• Title/Summary/Keyword: Inorganic fillers

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Fundamental Study on Developing Lignocellulosic Fillers for Papermaking(II) - Effect of lignocellulosic fillers on paper properties - (목질계 제지용 충전제 개발을 위한 기초연구(II) - 목질계 충전제가 종이 물성에 미치는 영향 연구 -)

  • Kim, Chul-Hwan;Lee, Ji-Young;Lee, Young-Rok;Chung, Ho-Kyung;Back, Kyung-Kil;Lee, Hui-Jin;Gwak, Hye-Joeng;Gang, Ha-Ryun;Kim, Sung-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.2
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    • pp.1-6
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    • 2009
  • The purpose of this study was to investigate effects of lignocellulosic fillers made of wood powder and inorganic fillers, such as GCC and PCC, on physical properties of papers. Mechanical treatment and chemical treatment were carried out subsequently for generating lignocellulosic fillers, and then inorganic filler and wood powder were mixed together, and then mechanically treated for making lignocellulosic fillers covered with inorganic fillers. Consequently the particle size of lignocellulosic fillers was higher than that of inorganic fillers, which led to lumen loading and simultaneously surface coverage of fine inorganic fillers. Lignocellulosic fillers contributed to the increase of both bulk and opacity of handsheets dramatically, but some of properties including tensile strength, brightness and roughness decreased compared to inorganic fillers.

Electrical Properties of Organic/lnorganic Hybrid Composites for Insulation materials (유기/무기 복합 절연재료의 전기적 특성)

  • 깅상철;김현석;옥정빈;안명진;박도현;이건주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.78-83
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    • 2001
  • In this work, the surface of inorganic fillers were modified with some functional groups such as stearic acid, aliphatic long chain, vinylsilane and aminosilane to control the interaction between inorganic fillers and polymer matrix. Ethylene-vinyl acetate copolymers (EVA) with various amount of vinyl-acetate content and copolyether-ester elastomer were used as polymer matrix. The addition of inorganic fillers increases flame retardancy, but results in steep drop of electrical and mechanical properties, which may be caused by the defect in the interface between organic/inorganic hybrid composites. The hybrid composites are found to show better mechanical properties and higher volume resistivities as inorganic fillers are well dispersed and have good adhesion with polymer matrix. Also, the most effective type of functional group coated on fillers depends on the chemical structure of polymer.

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Color Supplementation of Base Paper for Coating after Wooden Fillers Addition (목질계 충전제 사용에 따른 도공지 원지의 색상 보완)

  • Yoon, Myung-Suk;Yoo, Hyun-Jin;Jung, Chul-Hun;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.1
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    • pp.24-30
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    • 2012
  • This study was carried out in order to analyze a repletion possibility about color change of base paper after elevated heat exposure when wooden fillers were added. Fillers may reduce production cost because its price is usually inexpensive than pulp with higher bulkiness. Wooden fillers have lower density than inorganic fillers, so they may increase bulk more than inorganic fillers. Never the less wooden fillers have disadvantage of yellow color by heat exposure, so the addition level should be carefully controlled. Brightness and whiteness changes after elevated heat exposure depending on coating weight were analyzed. With wooden fillers addition, breaking length and surface strength decreased but bulkiness increased. As the exposure time of elevated heat increased the coating paper with wooden fillers addition had higher brightness and whiteness values than those of inorganic fillers.

Electrical Properties of Organic/Inorganic Hybrid Composites for Insulation Materials

  • Kim, Sang-Cheol;Ok, Jeong-Bin;Aho, Myeong-Jin;Park, Do-Hyun;Lee, Gun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.9-13
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    • 2002
  • In this work, the surface of inorganic fillers were modified with some functional groups such as stearic acid, aliphatic long chain, vinylsilane and aminosilane to control the interaction between inorganic fillers and polymer matrix. Ethylene-vinyl acetate copolymers (EVA) with various amount of vinyl-acetate and copolyether-ester elastomer were used as polymer matrix. The addition of inorganic fillers increases flame retardancy, but results in steep drop of electrical and mechanical properties, which may be caused by the defects in the interface between organic/inorganic hybrid composites. The hybrid composites are found to show better mechanical properties and higher volume resistivities as inorganic fillers are well dispersed and have good adhesion with polymer matrix. Also, the most effective type of functional group coated on fillers depends on the chemical structure of polymer.

PMMA수지의 수 Tree현상

  • 유근민;이재선
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.7 no.1
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    • pp.18-24
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    • 1982
  • The Tree phenomenon of the PMMA resin depends on an annex of the inorganic fillers and water. If the internal of an arganic insulating materials exist the fault of inorganic fillers, Void and Projecting part, the high voltage concentrates in this place. It leaves a trace about the partical breakdown and this phenomenon develops into the degration of insulating material. This paper researchses that have an effect on the tree phenomenon by the inorganic fillers and water. The results is as follow. (1) The growth of tree are less the influence of inorganic fillers. Because , the constant of water are more. (2) If the tree branches contact the inorganic filler, the advance are relaxation.

Effects of Inorganic Fillers on Mechanical Properties of Silicone Rubber

  • Kim, Gyu Tae;Lee, Young Seok;Ha, KiRyong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.142-148
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    • 2019
  • In this study, the effects of filler particle size and shape on the physical properties of silicone rubber composites were investigated using inorganic fillers (Minusil 5, Celite 219, and Nyad 400) except silica, which was already present as a reinforcing filler of silicone rubber. Fillers with small particle sizes are known to facilitate the formation of the bound rubber by increasing the contact area with the polymer. However, in this experiment, the bound rubber content of Celite 219-added silicone composite was higher than that of Minusil 5-added silicone composite. This was attributed to the porous structure of Celite 219, which led to an increase in the internal surface area of the filler. When the inorganic fillers were added, both thermal decomposition temperature and thermal stability were improved. The bound rubber formed between the silicone rubber and inorganic filler affected the degree of crosslinking of the silicone composite. It is well-known that as the size of the reinforcing filler decreases, the reinforcing effect increases. However, in this experiment, the hardness of the composite material filled with Celite 219 was the highest compared to the other three composites. Furthermore, the highest value of 2.19 MPa was observed for 100% modulus, and the fracture elongation was the lowest at 469%. This was a result of excellent interaction between Celite 219 filler and silicone rubber.

A Study on Effect of Inorganic Fillers to Rubber Properties (고무물성(物性)에 미치는 국산(國産) 무기충전제(無機充塡劑)의 효과(效果)에 관(關)한 연구(硏究))

  • Kim, Ki-Joo;Kim, Jong-Seok;Ahn, Byung-Kook;Suh, Soo-Kyo;Chang, Young-Jae;Kang, Kyoung-Ho
    • Elastomers and Composites
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    • v.24 no.4
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    • pp.276-289
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    • 1989
  • This study deals with both effects of inorganic fillers to vulcanized rubbers such as NR, CR, EPDM, NBR & SBR and inorganic characteristics of domestic fillers in comparision with hard clay produced in the USA. The results were as follows. 1. Main ingredient of domestic clay "Ha-dong clay" was Halloysite, "No-ha Island" was Pyrophyllite with $\alpha$-Quartz, and both of "Hard clay" & "Hwa-soon clay" were proved to be Kaolinite by XRD, DT-TGA and chemical analysis by XRF. 2. Tensile strength value of SBR compounded with these fillers, was Hard clay $146kg\;f/cm^2$, Kaolinite $123kg\;f/cm^2$, Pyrophyllite $82kg\;f/cm^2$, Halloysite $80kg\;f/cm^2$, precipitated $CaCO_3\;27kg\;f/cm^2$, and ground $CaCO_3$ was $21kg\;f/cm^2$. These results showed the increase of seven times according to filler species. 3. The physical properties of non-crystalline rubbers, such as SBR, NBR & EPDM, compared with NR & CR, have been considerably changed according to crystalline phase, particle size, shape and surface structure of fillers. Especially, tensile strength value in case of SBR & EPDM, was differentiated about 1.5 times by the particle size of fillers. 4. In SBR, physical properties of rubber compounded with Kaolinite which was surface treated with fatty acid and silane, almost approach to the value of hard clay. 5. Delayed cure time of Kaolinite and decrease of rubber properties by $CaCO_3$ can be improved by blending kaolinite & $CaCO_3$ in the ratio of 2:1.

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Effects of Tape Thickness and Inorganic Fillers on the Adhesion Properties of Double-sided Acrylic Adhesive Tape by Ultraviolet Curing (자외선 경화형 아크릴 양면 점착테이프의 두께 및 무기물 충전제 종류에 따른 접착특성)

  • Kim, Dong-Bok
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.397-405
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    • 2014
  • To manufacture of high-performance semi-structural double-sided adhesive tape, 2-ethylhexyl acrylate (2-EHA) and acrylic acid (AAC) were used, and the syrup was prepared by UV irradiation in this study. The effects of the thickness, various inorganic filler contents, and filler types on the semi-structural properties of acrylic double-sided adhesive tape were investigated. The peel strength increased with increasing thickness and wetting time. In case of the thin thickness (under $250{\mu}m$) with decreasing true density of inorganic filler, the peel strength increased with increasing wetting time. The initial peel strength showed a higher value at a big size of inorganic filler, and the filler's size in adhesive tapes was confirmed by SEM images. The peel strength and dynamic shear strength increased as a proportional relationship with various inorganic fillers and contents, and these inorganic fillers in $0.1{\mu}m$ thickness indicated more effect on the dynamic shear strength of double-sided adhesive tape. From these results the thin acrylic double-sided adhesive tape determined to be use for applications as a high-performance semi-structural.

Effect of Fillers on Dispersion of Carbon Nanotubes in a Twin-Screw Extruder (이축압출기에서 카본나노튜브의 분산에 대한 충전제 효과)

  • Hong, Seung Soo;Shin, Ji Hee;Song, Kwon Bin;Lee, Kwang Hee
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.342-346
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    • 2013
  • In this study, it was attempted to disperse carbon nanotubes (CNTs) in a polymer matrix using a twin-screw extruder which was good for dispersing fillers of micron sizes but not suitable for dispersing nanometer-sized materials. Improved dispersion of CNTs could be achieved by the addition of inorganic fillers with different geometrical shapes. An increase in the matrix viscosity provided a high shear stress on aggregated CNTs, leading to a good dispersion of CNTs. The presence of the inorganic fillers was supposed to suppress the re-aggregation of CNTs in the regions where a lower shear stress was applied. As a result, the CNTs dispersion was well stabilized.

A Study on the Behaviors of Inorganic Fillers in Recycling of the Waste Agricultural Plastic Films (I) - Effects on the Addition of Calcium Carbonate and Calpet - (무기(無機) 충진재(充鎭材) 첨가(添加)에 따른 재생(再生) 폐(廢)비닐의 특성(特性) 분석(分析) (I) - 중탄과 칼펫의 첨가(添加)에 따른 영향(影響) -)

  • Ahn, Tae-Kwang;Son, Sang-Jin;Kim, Hea-Tae;Kim, Myoung-Ho;Zhou, Gong-Ming;Chen, De-Zhen
    • Resources Recycling
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    • v.17 no.3
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    • pp.10-20
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    • 2008
  • In order to study the behaviors of inorganic fillers in recycling of the waste agricultural plastic films, the washed PE fluffs from Shihwa and Jungeup Plant belonging to ENVICO were used respectively. First of all, the test pellets were manufactured by adding of inorganic fillers suchlike calcium carbonate and calpet by certain portions to PE fluffs and then the tested sheets were formed. The mechanical and thermal properties of the samples were measured and compared with others. The items measured were tensile, flexural, Izod impact, HDT, MFT, and so on. Morphologies were also investigated for various samples using the SEM. Finally, optimum ratios between recycled PE and inorganic additives were found out for the best products in physical condition as well as in economic point of view.