewell. The elasto-plastic joint model on the contact area of soil-reinforcements was presumed, the reinforced soil assumed non-linear elastic model and the reinforcements supposed elastic model, respectively. The finite element analysis of assumed models was performed. The shear strain variation of non-reinforced state obtained by the FEM analysis including elasto-plastic joint elements were shown the rationality of general limit equilibrium analysis for the slope failure mode on driving zone and resistance zone, which based on the stress level step according to failure ratio. Through the variation of shear strain for the variation of inserting angle of reinforcements, the different mechanism on the bending and the shear resistance of reinforcements was shown fair possibility.

• Bulletin of the Korean Chemical Society
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• v.14 no.1
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• pp.91-95
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• 1993

In this work we have studied the spin-lattice relaxation of $^{19}$F spins in benzotrifluoride in our quest for a reliable method of discriminating the contribution due to dipolar relaxation mechanism from that due to spin-rotational mechanism for nuclear spins located on methyl or substituted methyl group in organic molecules. Over the temperature range of 248-268 K the decay of normalized longitudinal magnetization was found to be well described by a two parameter equation of the form R(t) = exp(-st){$\frac{5}{6}$exp(-s$_1$)+$\frac{1}{6}$} which was derived under the assumption that interactions in the A3 spin system are modulated randomly and predominantly by internal rotational motions of -CF_3$ top, and it was shown that the separation of contribution due to dipolar interactions from that due to spin-rotation interaction could be successfully achieved by least-square fitting of observed data to this equation. The results indicate that the spin-rotational contribution is overwhelmingly larger than that of dipolar origin over the given temperature range and becomes more deminating at higher temperature.

• Archives of Pharmacal Research
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• v.20 no.6
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• pp.579-585
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• 1997

To gain further insight into the mechanism of action of antiestrogens, we examined the interaction of antiestrogen with the estrogen receptor system and with estrogen- noncompetable antiestrogen binding sites. In addition to binding directly to the estrogen receptor, antiestrogens can be found associated with binding sites that are distinct from the estrogen receptor. In contrast to the restriction of estrogen receptors to estrogen target cells, such as those of uterus and mammary glands, antiestrogen binding sites are present in equal amounts in estrogen receptor-positive and -negative human breast cancer cell lines, such as MCF-7, T47D, and MDA-MB-231 that differ markedly in their sensitivity to antiestrogens. In order to gain greater insight into the role of these antiestrogen binding sites in the action of antiestrogens, we have examined the biopotency of different antiestrogens for the antiestrogen binding sites and that is CI628 > tamoxifen > trans-hydroxy tamoxifen > CI628M > H1285 > LY117018. This order of affinities does not parallel the affinity of these compounds for the estrogen receptor nor the potency of these compounds as antiestrogens. Indeed, compounds with high affinity for the estrogen receptor and greatest antiestrogenic potency have low affinities for these antiestrogen binding sites. Antiestrogenic potency correlates best with estrogen receptor affinity and not with affinity for antiestrogen binding sites. In summary, our findings suggested that interaction with the estrogen receptor is most likely the mechanism through which antiestrogens evoke their growth inhibitory effects.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1994.04a
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• pp.263-263
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• 1994

Annexin I is a member of the in family of calcium dependent phospholipid banding proteins and is an in vitro phospholipase $A_2$ (PLA$_2$) inhibitor. The mechanism of PLA$_2$ inhibition by annexin I is still ambiguous. The structure of annexin I was studied at the atomic level by using nuclear magnetic resonance (NMR), circular dichrotsm (CD) and fluorescence spectroscopy. Recombinant human annexin I and N-terminally truncated annexin I (1-31 deleted: d-annexin I) were purified and their NMR spectra were compared. The NMR spectra of the two were similar. When $Ca^{2+}$ ion added to annexin I ad d-annexin I, peak broadening occurred, but no significant spectroscopic change was observed. When porcine pancreatic PLA$_2$ was added to deuterium labeled annexin I, an interaction of annexin I with PLA$_2$ was observed as indicated by the disappearance and shift of several peaks in the NMR spectrum. This result supports a protein-protein interaction mechanism for PLA$_2$ inhibition by annexin I.I.

• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2357-2360
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• 2010

Kinetic studies on the pyridinolysis of aryl dithiocyclopentanecarboxyaltes 2 were carried out at $60.0^{\circ}C$ in acetonitrile. In the aminolysis of 2, the $\beta_X$ values were 0.5 - 0.8 with anilines, and there was no breakpoint. However, in the pyridinolysis of 2, biphasic Bronsted plots were obtained, with a change in slope from a large value ($\beta_X{\cong}0.7$) to a small value ($\beta_X{\cong}0.4$) at $pK_{a}^0$ = 5.2. This was attributed to a change in the rate-limiting step from breakdown to the formation of a zwitterionic tetrahedral intermediate, $T^{\pm}$, in the reaction path, with an increase in the basicity of the pyridine nucleophile. An obvious change in the cross-interaction constant ${\rho}_{XZ}$ from a large positive ($\rho_{XZ}$ = +1.02) value to a small negative value (${\rho}_{XZ}$ = -0.17) supports the proposed mechanistic change.

• Journal of the Korean Society of Safety
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• v.10 no.1
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• pp.3-8
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• 1995

The anemometer measurements were obtained from stationary hot-film probe mounted between the forward and rear rotors of a model CRP which rotated the forward and different directions. Data collection was done at several locations between rotors. To establish rotor-rotor interaction flow mechanism that contributes noise increasement of the CRP, methods of simple and the double condition-at sampling have been developed. The former uses to find similarity of the wake the later fixes the forward rotor position in time or space and permits averaging the mean wake at any fixed rotor angular location. The variation of the forward wake Is strongly depending upon the rear rotor location.

• The Journal of Korean Physical Therapy
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• v.12 no.3
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• pp.433-444
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• 2000

The purpose is paper was to discuss current concepts related to anatomic stabilizing structures of the shoulder joint complex and their clinical relevance to shoulder instability. The clinical syndrome of shoulder instability represents a wide spectrum of symtoms and signs which may produce various levels of dysfunctions, from subtle subluxations to gross joint instability. The glenohumeral joint attains functional stability through a delicate and intricate interaction between the passive and active stabilizing structures. The passive constraints include the bony geometry, glenoid labrum, and the glenohumeral joint capsuloligaments structure. Conversely, the active constraints, also referred to as active mechanism, include the shoulder complex musculature, the projprioceptive system, and the musculoligamentous relationship. The interaction of the active and passive mechanism which provide passive and active glenohumeral joint stability will be throughtly discussed in this paper

• Bulletin of the Korean Chemical Society
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• v.29 no.9
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• pp.1769-1773
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• 2008

fThe kinetics and mechanism of the reactions of Y-O-aryl phenylphosphonochloridothioates with X-pyridines are investigated in acetonitrile at 35.0 ${^{\circ}C}$. The negative value of the cross-interaction constant, $\rho$XY = −0.46, indicates that the reaction proceeds by concerted $S_N2$ mechanism. The observed $k_H/k_D$ values involving d-5 pyridine ($C_5D_5N$) nucleophiles are greater than unity (1.05-1.11). The net primary deuterium kinetic isotope effects, $(k_H/k_D)_{net}$ = 1.28-1.35, excluding the increased $pK_a$ effect of d-5 pyridine are obtained. The transition state with a hydrogen bond between the leaving group Cl and the hydrogen (deuterium) atom in the C-H(D) is suggested for the studied reaction system.

• Geomechanics and Engineering
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• v.9 no.5
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• pp.601-618
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• 2015

Soil-reinforcement interaction mechanism is an important issue in the design of geosynthetic reinforced soil structures. This mechanism depends on the soil properties, reinforcement characteristics and interaction between these two elements (soil and reinforcement). In this work the shear strength of sand/geotextile interfaces were characterized through direct and simple shear tests. The direct shear tests were performed on a conventional direct shear device and on a large scale direct shear apparatus. Unreinforced sand and one layer reinforced sand specimens were characterized trough simple shear tests. The interfaces shear strength achieved with the large scale direct shear device were slightly larger than those obtained with the conventional direct shear apparatus. Notwithstanding the differences between the shear strength characterization through simple shear and direct shear tests, it was concluded that the shear strength of one layer reinforced sand is similar to the sand/geotextile interface direct shear strength.