• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.665-675
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• 2007

In-situ Air Sparging (IAS, AS) is a remediation technique in which organic contaminants are volatilized from saturated zone to unsaturated layer. This study focuses on the removal and interaction of Volatile Organic Compounds (VOCs) and $CO_2$, and Total Petroleum Hydrocarbon (TPH) in saturated and unsaturated, and air space zone on the unsaturated soil surface. Soil sparging temperature of hot air has risen to $34.9{\pm}2.7^{\circ}C$ from $23.0{\pm}1.9^{\circ}C$ for 36 days. At the diffusing point, fluid TPH concentrations were reduced to 78.7% of the initial concentration in saturated zone when hot air was sparged. The TPH concentrations were decreased to 66.1% for room temperature air sparging. The amount of VOCs for hot air sparging system, in air space, was approximately 26% larger than constant air sparging system. The amount of $CO_2$ was 4,555 mg (in unsaturated zone) and 4,419 mg (in air space) when hot air was sparged was 3,015 mg (in unsaturated zone) and 3,634 mg (in air space) for room air temperature in the $CO_2$ amount. The removals of VOCs and biodegradable $CO_2$ through the hot air sparging system (modified SVE) were more effective than the room temperature air sparging. The regression equation were $Y=976.4e^{-0.015{\cdot}X}$, $R^2=0.98$ (hot air sparging) and $Y=1055e^{-0.028{\cdot}X}$, $R^2=0.90$ (room temperaure air sparging). Estimated remediation time was approximately 500 days, if final saturated soil TPH concentration was set to 1.2 mg/L application of tail effect.

• Journal of Soil and Groundwater Environment
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• v.21 no.1
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• pp.72-79
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• 2016

Bioremediation is one of the most effective ways to remediate TPH-contaminated sites. However, under actual field conditions that are not at the optimum temperature, degradation of microorganisms is generally reduced, which is why the efficiency of biodegradation is known to be significantly affected by the soil temperature. Therefore, in this study, the labscale experiment was conducted using indigenous crude oil degrading microorganisms isolated from crude oil contaminated site to evaluate the remediation efficiency. Crude oil degrading microorganisms were isolated from crude oil contaminated soil and temperature, which is a significant factor affecting the remediation efficiency of land farming, was adjusted to evaluate the microbial crude oil degrading ability, degradation time, and remediation efficiency. In order to assess the field applicability, the remediation efficiency was evaluated using crude oil contaminated soil (average TPH concentration of 10,000 mg/kg or more) from the OO premises. Followed by the application of microorganisms at 30℃, the bioremediation process reduced its initial TPH concentration of 10,812 mg/kg down to 1,890 mg/kg in 56 days, which was about an 83% remediation efficiency. By analyzing the correlation among the total number of cells, the number of effective cells, and TPH concentration, it was found that the number of effective microorganisms drastically increased during the period from 10 to 20 days while there was a sharp decrease in TPH concentration. Therefore, we confirmed the applicability of land farming with isolated microorganisms consortium to crude oil contaminated site, which is also expected to be applicable to bioremediation of other recalcitrant materials.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.58 no.3
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• pp.319-323
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• 2013

Red rice (Oryza sativa L.) is one of the most important weeds in most of rice cultivating area. Seed germination related experiments were done to evaluate germination percentage, emerging speed, and initial growth by seeding depth and soil moisture level. The four experiments, 1) temperature, 2) seeding depth, 3) soil moisture level, and 4) seeding position, were done with combination each other on phytotron for germination and seedling growth related experiments of redrice. The treatments levels were: 1) Temperatures were 20/15(Low), 25/20 (Mid.), $30/25{\circ}C$ (High), (day/night), 2) seeding depths were 0, 3, 6 cm, 3) soil moisture levels were 25, 35, 45, 55, 65% (VWC, %), and seeding position were furrow, ridge, ridge-top. The germination percentage and germination speed of red rice were higher and faster than Daeanbyeo in low temperature. Yoeongcheon redrice of seed germination percentage and seedling length was more vigor than Hapcheon red rice. Red rice was not germinated on 6 cm seeding depth until 11 days after seeding except high temperature treatment. Germination percentage increased with increasing soil water percentage in low temperature, however it was greatest in 45% in high soil moisture level between 25% to 65% in low temperature. Seed germination percentage and seedling length were not significantly different among the soil water level in mid- and high temperature levels. In conclusion, red rice could germinate in top soil (<6 cm) in mid- and high temperature range, so we might be control red rice by spraying herbicide after germination of red rice combined with delayed rotary cultivation.

• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.1
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• pp.120-127
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• 2002

This study was carried out to evaluate the effects of initial concentration on composting of diesel-contaminated soil. Silt loam was used in this study. Target contaminant, diesel oil, was spiked at about 2,000, 4,000, and 10,000mg/kg of dry soil, respectively. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was 0.7-3.5% of the initial concentrations. Volatilization loss of TPH was not increased in proportion to the initial concentration. After 30 days of operation, 86% and 94% of the initial concentrations at about 2,000 and 10,000mg TPH/kg were biodegraded. Normal alkanes were degraded more rapidly than TPH. The compounds of C12 to C14 were volatilized greatly among n-alkanes. The first order degradation rate constants of about 2,000, 4,000, and 10,000mg TPH/kg were 0.079, 0.069, and 0.061/day, respectively. Produced-$CO_2$ and degraded-TPH were correlated highly regardless of the initial TPH concentration(r = 0.97-0.99).

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.5
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• pp.595-610
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• 2003

The statistical indexes such as RMSE (Root Mean Square Error), Mean Bias error, and IOA (Index of agreement) are used to evaluate 3 Dimensional wind and temperature fields predicted by operational meteorological model RAMS (Regional Atmospheric Meteorological System) implemented in CARIS (Chemical Accident Response Information System) for the dispersion forecast of hazardous chemicals in case of the chemical accidents in Korea. The operational atmospheric model, RAMS in CARIS are designed to use GDAPS, GTS, and AWS meteorological data obtained from KMA (Korean Meteorological Administration) for the generation of 3-dimensional initial meteorological fields. The predicted meteorological variables such as wind speed, wind direction, temperature, and precipitation amount, during 19 ∼ 23, August 2002, are extracted at the nearest grid point to the meteorological monitoring sites, and validated against the observations located over the Korean peninsula. The results show that Mean bias and Root Mean Square Error are 0.9 (m/s), 1.85 (m/s) for wind speed at 10 m above the ground, respectively, and 1.45 ($^{\circ}C$), 2.82 ($^{\circ}C$) for surface temperature. Of particular interest is the distribution of forecasting error predicted by RAMS with respect to the altitude; relatively smaller error is found in the near-surface atmosphere for wind and temperature fields, while it grows larger as the altitude increases. Overall, some of the overpredictions in comparisons with the observations are detected for wind and temperature fields, whereas relatively small errors are found in the near-surface atmosphere. This discrepancies are partly attributed to the oversimplified spacing of soil, soil contents and initial temperature fields, suggesting some improvement could probably be gained if the sub-grid scale nature of moisture and temperature fields was taken into account. However, IOA values for the wind field (0.62) as well as temperature field (0.78) is greater than the 'good' value criteria (> 0.5) implied by other studies. The good value of IOA along with relatively small wind field error in the near surface atmosphere implies that, on the basis of current meteorological data for initial fields, RAMS has good potentials to be used as a operational meteorological model in predicting the urban or local scale 3-dimensional wind fields for the dispersion forecast in association with hazardous chemical releases in Korea.

• Journal of the Korean Solar Energy Society
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• v.30 no.4
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• pp.71-78
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• 2010

Investigation of the effective soil thermal conductivity(k) is the first step in designing the ground loop heat exchanger(borehole) of a geothermal heat pump system. The line source method is required by New and Renewable Energy Center of Korea Energy Management Corporation in analyzing data obtained from thermal response tests. Another important factor in designing the ground loop heat exchanger is the borehole thermal resistance($R_b$). There are two methods to evaluate $R_b$ : one is to use a line source method, and the other is to use a shape factor of the borehole. In this study, we demonstrated that the line source method produces better results than the shape factor method in evaluating $R_b$. This is because the borehole thermal resistance evaluated with the line source method characteristically reduces the temperature differences between an actual and a theoretical thermal behaviors of the borehole. Evaluation of $R_b$ requires soil volumetric heat capacity. However, the effect of the soil volumetric heat capacity on the borehole thermal resistance is very small. Therefore, it is possible to use a generally accepted average value of soil volumetric heat capacity($=2MJ/m^3{\cdot}K$) in the analysis. In this work, it is also shown that an acceptable range of the initial ignoring time should be in the range of 8~16hrs. Thus, a mean value of 12 hrs is recommended.

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.7-14
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• 2012

Batch tests were carried out to evaluate the thermal treatment of low volatile organic compounds in low-permeability soil. The chemical oxidation by sodium persulfate catalyzed by heat and Fe (II) was evaluated. Enhanced persulfate oxidation of n-decane (C-10), n-dodecane (C-12), n-tetradecane (C-14), n-hexadecane (C-16), and phenanthrene was observed with thermal catalyst, indicating increased sulfate radical production. Slight enhancement of the pollutants oxidation was observed when initial sodium persulfate concentration increased from 5 to 50 g/L. However, the removal efficiency greatly decreased as soil/water ratio increased. It indicates that mass transfer of the pollutants as well as the contact between the pollutants and sulfate radical were inhibited in the presence of solids. In addition, more pollutants can be adsorbed on soil particles and soil oxidant demand increased when soil/water ratio becomes higher. The oxidation of the pollutants was significantly improved when catalyzed by Fe(II). The sodium persulfate consumption increased at the same time because the residual Fe(II) acts as the sulfate radical scavenger.

• Microbiology and Biotechnology Letters
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• v.28 no.6
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• pp.329-333
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• 2000

Alkaline bacterium producing a high pro-tease activity at low temperature was isolated by using enrichment culture from soil samples and identified as Bacil-lus sp. WRD-1 Cell growth was maximal at 10 hours and the optimal initial pH and culture time of culture condition for enzyme production was pH 7 and 10 hours, respectively. Temperature range of high enzyme activity were $10~40^{\circ}C$. The optimal pH and temperature for the enzyme activity were pH9 and $30^{\circ}C$.

• Geomechanics and Engineering
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• v.29 no.3
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• pp.281-290
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• 2022

The direct shear test is commonly used to evaluate the shear behavior of frozen soil-structure interfaces under normal stress. However, failure criteria, such as the Mohr-Coulomb failure criterion, are needed to obtain the unconfined shear strength. Hence, the punch shear test, which is usually used to estimate the shear strength of rocks without confinement, was examined in this study to directly determine the adfreezing strength. It is measured as the shear strength of the frozen soil-structure interface under unconfined conditions. Different soils of silica sand, field sand, and field clay were prepared inside the steel and concrete ring structures. Soil and ring structures were frozen at the target temperature for more than 24 h. A punch shear test was then conducted. The test results show that the adfreezing strength increased with a decrease in the target temperature and increase in the initial water content, owing to the increase in ice content. The adfreezing strength of field clay was the smallest when compared with the other soil specimens because of the large amount of unfrozen water content. The field sand with the larger normalized roughness showed greater adfreezing strength than the silica sand with a lower normalized roughness. From the experiment and analysis, the applicability of the punch shear test was examined to measure the adfreezing strength of the frozen soil-structure interface. To find a proper sample dimension, supplementary experiments or numerical analysis will be needed in further research.

• Journal of Microbiology and Biotechnology
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• v.11 no.4
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• pp.607-613
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• 2001

The biodegradation rates of diesel oil by a selected diesel-degrading bacterium, Pseudomonas stutzeri strain Y2G1, and microbial consortia composed of combinations of 5 selected diesel-degrading bacterial were determined in liquid and soil systems. The diesel degradation rate by strain Y2G1 linearly increased $(R^2=0.98)$ as the diesel concentration increased up to 12%, and a degradation rate as high as 5.64 g/l/day was obtained. The diesel degradation by strain Y2G1 was significantly affected by several environmental factors, and the optimal conditions for pH, temperature, and moisture content were at pH8, $25^{\circ}C$, and 10%, respectively. In the batch soil microcosm tests, inoculation, especially in the form of a consortium, and the addition of nutrients both significantly enhanced the diesel degradation by a factor of 1.5 and 4, respectively. Aeration of the soil columns effectively accelerated the diesel degradation, and the initial degradation rate was obviously stimulated with the addition of inorganic nutrients. Based on these results, it was concluded that the major rate-limiting factors in the tested diesel-contaminated soil were the presence of inorganic nutrients, oxygen, and diesel-degrading microorganisms. To resolve these limiting parameters, bioremediation strategies were specifically designed for the tested soil, and the successful mitigation of the limiting parameters resulted in an enhancement of the bioremediation efficiency by a factor of 11.