• Title/Summary/Keyword: Inorganic particle

검색결과 302건 처리시간 0.248초

Effect of Heat Treatment on the Morphology and Transparency of Thick Inorganic-Organic Hybrid Films Prepared by the Electrophoretic Sol-Gel Deposition of Polyphenylsilsesquioxane Particles

  • Hasegawa, Koichi;Katagiri, Kiyofumi;Matsuda, Astunori;Tatsumisago, Masahiro;Minami, Tsutomu
    • The Korean Journal of Ceramics
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    • 제6권1호
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    • pp.15-20
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    • 2000
  • Thick inorganic-organic hybrid films were prepared on ITO-coated glass substrates by the electrophoretic sol-gel deposition of polyphenylsilsesquioxane particles. The morphology of the deposited films changed from the aggregate of the spherical particles to monolith by heat treatment at temperatures higher than $200^{\circ}C$. Transparency of the films was significantly improved accompanied by the morphological change of the particles. The degree of the morphological change was governed by two factors; maximum heat treatment temperature and heating rate. Transparent thick films of ca. 3$\mu\textrm{m}$ in thickness were obtained only by heat treatment at $400^{\circ}C$ for 2h with rapid heating from room temperature to $400^{\circ}C$. These films obtained were strongly adhered to the ITO-coated glass substrates and has a very smooth surface.

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Crystal growing of NaX type zeolite

  • Ha, Jong-Pil;Seo, Dong-Nam;Jung, Mi-Jeong;Moon, In-Ho;Cho, Sang-Joon;Park, Hyun-Min;Kim, Ik-Jin
    • 한국결정성장학회지
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    • 제9권4호
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    • pp.371-376
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    • 1999
  • A large NaX type zeolite crystal of a uniform particle size of 20$\mu\textrm{m}$ are grown with various {{{{{H}_{2}O}}}} content by hydrothermal reaction and added seed crystal (2~3$\mu\textrm{m}$) to reactant solution as a function of different adding seed levels from 3 to 15%. The result that increased purity of NaX zeolite above 95% and homogeneity of crystal size by increasing adding seed levels, also decreased crystallization time. It was explained that adding seed to synthesis solution leaded out increase of surface area for physical contact reaction and directed growth of seed crystal, so more rapid consumption of reaction gel as increase seeding levels.

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Selective Laser Sintering of Alumina Using an Inorganic Binder Monoclinic $HBO_2$ and Post-Processing

  • 이인섭
    • 한국분말재료학회지
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    • 제5권3호
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    • pp.199-209
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    • 1998
  • A new low melting inorganic binder, monoclinic $HBO_2$, has been developed for Selective Laser Sintering (SLS) of alumina powder by dehydration process of boron oxide powder in a vacuum oven at $120^{\circ}C$. It led to better green SLS parts and higher bend strength far green and fired parts compared to other inorganic binders such as aluminum and ammmonium phosphate. This appeared to be due to its low viscosity and better wettability of the alumina particle surface. A low density single phase ceramic, aluminum borate ($Al_{18}B_4O_{33}$), and multiphase ceramic composites, $A_{12}O_3-A_{14}B_2O_9$, were successfully developed by laser processing of alumina-monoclinic $HBO_2$ powder blends followed by post-thermal processing; both $Al_{18}B_4O_{33}$ and $A_{14}B_2O_9$ have whisker-like grains. The physical and mechanical properties of these SLS-processed ceramic parts were correlated to the materials and processing parameters. Further densification of the $A_{12}O_3-A_{14}B_2O_9$ ceramic composites was carried out by infiltration of colloidal silica, and chromic acid into these porous SLS parts followed by heat-treatment at high temperature ($1600^{\circ}C$). The densities obtained after infiltration and subsequent firing were between 75 and 80% of the theoretical densities. The bend strengths are between 15 and 33 MPa.

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Preparation of Functional Antibiotic and Deodorization Pigments Using Surface Modification Method for Special Papermaking

  • Cho, Jun-Hyung;Lee, Yong-Won;Min, Dong-Jin
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.417-421
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    • 2006
  • In this study, colloidal Ag solution was spouted on the surface of the inorganic pigment using the hybridizer system and the spray nozzle. Then, the surface of the inorganic pigment was modified by titanium dioxide in order to possess antibacterial ability. Nano-sized colloidal Ag was made by using a seed sol method in this study. It was confirmed that the size of particle per unit weight becomes enlarged, as the addition of $AgNO_{3}$ increased, and as the time of reaction increased, in the manufacturing process of nano-sized colloidal Ag. The antibacterial measurement of the inorganic pigment showed that the growth of fungus was reduced as the reaction time increased. It was measured that the antibacterial activity was excellent at fixed time frame, after the antibacterial ability appeared in $5{\sim}7$ hours of the antibacterial inoculation experiment. The experiment of titanium dioxide's Photocatalyst effect showed $60{\sim}70%$ efficiency in about 80 minute reaction time of the dissolution results regarding measurements of benzene. It was shown that more than 90% of the dissolution efficiency was achieved in the reaction time of about 30 minute.

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폴리에스터 필름의 광투과도 향상에 대한 연구 (Study on the Improvement of Light Transmittance of Polyester Film)

  • 김시민;박수영
    • 폴리머
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    • 제36권5호
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    • pp.662-667
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    • 2012
  • 평판 디스플레이에 사용되는 PET 필름의 광학적 특성을 알아보기 위하여 필름 표면 굴절률, 필름 표면조도 및 필름 내부입자가 광투과율에 미치는 영향을 알아 보았다. 필름표면에 굴절률이 낮은 코팅층을 형성함에 따라 필름의 광투과율이 향상되었고, 최대의 광투과율을 가지는 코팅두께가 있음을 확인하였다. 표면 거칠기의 영향에 대해서는 표면조도를 나타내는 Ra를 입사 파장의 1/4 이하로 조절한 경우 광손실이 발생되지 않았다. 필름 내 무기입자는 입사된 광의 흡수 및 산란을 발생시켜 광손실을 증가시켰다.

Analysis of microstructural characteristics and components of red and yellow ink pigments used in permanent makeup

  • Hyun Sook Jin;Byung Soo Chang
    • Applied Microscopy
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    • 제52권
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    • pp.3.1-3.8
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    • 2022
  • Our purpose in this study is to analyze the microstructural characteristics and constituent elements of inorganic substances added to the yellow ink and red ink pigments used in permanent makeup. We observed the microstructural properties of inorganic pigments added to the ink using a scanning electron microscopy (SEM) and analyzed the constituent elements of the inorganic pigment particles using an energy dispersive X-ray spectroscopy (EDX). In red wine-colored ink, cubic titanium dioxide with a diameter of 110 to 200 nm was the major component, and rod-shaped iron oxide was rarely observed. Most of the ingredients of taupe yellow ink were rod-shaped yellow iron oxide, and a small amount of cubic titanium dioxide was observed. Red wine-colored ink and taupe yellow ink contained lumps composed of titanium dioxide particles. In red wine-colored ink, lumps were formed by agglomeration. However, we observed that the surface of the lump composed of titanium dioxide in the taupe yellow ink had a smooth surface caused by external physical compression. The titanium dioxide particle mass which found in taupe yellow ink in this study is an artificial product. When this mass accumulates in the dermis, it may cause a color mismatch. Therefore, permanent makeup using fine pigments should be free of foreign substances that may cause trouble in the skin. In addition, there is a need to improve the quality of the ink so that the required color can be safe and long lasting in the dermis.

금속 나노입자 프린팅 공정을 이용한 유연전기소자 연구 현황 (Research Status on Flexible Electronics Fabrication by Metal Nano-particle Printing Processes)

  • 고승환
    • 한국입자에어로졸학회지
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    • 제6권3호
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    • pp.131-138
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    • 2010
  • Flexible electronics are the electronics on flexible substrates such as a plastic, fabric or paper, so that they can be folded or attached on any curved surfaces. They are currently recognized as one of the most innovating future technologies especially in the area of portable electronics. The conventional vacuum deposition and photolithographic patterning methods are well developed for inorganic microelectronics. However, flexible polymer substrates are generally chemically incompatible with resists, etchants and developers and high temperature processes used in conventional integrated circuit processing. Additionally, conventional processes are time consuming, very expensive and not environmentally friendly. Therefore, there are strong needs for new materials and a novel processing scheme to realize flexible electronics. This paper introduces current research trends for flexible electronics based on (a) nanoparticles, and (b) novel processing schemes: nanomaterial based direct patterning methods to remove any conventional vacuum deposition and photolithography processes. Among the several unique nanomaterial characteristics, dramatic melting temperature depression (Tm, 3nm particle~$150^{\circ}C$) and strong light absorption can be exploited to reduce the processing temperature and to enhance the resolution. This opens a possibility of developing a cost effective, low temperature, high resolution and environmentally friendly approach in the high performance flexible electronics fabrication area.

Synthesis and Characterization of Submicrometer Monodispersed Ceramic Powders of Aluminium Titanate-Mullite Composite by Sol-Gel Process

  • Kim, Ik-Jin;Kim, Do-Kyung;Lee, Hyung-Bock;Ko, Young-Shin
    • The Korean Journal of Ceramics
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    • 제1권1호
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    • pp.1-6
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    • 1995
  • Submicrometer, monosized ceramic powder of $Al_2TiO_5$$Al_2O_3$ ethanolic solutions. All particles produced by sol-gel-process were amprphous, monodispersed and with a narrow particle-size distribution. Compacts fired above $1300^{\circ}C$ formed aluminium titanate. Mullite formed first at $1480^{\circ}C$. After decomposition test at $1100^{\circ}C$, and cyclic thermal decomposition test at 750-1400-$750^{\circ}C$ for 100hrs., aluminium titanate was well stablized by composition with mullite.

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Preparation of PET Nanocomposites: Dispersion of Nanoparticles and Thermal Properties

  • Her, Ki-Young;Kim, Dae-Heum;Lim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • 제9권4호
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    • pp.71-73
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    • 2008
  • The development of polymer/inorganic nanocomposites has attracted a great deal of interest due to the improved hybrid properties derived from the two different components. Various nanoscale fillers have been used to enhance polymer mechanical and thermal properties, such as toughness, stiffness, and heat resistance. The effects of the filler on the final properties of the nanocomposites are highly dependent on the filler shape, particle size, aggregate size, surface characteristics, polymer/inorganic interactions, and degree of dispersion. In this paper, we describe the influence of different $CaCO_3$ dispersion methods on the thermal properties of polyethylene terephthalate (PET)/$CaCO_3$ composites: i.e., the adsorption of $CaCO_3$ on the modified PET surface, and the hydrophobic modification of the hydrophilic $CaCO_3$ surface. We prepared PET/$CaCO_3$ nanocomposites using a twin-screw extruder, and investigated their thermal properties and morphology.

Effect of Grain Size and Replacement Ratio on the Plastic Properties of Precipitated Calcium Carbonate Using Limestone as Raw Material

  • Baek, Chul Seoung;Cho, Kye Hong;Ahn, Ji-Whan
    • 한국세라믹학회지
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    • 제51권2호
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    • pp.127-131
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    • 2014
  • Precipitated calcium carbonate(PCC) inorganic fillers for plastic offera higher replacement ratio with improved mechanical properties than any other inorganic fillers. Due to its secure economic feasibility, its fields of application areexpanding. For optimized PCC grain size and polymer replacement ratio, it is good to maintain at least $0.035{\mu}m$ grains and keep double the grain size of distance between particles, depending on the molecular weight and volume replacement rate of the polymer. PCC has unique characteristics, ie, with smaller grain size, dispersibility decreases, and if grain size is not homogenous, polymer cracking occurs. The maximum replacement ratio of PCC is approximately 30%, but in the range of 10 - 15% it produces the highest mechanical strength. When mixed with a biodegradable plastic like starch, it also improves initial environmental degradability.