• Title/Summary/Keyword: Initial concentration

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Effect of Initial Volume of Hard Water and Contact Time on the Reduction of Calcium Ion Concentration using High Voltage Impulse Technique (고전압 임펄스 기술을 활용한 경도 제거에서 경수의 초기부피와 인가시간이 칼슘이온 농도에 미치는 영향)

  • Cho, Seung-Yeon;Kim, Tae-Hui;Chang, In-Soung;Hong, Woong-ki;Lee, June-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.7
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    • pp.1066-1071
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    • 2017
  • Recently high voltage impulse (HVI) technique has been extensively studied for desalting processes to control the $CaCO_3$ scale formation in industrial water practices such as power plant, boiler, and heat exchange operations. Investigation of the operational parameters for the HVI is important, however, those had not been reported yet. In this study, the effect of initial feed volume and contact time on reduction of calcium ion concentration by the HVI technique was investigated. Initial feed volumes of artificial hard water which contained 100 mg/L of $Ca^{2+}$, were set to 1, 2, and 3 L respectively. After 24hr of HVI contact with 12kV, $Ca^{2+}$ ion was reduced to 50, 29 and 19 % of their initial concentration, indicating that calcium removal increased as initial feed volume decreased. This implies the applied HVI pulse energy per unit mass of calcium is important parameter determining overall desalting efficiency. A series of extended operations of HVI up to 30 days verified the long term stability of the HVI system. The calcium ion declined to 40 mg/L after 2~3 days, and further reduction of calcium was not achieved, indicating that optimum operation time could be 2~3 days under these experimental conditions. Consequently, it was confirmed that the important operational parameter of HVI technique is initial feed volume and contact time as well as the applied voltage that was already proven in the previous study.

The effect of gap between ingot and crucible on the distribution of initial melt concentration in Bridgman crystal growth (Bridgman 결정성장시 장입 주괴와 도가니 사이의 틈이 용액이 초기농도에 미치는 영향)

  • Seung-Mo Chung;Man-Sug Kang;Zin-Hyoung Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.2
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    • pp.169-177
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    • 1994
  • Dilute Al-Cu and Al-Mg alloys were solidified unidirectionally upward by Bridgman method. It is necessary that solute concentration of initial melt is uniform to be able to control the concentration of crystal. When solute concentration is not uniform, it can cause unusual macro-segregation in grown solid. A non-steady state solidification was observed where the solute concentration in the grown solid decreased with the progress of solidification, when a dilute Al-Cu melt with positive axial temeprature gradient was solidified. This was caused by leaking out of Cu-rich melt into the gap between ingot and crucible during melt-down and its sedimentation after complete melting. In the case of Al-Mg alloy, the solute concentration has a minimum in the middle of grown specimen because Mg-rich melt flowed down the gap between ingot and crucible and floated after complete melting. Uniform initial melt concentration can be achieved by the homogenization of the ingot or by the absence of the gap between ingot and crucible.

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Effects of Initial Concentration and Moisture Content on the Removal of Phenol in Soil (초기농도 및 수분함량이 토양내 페놀의 제거에 미치는 영향)

  • Namkoong, Wan;Park, Joon-Seok;In, Byung-Hoon;Lee, Noh-Sup;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.37-44
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    • 2001
  • This study was carried out to evaluate the effects of initial concentration and moisture content on removal of phenol in soil. Texture of soil used was sandy loam. Air was supplied at the rate of $31{\ell}/m^3$(soil)/min. Initial phenol concentrations of contaminated-soils were about 700mg/kg and 1,200mg/kg(as dry weight basis), respectively. Low phenol concentration (about 700mg/kg) was degraded more rapidly than high concentration (about 1,200mg/kg). After phenol concentration of 1,200mg/kg was decreased to about 700mg/kg, its degradation was similar to the case of initial phenol concentration of about 700mg/kg. Phenol degradationrate rate of 15% soil moisture content was higher than that of 20%.

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Factors Influencing Nitrite Build-up Nitrification of High Strength Ammonia Wastewater (고농도 암모니아성 폐수의 질산화과정에서 아질산염 축적의 영향인자)

  • 한동준;강성환;임재명
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.128-138
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    • 1998
  • This study was focused to find how each factors effect on the biological nitrification in wastewater treatment under high ammonia nitrogen concentration. Batch reactors in aerobic conditions were used to test the treatment efficiency of mixed liquor, nightsoil and piggery wastewater. The results are summeried as follows; Initial ammonia nitrogen concentration and pH were the direct influencing factors of nitrite build-up. More than 250 mg NH$_{4}$$^{+}$ - N/L in initial concentration built up nitrite and then the inhibition rate to Nitrobacter was above 70 percentage. And maximum nitritation rate was showed at pH 8.3 and nitrification could be completely achieved by pH control. Temperature and dissolved oxygen were the indirect influencing factors of nitrite build-up. These were a great effect on the activity of nitrifying microbes and ammonia nitrogen removal. Maximum nitritation rate was showed at 30 $\circ $C. The effect of DO concentration was negligible at more than 3 mg/L.

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THE EFFECTS OF CONCENTRATION AND pH OF LACTIC ACID ON THE FORMATION OF ARTIFICIAL ROOT CARIES LESION (젖산의 농도와 pH가 인공 치근 우식 병소의 형성에 미치는 영향)

  • Lim, Yoo-Koung;Hur, Bok;Lee, Hee-Ju
    • Restorative Dentistry and Endodontics
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    • v.22 no.2
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    • pp.637-647
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    • 1997
  • The purpose of this study was to evaluate the effect of concentration and pH of lactic acid on the formation of artificial root caries lesions formation in bovine teeth. The characterictics of artificially produced early root lesions were observed with polarized light microscope and the depth of lesions were mearsured with measuring microscope The results were as follows: 1. In the group of low pH and high concentration of lactic acid, the progress of lesion formation was faster than that of high pH and low concentration lactic acid group. 2. In the same group, initial lesion progress faster, but progression rate was reduced as time goes by. 3. In the development of initial root caries, cementum was act as a barrier to protect dentin from lesion progression.

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Comparative Sonophotocatalysis and Photocatalysis for Chloroform Degradation (Sonophotocatalysis와 Photocatalysis를 이용한 Chloroform의 광산화)

  • Park, Jae-Hong;Cho, Il-Hyoung
    • Journal of Korean Society on Water Environment
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    • v.21 no.3
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    • pp.263-266
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    • 2005
  • Comparison between photocatalysis (UV+$TiO_2$) and sonophotocatalysis (Sonication+UV+$TiO_2$) were performed in lab-scale experiments for the treatment of chloroform. The effect of operational parameters, i.e., initial chloroform concentration, $TiO_2$ concentration, UV light intensity and sonication time on the degradation rate of aqueous solution of chloroform has been examined. The optimal conditions for photocatalysis and sonophotocatalysis processes were determined: initial chloroform concentration was 25 mg/L, the concentration of $TiO_2$ was 200 mg/L and UV light intensity was $6.630 mW/cm^2$, respectively. The optimal sonication time on sonophotocatalysis process was 90 min. Under the optimal conditions, sonophotocatalysis was effective for inducing faster degradation of the chloroform.

Low concentration cadmium removal using weathered sand of basalt

  • Park, Jae Hong;Lee, Jae Kwan;Shin, Dong Seok
    • Membrane and Water Treatment
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    • v.12 no.2
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    • pp.51-58
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    • 2021
  • The natural weathered sand of basalt (WSB) has been used for the removal of cadmium from aqueous solution. The influence of various parameters i.e., contact time, pH, weathered sand of basalt dosage, particle size of the weathered sand of basalt, temperature and initial cadmium concentration were analyzed. Cadmium adsorption kinetics was well described by the pseudo second order model. Adsorption equilibrium for cadmium was properly well fitted to Langmuir isotherm model with maximum adsorption capacity 0.50 mg/g. Compared with the other experimental results using various kinds of adsorbents at a low concentration (1.0 mg/L or so) similar to that of this study, the cadmium removal efficiency using weathered sand of basalt was higher. It has been demonstrated that weathered sand of basalt has a available alternative adsorbent for cadmium when its initial concentration is low.

Studies of the Passivation Film as a Function of the Concentration of Electrolyte in Lithium-ion Battery

  • Jeong, Gwang Il;Jeong, Myeong U;Kim, U Seong;Kim, Sin Guk;Seong, Yong Eun;Choe, Yong Guk
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.189-193
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    • 2001
  • The irreversible capacities caused by the reduction of solvent on the surface of a negative electrode (KMFC:Kawasaki Mesophase Fine Carbon) were examined during the initial cycle in ethylene carbonate (EC)-diethyl carbonate (DEC) electrolyte solut ions at various concentrations of LiPF6. Chronopotentiograms, linear sweep voltammograms, and impedance spectra clearly showed differences in irreversible capacity and that those differences are related to the concentration of electrolyte during the initial charge. These differences were caused by the amount of solvent decomposition as a function of the concentration of LiPF6 electrolytic salt. The data are discussed with reference to the concentration of electrolytic salt and the properties of passivation film formed by solvent decomposition.

An Experimental Study on the VOCs Concentration Variation using a Petroleum Spill Imitation Trial Test Chamber (원유유출 모의시험 챔버를 이용한 휘발성유기화합물(VOCs)의 농도변화에 관한 연구)

  • Chung, Jin-Do;Lee, Dong-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.4
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    • pp.393-398
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    • 2010
  • This study prepared and utilized an imitation trial test chamber for a petroleum spill to predict the concentration of discharged Volatile Organic Compounds in the air at the time of Tae-An peninsula's petroleum spill, which happened in December, 2007. The petroleum spill imitation trial test chamber measured and analyzed the concentration variation of total VOCs. As the ambient air velocity increased, so the concentration of VOCs decreased; and as the water temperature rose, the concentration of VOCs increased. Furthermore, it appears that total concentration of VOCs decrease by more than 90% 6 days after the initial petroleum spill compared to the initial concentration of VOCs.

Effects of Initial Concentration and Nutrients in Treatment of petroleum Hydrocarbon Contaminated Soils using a Slurry-Phase Bioreactor (슬러리상 생물반응기를 이용한 석유계탄화수소 오염토양의 처리에 있어서 초기농도 및 영양소의 영향)

  • 김수철;남궁완;박대원
    • Journal of Korea Soil Environment Society
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    • v.3 no.3
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    • pp.45-53
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    • 1998
  • The purpose of this study was to evaluate effects of initial concentration and nutrients in treatment of petroleum hydrocarbon contaminated soils. The reactor used in this study was slurry-phase bioreactor of in-vessel type. Performance results on treatment of diesel fuel contaminated soils and micorbial growth were generated at the bench-scale level. The fate of TPH(Total Petroleum Hydrocarbon) and the microbial growth were evaluated in combination with biodegradation rate. Effect of initial loading levels of 50,000 and 100,000mg TPH/kg soil was studied. Performance results with two reactors were showed at the total TPH removal rate of 90.5% and 90.8%, respectively. However, the reactor with the initial concentration of 50,000mg TPH/kg soil showed higher biological TPH removal efficiency except for removal by volatilization than the other Although the different amount of nutrients was applied in two reactors, there was no remarkable difference in microbial growth rate. However, considerable factor in this results was that applied different initial concentration to two reactors. Although initial concentration was two times higher than it applied to the reactor without addition of nutrients, in total and biological TPH removal rate the reactor with addition of nutrients showed a higher than the other.

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