• Title/Summary/Keyword: Inorganic ions

Search Result 299, Processing Time 0.032 seconds

Current Researches on the Protection of Exterior Wood from Weathering (목재의 기상열화 방지에 관한 최근의 연구 동향)

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
    • /
    • v.46 no.5
    • /
    • pp.449-470
    • /
    • 2018
  • A review of research trends on wood surface protection for exterior use obtained the following conclusions: It has been reported that inorganic compounds such as chrome and copper used as wood preservatives can protect wood from weathering. It has been shown that precoating with hydrophobic substances such as wax and oil, UV absorbers, and HALS (Hindered Amine Light Stabilizers) enhances weathering resistance on the surface of ACQ-treated wood. Opaque coatings of paint/stains and semitransparent stains on the surface of preservative treated wood can increase the synergistic effects on prevention of weathering deterioration. Also the need for repainting periodically for the protection of the preservative treated wood surface has also been suggested. ZnO or $TiO_2$ of fine particles, metal ions such as Co, Cr, Fe, Mn, Ni and Ti, and UV absorbers such as tris-resorcinol triazine derivatives, triazine and benzotriazole were introduced as additives for preventing UV in the transparent coating on wood. Several reports showed that chemical modification such as methylation, acetylation, or alkylations have made some increases the effects of preventing weathering with the increasing weight gain of chemical formulas. In heat-treated wood, there were various contradictory reports on the resistance of weathering, and there were some other reports emphasizing the necessity of painting with UV resistance, which leads to the necessity of more advanced studies.

Adaptations and Physiological Characteristics of Three Chenopodiaceae Species under Saline Environments (명아주과 3종 식물의 염 환경에 대한 적응특성의 비교)

  • 송승달;김진아;추연식;배정진;김인숙;추보혜;이인중
    • The Korean Journal of Ecology
    • /
    • v.25 no.2
    • /
    • pp.101-107
    • /
    • 2002
  • Three species of Chenopodiaceae, i.e. Suaeda japonica, Salicomia herbacea, Beta vulgaris var. cicla, were investigated to compare the physiological characteristics through inoic balances and osmoregulations under different environmental salt gradients. Plats were harvested in two weeks from treatments with salt gradients (0, 50, 100, 200 and 400 mM NaCl) and mineral nutrition gradients(1/1, 1/5, 1/10 dilutions of Hoagland solution). Plants were analyzed for growth responses, ionic balances, osmolalities, conductivities, glycinebetaine and proline contents quantitatively. Three plants of Chenopodiaceae accumulated slats into tissues unlike some salt sensitive species, and showed unique adaptation patterns to overcome saline environments, i.e. strong growth stimulation for Salicomia herbacea, growth negative tolerance for Suaeda japonica, and growth positive tolerance for Beta vulgaris var. cicla. The absorption of inorganic Ca/sup 2+/ ions was inhibited remarkably due to the excess uptake of Na+ with increasing salinity. The K+ content in plants was significantly reduced with increasing salinity. Total nitrogen content was reduced as mineral nutritions and salinity increased. Conductivity and osmolality increased with increasing salinity regardless of mineral nutritions. The ranges of glycinebetaine and proline contents were 0.2∼2.5 μM/g plant water and 0.1∼0.6μM/g plant water, respectively.

Properties analysis of environment friendly calcareous deposit films electrodeposited at various temperature conditions in natural seawater (천연해수 중 온도 변화에 따라 전착한 환경친화적인 석회질 피막의 특성 분석)

  • Lee, Chan-Sik;Kang, Jun;Lee, Myeong-Hoon
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.39 no.7
    • /
    • pp.779-785
    • /
    • 2015
  • Cathodic protection is recognized as the most cost-effective and technically appropriate corrosion prevention method for the submerged zone of offshore structures, ships, and deep-sea facilities. When cathodic protection is applied, the cathodic currents cause dissolved oxygen reduction, generating hydroxyl ions near the polarized surface that increase the interfacial pH and result in enhanced carbonate ion concentration and precipitation of an inorganic layer whose principal component is calcium carbonate. Depending on the potential, magnesium hydroxide can also precipitate. This mixed deposit is generally called "calcareous deposit." This layer functions as a barrier against the corrosive environment, leading to a decrease in current demand. Hence, the importance of calcareous deposits for the effective, efficient operation of marine cathodic protection systems is recognized by engineers and scientists concerned with cathodic protection in submerged marine environments. Calcareous deposit formation on a marine structure depends on the potential, current, pH, temperature, pressure, sea-water chemistry, flow, and time; deposit quality is significantly influenced by these factors. This study determines how calcareous deposits form in sea water, and assesses the interrelationship of formation conditions (such as the sea water temperature and surface condition of steel), deposited structure, and properties and the effectiveness of the cathodic protection.

Food Component Characteristics of Cultured and Wild Oysters Crassostrea gigas and Ostrea denselamellos in Korea (양식산 및 자연산 굴(Crassostrea gigas, Ostrea denselamellos)의 성분 특성)

  • Lee, Yeong-Man;Lee, So-Jeong;Kim, Seon-Geun;Hwang, Young-Sook;Jeong, Bo-Young;Oh, Kwang-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.45 no.6
    • /
    • pp.586-593
    • /
    • 2012
  • To identify the food component characteristics of seven oysters(four cultured oysters and two wild oysters Crassostrea gigas and one dendely lamellated oyster Ostrea denselamellos Korean name beotgul) in Korea, the proximate, fatty/amino acid, mineral compositions, texture, color, chemical and taste compounds were investigated. The proximate compositions were not significantly different between cultured and wild oysters, whereas beotgul had lower levels of crude protein, ash and lipid content, and a higher carbohydrate content. The amino nitrogen contents of the three main types were 232.8-258.2, 160.5-213.9, and 218.5 mg/100 g, respectively, and the salinities were 1.5-1.7, 1.5-1.8, and 0.9%, respectively. Regarding the muscle texture, the shearing forces were 95-114, 105-132, and 170 g, respectively. Amounts of total amino acids of cultured, wild oysters and beotgul were 9,004-10,198, 8,165-8,942, and 7,767 mg/100 g, respectively. The major amino acids were aspartic acid (Asx), glutamic acid (Glx), proline, alanine, leucine, phenylalanine, lysine and arginine. Regarding inorganic ions, beotgul had much lower Fe and S contents than the cultured and wild oysters. The major fatty acids of cultured and wild oysters were 16:0, 18:0, 16:1n-9, 18:1n-9, 22:1n-9, 16:4n-3, 20:5n-3, and 22:6n-3, and there was little difference between the two. Beotgul had a higher polyenes ratio, i.e., 20:5n-3, and a lower monoenes ratio than the cultured and wild oysters. The free amino acid contents of cultured, wild oysters and beotgul extracts were 1,444-1,620, 1,017-1,277, and 1,144 mg/100 g, respectively, and the major free amino acids were taurine, glutamic acid, glycine, alanine, tryptophan, ornithine, and lysine. There was a little difference in the glycine, tryptophan, ornithine, and arginine contents.

Investigation of residual tricyclazole and its risk assessment in Korean sundried salts (국내 생산 천일염의 트리사이클라졸 잔류 및 위해성 평가)

  • Kim, Jin-Hyo;Choi, Geun-Hyung;Lee, Ji-Ho;Kwon, Oh-Kyung
    • The Korean Journal of Pesticide Science
    • /
    • v.16 no.3
    • /
    • pp.257-260
    • /
    • 2012
  • Sundried salt was recently registered in food category in Korea in 2008, and food hygiene regulation only applied to several heavy metals and a few inorganic ions. In this report, we investigated the residual amounts of tricyclazole, a highly concerned contaminant from agricultural activity, and estimated their daily intake and hazard index. All 60 sundried salts were collected by region, and qualitatively and quantitatively were analyzed with GC-NPD. In this investigation, only three samples were confirmed the residual tricyclazole in sundried salts. Their maximum residue was $1.7{\mu}g/kg$, and their estimated average daily intake was $2.40{\times}10^{-8}{\sim}6.22{\times}10^{-8}mg/kg-day$. From these results, HI of tricyclazole for sundried salts was $7.53{\times}10^{-7}{\sim}2.07{\times}10^{-6}$ for Koreans, and the values were not considered as serious risk issues currently.

Optical Diagnostics of Nanopowder Processed in Liquid Plasmas

  • Bratescu, M.A.;Saito, N.;Takai, O.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.17-18
    • /
    • 2011
  • Plasma in liquid phase has attracted great attention in the last few years by the wide domain of applications in material processing, decomposition of organic and inorganic chemical compounds and sterilization of water. The plasma in liquid is characterized by three main regions which interact each - other during the plasma operation: the liquid phase, which supply the plasma gas phase with various chemical compounds and ions, the plasma in the gas phase at atmospheric pressure and the interface between these two regions. The most complex region, but extremely interesting from the fundamental, chemical and physical processes which occur here, is the boundary between the liquid phase and the plasma gas phase. In our laboratory, plasma in liquid which behaves as a glow discharge type, is generated by using a bipolar pulsed power supply, with variable pulse width, in the range of 0.5~10 ${\mu}s$ and 10 to 30 kHz repetition rate. Plasma in water and other different solutions was characterized by electrical and optical measurements. Strong emissions of OH and H radicals dominate the optical spectra. Generally water with 500 ${\mu}S/cm$ conductivity has a breakdown voltage around 2 kV, depending on the pulse width and the repetition rate of the power supply. The characteristics of the plasma initiated in ultrapure water between pairs of different materials used for electrodes (W and Ta) were investigated by the time-resolved optical emission and the broad-band absorption spectroscopy. The deexcitation processes of the reactive species formed in the water plasma depend on the electrode material, but have been independent on the polarity of the applied voltage pulses. Recently, Coherent anti-Stokes Raman Spectroscopy method was employed to investigate the chemistry in the liquid phase and at the interface between the gas and the liquid phases of the solution plasma system. The use of the solution plasma allows rapid fabrication of the metal nanoparticles without being necessary the addition of different reducing agents, because plasma in the liquid phase provides a reaction field with a highly excited energy radicals. We successfully synthesized gold nanoparticles using a glow discharge in aqueous solution. Nanoparticles with an average size of less than 10 nm were obtained using chlorauric acid solutions as the metal source. Carbon/Pt hybrid nanostructures have been obtained by treating carbon balls, synthesized in a CVD chamber, with hexachloro- platinum acid in a solution plasma system. The solution plasma was successfully used to remove the template remained after the mesoporous silica synthesis. Surface functionalization of the carbon structures and the silica surface with different chemical groups and nanoparticles, was also performed by processing these materials in the liquid plasma.

  • PDF

Simulation of Plume Length Induced by Orimulsion Combustion (오리멀젼 연소시 발생하는 백연의 연기거리 전산모사)

  • Kwak, Byoung-Kyu;Kim, Jong-Ho;Joo, Ji-Bong;Lee, Jeong-Jin;Kim, Jin-Soo;Kim, Young-Hun;Yi, Jong-Heop
    • Clean Technology
    • /
    • v.14 no.2
    • /
    • pp.136-143
    • /
    • 2008
  • The objective of this study is to investigate the visibility of plume at the Y power plant stack, which fires the orimulsion as a fuel. The plume contains numerous primary particles under $1\;{\mu}m$ size and inorganic ions possibly inferred by the chemicals of secondary aerosol formation. We evaluated the visibility of the plume using the modified PLUVUE-II model. The monitoring data on the particle size distribution (PSD) and secondary aerosols of sulfate were applied to estimate and evaluate the main factors of plume opacity. The chemical reactions were applied to the model for the secondary aerosol formation of $(NH_4)_2SO_4(s)$. The maximum plume length was estimated by an optic method using threshold contrast. The results showed that the plume length was strongly dependent upon the PSD and $(NH_4)_2SO_4(s)$ concentration of the plume emitted from the stack.

  • PDF

Effect of Mercuric Chloride on the Contents of Mineral Nutrients in the Liver and Kidney of Rats (흰쥐의 간장(肝臟) 및 신장(腎臟) 무기질(無機質)에 미치는 수은(水銀)의 영향(影響))

  • Cho, Soo-Yeul;Park, Sun-Woo;Lee, Sang-Il
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.13 no.1
    • /
    • pp.22-26
    • /
    • 1984
  • The effect of changes in body weight, some blood components and some inorganic ions in liver and kidney, were studied on male rats receiving ad libitum on 5, 40, and 200 ppm of mercuric chloride solution during so days. The results obtained were summarized as follows ; 1. The total body weights were decreased in proportion to increment of mercury concentration. The internal organs weights i. e. , liver, kidney, spleen, and heart, were generally increased. Especially, the weight increment of kidney was the highest by intaking of mercuric chloride solution. 2. There were no significant changes in hematocrit values, activities of GOT and GPT in blood of rats receiving mercuric chloride. On the other hand, the plasma levels of cholesterol were significantly increased. The receiving of 200 ppm mercuric chloride solution to rats was resulted in the remarkable reduction of total protein levels and A/G ratio in plasma. 3. The markable rise occured in the accumulation of Hg, in both liver and kidney in proportion to supplying in rats while there was a tendency decreasing of Cu, Zn contents in liver, whereas there was a tendency increasing of Cu, Zn in kidney of rats.

  • PDF

Study on the control of marine biofouling developed on the surface of porous ceramics (세라믹 다공체 표면에 발생하는 해양 생물 오손 억제에 관한 연구)

  • Kang, Jimin;Kang, Seunggu;Kim, YooTack
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.25 no.5
    • /
    • pp.218-224
    • /
    • 2015
  • Recently, removing methods of red tide has been attempted by filtering the organisms using the ceramic porous bodies. However, the marine biofouling could be developed on the surfaces of porous ceramic body after use for more than one month, and it might decrease the function of the specimen. In this paper, a method of inhibiting marine biofouling by changing the physical properties or surface-modification of ceramic porous body was studied. After experiment with six different ceramic porous bodies, it was found that the specimen of lower porosity and water absorption showed the least amount of biofouling. In addition, by increasing the surface roughness with silica particles bonded to the surface of specimen, the amount of biofouling caused by large marine life such as barnacle and mussel could be decreased. On the other hand, when the surface of specimen was coated and fused by glass powder, the amount of biofouling was rather increased. This might be due to eluted inorganic ions from the glass which can promote the growth of the microorganism. In conclusion, the environmental-friendly methods to reduce the amount of marine biofouling, such as controlling the physical properties and the surface roughness of the porous ceramics, can be possible without the use of dangerous substances. So it is expected for the results obtained to be applicable to a marine structure.

A STUDY ON THE ENAMEL EROSION CAUSED BY ORANGE JUICES (오렌지쥬스의 치아 법랑질 침식효과에 대한 연구)

  • Lee, Chang-Yun;Jung, Tae-Sung;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
    • /
    • v.31 no.4
    • /
    • pp.617-623
    • /
    • 2004
  • Acidic drink has been known as a cause of tooth erosion. The purpose of this study is to verify the acid levels of orange juices in market and evaluate the erosion effects on the enamel of deciduous teeth by orange juices in relatively short period of time. With four kinds of orange juice selected from market, pH, buffering capacity and concentration of Ca and P ion were measured. And forty segments of normal enamel of deciduous incisors were divided into four groups and level of erosion was measured by surface hardness test before and after soaking at 50ml of orange juice for 10 minutes. The results of this study showed that the average pH of orange juices was 4.0 and this pH value was so acidic as to cause the tooth erosion. There were differences in small quantity for each group of teeth, however, the result was statistically so significant that orange juices can cause enamel erosion in relatively short period of time.

  • PDF