• Title/Summary/Keyword: Insulating characteristics

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Characteristics of Plasma Blacks Used as an Electrode of Direct Formic Acid Fuel Cell

  • Park, Young-Sook;Choi, Jong-Ho;Han, Jong-Hee;Lim, Tae-Hoon;Beak, Young-Soon;Ju, Jeh-Beck;Shon, Tae-Won;Lee, Joong-Kee
    • Carbon letters
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    • v.6 no.1
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    • pp.41-46
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    • 2005
  • Plasma carbon blacks of 20~30 nm diameter were synthesized by direct decomposition of natural gas using a hybrid plasma torch system with 50 kW direct current and 4 MHz of radio frequency. The insulating rector which inside diameter of 400 mm and length of 1500 mm, respectively was kept at 300~$400^{\circ}C$ during the preparation. The ultimate analysis of plasma carbon blacks reveals that the raw plasma carbon blacks contains a large quantity of volatile which is mainly consist of hydrogen. Therefore devolatilization of raw plasma carbon blacks were carried out at $900^{\circ}C$ for one hour under nitrogen atmosphere. The devolatilization leads to the decrease in electrical resistivity and surface oxygen functional groups of plasma carbon black significantly. In order to investigate the plasma carbon as a catalyst support, devolatilized plasma black at $900^{\circ}C$ (DPB) supported PtAu catalyst was synthesized by sodium boronhydride reduction method. Electrochemical measurements and direct formic acid fuel cell test indicated that catalytic activity of DPB supported PtAu catalyst for formic acid oxidation was similar to that of Vulcan XC-72 of commercial carbon black supported one.

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A Study on Dynamic Characteristics of EFPCD for Electrical Fire Prevention (전기화재 예방을 위한 EFPCD동작 특성에 관한 연구)

  • 이상호;오홍석
    • Fire Science and Engineering
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    • v.16 no.3
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    • pp.8-11
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    • 2002
  • Recently, the spark and the overheat due to in the failure of pressure contacts on connecting points and the momentary short circuit have been the major causes of electrical fire because these may cause the deposition and the graphite of insulating materials in electrical wiring system. Also, because in these cases the current is a surge one, the losses and faults of a communication, a home appliances, a computer and a measuring instrument may occur. Especially, in such cases, we are very difficult to detect the failure of pressure contacts on connecting points and the momentary short circuit. In this paper, we have developed an auxiliary control device, the electrical fire prevention control device(EFPCD), of an earth leakage breaker(ELB). And we can pre-vent the electrical fire caused by the spark and the overheat occurring in the failure of pressure contacts in connecting points and the momentary short circuit with the EFPCD.

Characteristic Analysis of Poly(4-Vinyl Phenol) Based Organic Memory Device Using CdSe/ZnS Core/Shell Qunatum Dots

  • Kim, Jin-U;Kim, Yeong-Chan;Eom, Se-Won;No, Yong-Han
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.289.1-289.1
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    • 2014
  • In this study, we made a organic thin film device in MIS(Metal-Insulator-Semiconductor) structure by using PVP (Poly vinyl phenol) as a insulating layer, and CdSe/ZnS nano particles which have a core/shell structure inside. We dissolved PVP and PMF in PGMEA, organic solvent, then formed a thin film through a spin coating. After that, it was cross-linked by annealing for 1 hour in a vacuum oven at $185^{\circ}C$. We operated FTIR measurement to check this, and discovered the amount of absorption reduced in the wave-length region near 3400 cm-1, so could observe decrease of -OH. Boonton7200 was used to measure a C-V relationship to confirm a properties of the nano particles, and as a result, the width of the memory window increased when device including nano particles. Additionally, we used HP4145B in order to make sure the electrical characteristics of the organic thin film device and analyzed a conduction mechanism of the device by measuring I-V relationship. When the voltage was low, FNT occurred chiefly, but as the voltage increased, Schottky Emission occurred mainly. We synthesized CdSe/ZnS and to confirm this, took a picture of Si substrate including nano particles with SEM. Spherical quantum dots were properly made. Due to this study, we realized there is high possibility of application of next generation memory device using organic thin film device and nano particles, and we expect more researches about this issue would be done.

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Terahertz Characteristics of InGaAs/InAlAs MQW with Different Excitation Laser Source

  • Park, Dong-U;No, Sam-Gyu;Ji, Yeong-Bin;O, Seung-Jae;Seo, Jin-Seok;Jeon, Tae-In;Kim, Jin-Su;Kim, Jong-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.300.2-300.2
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    • 2014
  • 테라헤르쯔(terahertz : THz)파는 0.1~10 THz 의 범위로 적외선과 방송파 사이에 광대역 주파수 스펙트럼을 차지하고 있으며 직진성, 투과성, 그리고 낮은 에너지(meV)를 가지고 있어 비 파괴적이고 무해한 장점을 지니고 있다. Ti:sapphire laser와 같은 femto-pulse source 등이 많은 발전이 되어 현재 많은 연구와 발전이 이루어지고 있다. femto-pulse source를 이용한 THz 응용에서는 높은 저항, 큰 전자이동도, 그리고 아주 짧은 전하수명의 기판을 요구하는데 저온에서 성장한(low-temperature grown : LT) InGaAs는 격자 내에 Gallium 자리에 Arsenic이 치환 하면서 AsGa antisite가 발생하여 전하수명을 짧아지는 것을 응용하여 가장 많이 이용되고 있다. 본 연구에서는 보다 높은 저항을 얻기 위하여 molecular beam epitaxy를 이용하여 semi-insulating InP:Fe 기판위에 격자 정합된 LT-InGaAs:Be/InAlAs multi quantum well (MQW)를 well과 barrier를 가각 $10{\mu}m$ 씩 100주기 성장을 하였고 Ti와 Au를 각각 30, $200{\mu}m$로 dipole antenna를 제작 하였다. 이 때 Ti:sapphire femto-pulse laser (30 fs/90 MHz)를 excitation source로 사용하였을 때 9000 pA로 LT-InGaAs epilayer (180 pA)보다 50배 이상 큰 전류 신호를 얻을 수 있었다. THz 발생과 검출을 초소형, 초경량, 고효율로 하기 위해서는 fiber-optic를 이용해야 하는데 이때 분산과 산란 손실이 가장 적은 1550 nm 대역에서 많은 연구가 이루어 졌다. 780, 1560 nm의 mode-locking laser (90 fs/100 MHz)를 사용하여 현재 많이 이용되고 있는 Ti:sapphire femto-pulse laser와 비교하여 THz 특성 변화를 확인하는 연구를 진행 하고 있다.

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Fabrication of SnO2-based All-solid-state Transmittance Variation Devices (SnO2 기반 고체상의 투과도 가변 소자 제조)

  • Shin, Dongkyun;Seo, Yuseok;Lee, Jinyoung;Park, Jongwoon
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.3
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    • pp.23-29
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    • 2020
  • Electrochromic (EC) device is an element whose transmittance is changed by electrical energy. Coloring and decoloring states can be easily controlled and thus used in buildings and automobiles for energy saving. There exist several types of EC devices; EC using electrolytes, polymer dispersed liquid crystal (PDLC), and suspended particle device (SPD) using polarized molecules. However, these devices involve solutions such as electrolytes and liquid crystals, limiting their applications in high temperature environments. In this study, we have studied all-solid-state EC device based on Tin(IV) oxide (SnO2). A coloring phase is achieved when electrons are accumulated in the ultraviolet (UV)-treated SnO2 layer, whereas a decoloring mode is obtained when electrons are empty there. The UV treatment of SnO2 layer brings in a number of localized states in the bandgap, which traps electrons near the conduction band. The SnO2-based EC device shows a transmittance of 70.7% in the decoloring mode and 41% in the coloring mode at a voltage of 2.5 V. We have achieved a transmittance change as large as 29.7% at the wavelength of 550 nm. It also exhibits fast and stable driving characteristics, which have been demonstrated by the cyclic experiments of coloration and decoloration. It has also showed the memory effects induced by the insulating layer of titanium dioxide (TiO2) and silicone (Si).

Analysis of Insulating Reliability in Epoxy Composites (Epoxy 복합체의 절연 신뢰도 해석)

  • 임중관;천민우;박용필
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.10a
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    • pp.724-728
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    • 2001
  • In this study, the dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. The dielectric breakdown characteristics origin in epoxy composites were examined and various effects of dielectric breakdown on epoxy composites were also discussed. As a result, first of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. And the breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised, the electric field is concentrated, and the acceleration of electron and the growth of electron avalanche are early accomplished. In the case of filled specimens with treating silane, the breakdown strength become much higher since this suggests that silane coupling agent improves interfacial combination and relaxs electric field concentration. Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1%, the applied field value needed to be under 21.5㎹/cm.

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Magnetic Characteristics and Annealing Effects of $NiFe/FeMn/NiFe/CoFe/Al_2O_3/CoFe/NiFe$Spin Tunneling Junctions ($NiFe/FeMn/NiFe/CoFe/Al_2O_3/CoFe/NiFe$ 스핀 터널링 접합의 자기적 특성과 열처리 효과)

  • 최연봉;박승영;강재구;조순철
    • Journal of the Korean Magnetics Society
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    • v.9 no.6
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    • pp.296-300
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    • 1999
  • Cross-shape structures of spin tunneling junctions were fabricated using DC magnetron sputtering and metal masks. The film structures were $substrate/Ta/NiFe/FeMn/NiFe/CoFe/Al_2O_3/CoFe/NiFe$ and $substrate/Ta/NiFe/CoFe/ Al_2O_3/CoFe/NiFe/FeMn/NiFe$. Fabrication conditions of insulating layer ($Al_2O_3$) and thickness and sputtering power of each film layer were varied, and maximum magnetoresistance ratio of 24.3 % was obtained. Magnetic characteristic variations in the above mentioned two structures and two types of substrates (Corning glass 7059 and Si(111)) were compared. Annealing of the junctions was performed to find out magnetic characteristic variations expected from the device fabrication. Magneoresistance Ratio were observed to maintain as-deposited value up to 150 $^{\circ}C$ annealing and then to drop rapidly after 180 $^{\circ}C$ annealing.

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The Electrical Characteristics of Ceramic Capacitor for High Voltage (고전압용 세라믹 커패시터의 전기적 특성)

  • 홍경진;김태성
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.1
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    • pp.53-59
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    • 1999
  • The ceramic capacitor was fabricated by $(Ba_{0.85}Ca_(0.15)TiO_3+ZnO$ + ZnO(from 0.1 to 0.4 mol ratio). The electrical and structural properties of ceramic capacitor for high voltage application was studied in this study. The relative rensity of ceramics capacitor has shown high in all specimen. The grain was a small size from $1.0[\mum]$ to $1.22[\mum]$ and it was increased with ZnO at 0.3 mol ratio. It was stabilized that the temperature coefficient of ceramic capacitor to change temperature had below 100[ppm] at 0.12~10[kHz]. The dielectric reIaxation time was decreased by interface polarization over $110[^{\circ}C]$ and it was increased by space polarization of paraelectric layer below $110[^{\circ}C]$. The insulating layer was increased with ZnO and dielectric constant to voltage was stabilized by 0.1[%].0.1[%].

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A Voltage Drops Computation Program on Multi-Distributed Random Loads (다중 분산부하 전압강하산정 프로그램)

  • Kang, Cha-Nyeong;Kwon, Sae-Hyuk;Cho, Sung-Pil
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.2
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    • pp.64-70
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    • 2007
  • A voltage drop in the electrical circuit must be unavoidable. The voltage drop in the electrical circuit means a loss of heat. The heat lost would change the characteristics of the insulator and thus, the insulating performance would be towered resulting in electric leakage, electric shock, power failure, fire and other accidents. Hence, an optimized design against the voltage drop in the electrical circuit must be an important factor determining safety and economy of electrical facilities. This study analyzed the effects of voltage drop on the electrical circuit for such low-voltage electrical facilities requiring the public safety foremost and subject to multi-distributed random loads as street lamps, buildings and subway stations, and thereupon, developed an optimized voltage drop computation program to enhance safety and economy of those electrical facilities.

Design and Optimization of Vibration-resistant and Heat-insulating Support Structure of Fuel Cylinder for LNG Vehicles (차량용 LNG 연료 용기의 내진동 단열지지구조 설계 및 최적화)

  • Kwon, Hyun-Wook;Hwang, In-Cheol
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.6-11
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    • 2014
  • To optimize the design of fuel cylinder for LNG vehicles, we introduced the design parameters of the inner and the outer tank of the vessel support structure by analyzing the structural characteristics of conventional design. We selected the inner and outer diameter of the hollow support bars and a dimension of the inner structure of the vessel among the design parameters for design optimization. In this study the temperature distribution and thermal stress of the support structure were evaluated by using the utility program as MSC/MARC. The evaluation criteria are first mode natural frequency, total transferred energy through support structure and thermal stress. The developed design satisfied the design criteria and it was made of prototype. The prototype was verified through three-dimensional vibration testing and thermal performance test.