• Journal of Korean Society on Water Environment
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• v.37 no.6
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• pp.442-448
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• 2021

Seawater desalination is a technology through which salt and other constituents are removed from seawater to produce fresh water. While a significant amount of fresh water is produced, the desalination process is limited by the generation of concentrated brine with a higher salinity than seawater; this imposes environmental and economic problems. In this study, characteristics of seawater from three different locations in South Korea were analyzed to evaluate the feasibility of crystallization to seawater desalination. Organic and inorganic substances participating in crystal formation during concentration were identified. Then, prediction and economic feasibility analysis were conducted on the actual water flux and obtainable salt resources (i.e. Na2SO4) using membrane distillation and energy-saving crystallizer based on multi-stage flash (MSF-Cr). The seawater showed a rather low salinity (29.9~34.4 g/L) and different composition ratios depending on the location. At high concentrations, it was possible to observe the participation of dissolved organic matter and various ionic substances in crystalization. When crystallized, materials capable of forming various crystals are expected. However, it seems that different salt concentrations should be considered for each location. When the model developed using the Aspen Plus modular was applied in Korean seawater conditions, relatively high economic feasibility was confirmed in the MSF-Cr. The results of this study will help solve the environmental and economic problems of concentrated brine from seawater desalination.

• Journal of the Korean Society of Food Science and Nutrition
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• v.37 no.2
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• pp.203-209
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• 2008

Recrystallization characteristics of salt after removing bittern and impurities from solar salt (SD) were investigated. To remove the bittern, the SD was treated at 30, 40 and $50^{\circ}C$ under 95% humidity. 86% of the bittern was removed when the SD was kept at $30^{\circ}C$ for three weeks. Total amount of impurity in SD was 6.94% (w/w) with organic impurity (5.58%) and inorganic impurity (1.36%). Most organic impurities (89%) were soluble. When the SD was roasted at $350^{\circ}C$ for 40 minutes, 90.14% of the soluble organic impurities were removed; however, the removable organic impurity was reduced, when the SD roasted for 50 minutes at $350^{\circ}C$. L* value decreased while a* and b* values increased when the SD was roasted until 40 minutes at $350^{\circ}C$. In contrast, L* value increased while a*, b* values decreased with SD roasted over 50 minutes at $350^{\circ}C$. The size of recrystallized pure salt was positively correlated to temperature and depth of salt solution, while the crystallization time was negatively correlated to temperature and salinity. Yield of recrystallized salt was negatively correlated to temperature. Overall acceptability tended to increase at low crystallization temperature and high salinity.

• Journal of Environmental Science International
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• v.2 no.4
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• pp.337-346
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• 1993

The amount of inorganic ions such as $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$, $NH_4^+$, $Cl^-$, $NO_3^-$, and $SO_4^{2-}$ in the precipitation at hongwon area were analyzed during the period of February 1991 - June 1993. Ammonium ion was analyzed using Messier and indophenol methods. Cations were determined by atomic absorption spectroscopy, and ion chromatography was used for anions. For the entire period of study, there was no particular ion which has significant]y high correlation coefficient with hydrogen ion. The correlation between $NO_3^-$, and $SO_4^{2-}$ was 0.6, which suggests that these ions may be from the same source. Most cations have high correlation with each other. In the seasonal analysis, the nitrate and sulfate ions have high correlations with the acidity in the fall and winter. The rain waters of Taeahn area showed usually high concentrations of the ions, even though the pH was much higher than that of Chongwon area. It is considered that the ions came as neutral salt in Taeahn, while $NO_x$ and $SO_x$ contributes largely to the acidity of rains in Chongwon.

• Journal of Plant Biology
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• v.26 no.2
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• pp.53-71
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• 1983

Physicochemical properties of soil, mineral cyclings, production of plants, and relationship between sodium(Na) content and progresses of plant communities were studied in a coastal salt marsh in Incheon. Contents of Na, available phosphorus(A-P) and value of electric conductivity of soil decreased in order of Salicornia herbacea, Limonium tetragonum, Phragmites communis and Zoysia sinica communities, but contents of organic matter, total nitrogen(T-N) and calcium(Ca) of soil were vice versa. Specise diversity index decreased with increase of Na content of soil with correlation coefficient of -0.82. The aboveground biomass of plant communities were 2,981 g.dw/$m^2$ in P. communis, 1,471 g.dw/$m^2$ in Z. sinica, 189g.dw/$m^2$ in S. herbacea and 71 g.dw/$m^2$ L. tetragonum, respectively. Seasonal changes of contents of inorganic nutrients per unit land area coincided with those of biomass of plant communities, however, the maximum contents of K occured earlier than the maximum biomass. Amounts of inorganic nutrients absorbed by plant were directly proportion to its biomass and it was true to reverse in restored amounts of them to soil. In turnover times of nutrients of the communities, it took the shortest time for P but the longest for Ca and P. communis community took the shortest but L. tetragonum the longest. For example, in P. communis turover time of P took one year and that of Na 1,440 years. Lack of P element, therefore, was expected in this study area.

• Journal of the Korean Chemical Society
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• v.17 no.6
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• pp.411-415
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• 1973

The reaction between cyanide ion and triphenyl methane dyes is subject to marked catalysis by cationic micelles of cetyltrimethyl ammonium bromide(CTABr) and retarded by anionic micelles of sodium lauryl sulfate(NaLS). Added salts, anions inhibit the catalysis by CTABr, and cations, especially $Zn^{++},\;Cd^{++}$ decrease the retardation of the reaction rates in the presence of NaLS. The kinetic effects of the ionic micelles are much larger in water than in ethanol-water, methanol-water, propanol-water and acetone-water, but strange solvent effects, acceleration the reaction rates, was found in the reaction with malachite green in water-methanol system.

• Journal of Environmental Science International
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• v.29 no.5
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• pp.495-506
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• 2020

This study investigated the nitrate formation process, and mass closure of Particulate Matter (PM) were calculated over the urbanized area of Jeju Island. The data for eight water-soluble inorganic ions and nineteen elements in PM_2.5 and PM₁₀ were used. The results show that the nitrate concentration increased as excess ammonium increased in ammonium-rich samples. Furthermore, nitrate formation was not as important in ammonium-poor samples as it was in previous studies. According to the sum of the measured species, approximately 45~53% of gravimetric mass of PM remained unidentified. To calculate the mass closure for both PM_2.5 and PM₁₀, PM chemical components were categorized into secondary inorganic aerosol, crustal matter, sea salt, trace matter and unidentified matter. The results by the mass reconstruction of PM components show that the portion of unidentified matter was decreased from 52.7% to 44.0% in PM_2.5 and from 45.1% to 29.1% in PM₁₀, despite the exclusion of organic matter and elemental carbon.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.489-490
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• 2006

Branched sulfonated poly(ether sulfone-ketone) copolymer was prepared with bisphenol A, 4,4-difluorobenzophenone, sulfonated chlorophenyl sulfone (40mole% of bisphenol A) and THPE (1,1,1-tris-p-hydroxyphenylethane). THPE was used 0.4 mol% of bisphenol A to synthesize branched copolymers. Organic-inorganic nano composite membranes were prepared with copolymer and a series of $SiO_2$ nanoparticles (20 nm, 4, 7 and 10 wt%). The composite membranes were cast from dimethylsulfoxide solutions. The films were converted from the salt to acid forms with dilute hydrochloric acid. The membranes were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Sorption experiments were conducted to observe the interaction of sulfonated polymers with water and methanol. Branched copolymer and nano composite membranes exhibit proton conductivities from $1.12{\times}10^{-3}$ to $6.04{\times}10^{-3}\;S/cm^2$, water uptake from 52.9 to 62.4%, IEC from 0.81 to 1.21 meq/g and methanol diffusion coefficients from $1.2{\times}10^{-7}$ to $1.5{\times}10^{-7}\;cm^2/S$.

• Food Science of Animal Resources
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• v.30 no.3
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• pp.359-364
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• 2010

Lactobacillus acidophilus A12 was isolated from chicken feces for use as an immunostimulating livestock probiotic. The purpose of this study was to optimize the production of L. acidophilus A12 using response surface methodology (RSM). Initially, the influence of growth medium was studied in terms of carbon sources (glucose, fructose, lactose, glycerol, sucrose, ethanol, and mannitol), nitrogen sources (beef extract, yeast extract, malt extract, and tryptone), and inorganic salts ($CaCl_2$, $MgSO_4$, $KH_2PO_4$, $(NH_4)_2SO_4$, $FeSO_4$, and NaCl). Through one factor-at-a time experiment, lactose, yeast extract, and $CaCl_2$ were determined to be the best sources of carbon, nitrogen, and inorganic salt, respectively. The optimum composition was found to be 17.7 g/L lactose, 18.6 g/L yeast extract, and 0.9 g/L $CaCl_2$. Under these conditions, a maximum cell density of 9.33 Log CFU/mL was produced, similar to the predicted value.

• Asian Journal of Atmospheric Environment
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• v.8 no.3
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• pp.115-125
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• 2014

In this study, particle composition data for $PM_{10}$ samples were collected every 3 days at Seoul, Korea from August 2006 to November 2007, and were analyzed to provide source identification and apportionment. A total of 164 samples were collected and 21 species (15 inorganic species, 4 ionic species, OC, and EC) were analyzed by particle-induced x-ray emission, ion chromatography, and thermal optical transmittance methods. Positive matrix factorization (PMF) was used to develop source profiles and to estimate their mass contributions. The PMF modeling identified nine sources and the average mass was apportioned to secondary nitrate (9.3%), motor vehicle (16.6%), road salt (5.8%), industry (4.9%), airborne soil (17.2 %), aged sea salt (6.2%), field burning (6.0%), secondary sulfate (16.2%), and road dust (17.7%), respectively. The nonparametric regression (NPR) analysis was used to help identify local source in the vicinity of the sampling area. These results suggest the possible strategy to maintain and manage the ambient air quality of Seoul.

• Journal of environmental and Sanitary engineering
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• v.8 no.1
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• pp.81-91
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• 1993

This paper was carried out to isolate and identify Aeromonas caviae which can degrade Sodium Dodecyl Benzene Sulfonate(SDBS) effectively. And the affecting factors for the ability of bacterial degradation were also studied. Frm October 1991 to February 1992, two hundred samples from sweage in Taegu area and Nakdong river waters in Talsung Gun area were tested. Minimal salt medium which contain SDBS only as a carbon source was used as a culture medium. The isolated new strain was identified as Aeromonas caviae Kim & Kweon. The optimal pH for SDBS degradation were 7.0 and temperature, $32^{\circ}C.$ It was taken 24 hours to degrade SDBS of 20mg/l completely under the optimal pH and temperature. And in the case of 30 mg/l of SDBS, it was taken 36 hours. The nitrogen sources were added to the minimal salt media containing 20mg/l of SDBS, and they were incubated at $32^{\circ}C$ for 14 hours. 86.9% SDBS were degraded after addition of 0.03% peptone as a organic nitrogen source. And 70.5% SDBS after addition of 0.05% ammonium sulfate as a inorganic nitrogen source. In the case of metal compounds(0.015%), the degradation rate for SDBS were 3.5 fold increased in the media containing magnesium chloride and calcium chloride than in the media that were not containing these metal compounds. And where the media containing magnesium chloride was 0.05%, the degradation rate was 65.8%. And above 0.3% NaCI, the degradation rate was decreased slowly.