• 제목/요약/키워드: Initial Solution

검색결과 2,473건 처리시간 0.026초

화산재에 의한 수용액의 납 이온 흡착특성 (Adsorption characteristics of lead ion in aqueous solution by volcanic ash)

  • 김미연;소명기;김영관
    • 상하수도학회지
    • /
    • 제25권3호
    • /
    • pp.359-366
    • /
    • 2011
  • The feasibility of using volcanic ash for lead ion removal from wastewater was evaluated. The adsorption experiments were carried out in batch tests using volcanic ash that was treated with either NaOH or HCl prior to the use. Volcanic ash dose, temperature and initial Pb(II) concentration were chosen as 3 operational variables for a $2^3$ factorial design. Ash dose and concentration were found to be significant factors affecting Pb(II) adsorption. The removal of Pb(II) was enhanced with increasing volcanic ash dose and with decreasing the initial Pb(II) concentration. Pb(II) adsorption on the volcanic ash surface was spontaneous reaction and favored at high temperatures. Calculation of Gibb's free energy indicated that the adsorption was endothermic reaction. The equilibrium parameters were determined by fitting the Langmuir and Freundlich isotherms, and Langmuir model better fitted to the data than Freundlich model. BTV(base-treated volcanic ash) showed the maximum adsorption capacity($Q_{max}$) of 47.39mg/g. A pseudo second-order kinetic model was fitted to the data and the calculated $q_e$ values from the kinetic model were found close to the values obtained from the equilibrium experiments. The results of this study provided useful information about the adsorption characteristics of volcanic ash for Pb(II) removal from aqueous solution.

Removal of methylene blue using lemon grass ash as an adsorbent

  • Singh, Harminder;Dawa, Tshering B.
    • Carbon letters
    • /
    • 제15권2호
    • /
    • pp.105-112
    • /
    • 2014
  • Wastewater from textile industries is a major cause of water pollution in most developing countries. In order to address the issues of water pollution and high cost for treatment processes, the use of an inexpensive and environmentally benign adsorbents has been studied. The objective was to find a better alternative to the conventional methods. Lemon grass waste (ash) collected from a lemon grass stream distillation subunit in Bhutan was tested for dye removal from aqueous solutions. The study investigated the removal of methylene blue using the following operational parameters: initial concentration (100-600 mg/L), contact time, adsorbent dose (0.1-0.55 gm/100 mL), and pH (3-10). It was found that the percentage removal of dye increased with a decrease of the initial concentration and increased contact time and dose of adsorbent. The basic pH solution of dye showed better adsorption capacity as compared to the acidic dye solution. Langmuir and Freundlich adsorption isotherms were fitted to the data well. Data fitted better to Lagergren pseudo 2nd order kinetics than a 1st order kinetic model. Surface morphology was also examined via scanning electron microscopy. An elemental analysis was also carried out and the chemical composition and functional groups were analyzed using energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy techniques, respectively. The obtained results indicate that lemon grass ash could be employed as a low cost alternative to commercial activated carbon in wastewater treatment for the removal of dyes.

Antimicrobial Effect of Acidified Sodium Chlorite (ASC) on Whole Croaker

  • Lee, Byung-Doo;Koo, Ja-Heon;Jahncke, Michael L.;Kim, Du-Woon;Chung, Dong-Ok;Eun, Jong-Bang
    • Preventive Nutrition and Food Science
    • /
    • 제13권4호
    • /
    • pp.266-268
    • /
    • 2008
  • The antimicrobial effect of acidified sodium chlorite (ASC) solution on whole croaker skin was evaluated. Whole croaker skin was treated with ASC (50, 100, 200, 400, and 600 ppm) and distilled water. After 10-minute exposure to 600 ppm ASC, 8% of Gram-negative bacteria survived on the whole croaker sample. Treatment with 50 ppm ASC eliminated all coliforms in the initial load. Immersion treatment with 600 ppm ASC resulted in $1.3\;log\;CFU/cm^2$ greater kill of the initial mesophile loads of control ($2.8\;log\;CFU/cm^2$) than distilled water. Fifty ppm ASC solution produced a 1.6-log reduction of psychrotrophic bacteria. ASC treatment was an effective method for reducing naturally occurring microflora on whole croaker skin.

Numerical modeling of two-dimensional simulation of groundwater protection from lead using different sorbents in permeable barriers

  • Masood, Zehraa B.;Ali, Ziad Tark Abd
    • Environmental Engineering Research
    • /
    • 제25권4호
    • /
    • pp.605-613
    • /
    • 2020
  • This study is to investigate the possibility of using activated carbon prepared from Iraqi date-pits (ADP) which are produced from palm trees (Phoenix dactylifera L.) as low-cost reactive material in the permeable reactive barrier (PRB) for treating lead (Pb+2) from the contaminated groundwater, and then compare the results experimentally with other common reactive materials such as commercial activated carbon (CAC), zeolite pellets (ZP). Factors influencing sorption such as contact time, initial pH of the solution, sorbent dosage, agitation speed, and initial lead concentration has been studied. Two isotherm models were used for the description of sorption data (Langmuir and Freundlich). The maximum lead sorption capacities were measured for ADP, CAC, and ZP and were found to be 24.5, 12.125, and 4.45 mg/g, respectively. The kinetic data were analyzed using various kinetic models particularly pseudo-first-order, pseudo-second-order, and intraparticle diffusion. COMSOL Multiphysics 3.5a depend on finite element procedure was applied to formulate transmit of lead (Pb+2) in the two-dimensional numerical (2D) model under an equilibrium condition. The numerical solution shows that the contaminant plume is hindered by PRB.

Effect of pH on Successive Foam and Sonic Droplet Fractionation of a Bromelain-invertase Mixture

  • Ko Samuel;Prokop Ales;Tanner Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제7권1호
    • /
    • pp.26-30
    • /
    • 2002
  • A droplet fractionation method was previously developed to concentrate a dilute nonfoaming protein solution. In that earlier study with invertase, it was demonstrated that droplets created by ultrasonic energy waves could be enriched up to 8 times that of the initial dilute invertase solution. In this study, a mixture of bromelain (a foaming protein) and invertase (a nonfoaming protein) is investigated as a preliminary step to determine if droplet fractionation can also be used to separate a non-foaming protein from foaming proteins. The foaming mixture containing bromelain is first removed by bubbling the binary mixture with air. After the foam is removed, the protein rich air-water interfacial layer is skimmed off (prior to droplet fractionation) so as not to interfere with the subsequent droplet production from the remaining bulk liquid, rich in non-foaming protein. Finally, sonic energy waves are then applied to this residual bulk liquid to recover droplets containing the non-foaming protein, presumed to be invertase. The primary control variable used in this droplet fractionation process is the pH, which ranged for separate experiments between 2 and 9. It was observed that the maximum overall protein partition coefficients of 5 and 4 were achieved at pH 2 and 4, respectively, for the initial foaming experiment followed by the post foaming droplet fractionation experiment.

Robust Most Significant Periods of Developments In Time Dominated Data

  • Aboukalam, F.
    • International Journal of Reliability and Applications
    • /
    • 제7권2호
    • /
    • pp.101-110
    • /
    • 2006
  • Let E be a set of n quantitative observations under the time control. The interval of time is to be split into several subintervals such that the observations in each subinterval are almost similar, whereas the observations between the subintervals are very dissimilar. The corresponding time-subintervals become periods or phases of the development that exist in the underlying phenomenon. Aboukalam(2005) proposes a robust solution based on some initial subintervals and a technique for combining any two successive groups in that starter using a t-test under a fixed significant level ($\alpha$). The inconvenience is that; the technique reliability is not released from the level $\alpha$ which must not be defined apart from the number of the periods that is, in its turn, unknown. To avoid this, we propose what so called; most significant periods solution. The new technique constructs its own initial subintervals and uses another way for combining the groups. However, the way of determining and treating outliers has not changed. This paper conducts many empirical simulations using different possible time dominated data in order to illustrate the reliability of the proposed technique. Finally, we apply both techniques on some real time dominated data to explain the advantage of the proposal.

  • PDF

Kinetic Modeling for Biosorption of Metylene Blue onto H3PO4 Activated Acacia arabica

  • Sivarajasekar, N.;Srileka, S.;Samson Arun Prasath, S.;Robinson, S.;Saravanan, K.
    • Carbon letters
    • /
    • 제9권3호
    • /
    • pp.181-187
    • /
    • 2008
  • Batch sorption experiments were carried out for the removal of metylene blue from its aqueous solution using $H_3PO_4$ activated Acacia arabica carbon (AAC). The prepared activated carbon was characterized and was found as an effective adsorbent material. The operating variables studied were initial metylene blue concentration, AAC concentration and solution pH. AAC activated carbon posses a maximum sorption capacity for the range of initial dye concentrations studied (60~100 mg $L^{-1}$). The sorption kinetics were analyzed using reversible first order kinetics, second order, reversible first order, pseudo-first order, and pseudo-second order model. The sorption data tend to fit very well in pseudo-second order model for the entire sorption time. The average pseudo-second order rate constant, $K_{II}$ and regression coefficient value were determined to be 0.0174 mg $g^{-1}$ $min^{-1}$ and 0.9977. The biosorption process also fit well to reversible I order kinetics with a regression coefficient of 0.9878.

SS41강의 F.E.M.복합조직강에서 노치변화가 부식피로파괴에 미치는 영향 (Influence of Notch Change on Corrosion Fatigue Fracture in F.E.M. Dual phase Steel of SS41 Steel)

  • 도영민;이규천
    • 한국안전학회지
    • /
    • 제16권2호
    • /
    • pp.44-50
    • /
    • 2001
  • The rotated bending fatigue test was conducted in air md in 3.5% NaCl salt solution to investigate the fatigue fracture behaviour of raw material and F.E.M dual phase steel made from raw material(SS41) by a suitable heat treatment. This study has compared the initial microcrack creation of material by tensile test with that by fatigue test. And the rotated bending test of cantilever type under the condition of 3.5% NaCl salt solution and air has investigated the corrosion fatigue fracture behaviour with the variation of stress concentration factor determined by each of notch shapes. The initial microcrack have been developed in fragile grainboundary with general corrosion occurring in raw material : in the pits built up by corrosion in F.E.M. dual phase steel because pits bring out stress concentration. It is small that the degree of decrease in corrosion fatigue life for F.E.M. dual phase steel compared with raw material because the notch sensitivity of F.E.M. dual phase steel is lower than raw material in reason of characteristics with two-phase construction.

  • PDF

Analytical solution for analyzing initial curvature effect on vibrational behavior of PM beams integrated with FGP layers based on trigonometric theories

  • Mousavi, S. Behnam;Amir, Saeed;Jafari, Akbar;Arshid, Ehsan
    • Advances in nano research
    • /
    • 제10권3호
    • /
    • pp.235-251
    • /
    • 2021
  • In the current study, the free vibrational behavior of a Porous Micro (PM) beam which is integrated with Functionally Graded Piezoelectric (FGP) layers with initial curvature is considered based on the two trigonometric shear deformation theories namely SSDBT and Tan-SDBT. The structure's mechanical properties are varied through its thicknesses following the given functions. The curved microbeam is exposed to electro-mechanical preload and also is rested on a Pasternak type of elastic foundation. Hamilton's principle is used to extract the motion equations and the MCST is used to capture the size effect. Navier's solution method is selected as an analytical method to solve the motion equations for a simply supported ends case and by validating the results for a simpler state with previously published works, effects of different important parameters on the behavior of the structure are considered. It is found that although increasing the porosity reduces the natural frequency, but enhancing the volume fraction of CNTs increasing it. Also, by increasing the central angle of the curved beam the vibrations of the structure increases. Designing and manufacturing more efficient smart structures such as sensors and actuators are of the aims of this study.

SIMULATED ANNEALING FOR LINEAR SCHEDULING PROJECTS WITH MULTIPLE RESOURCE CONSTRAINTS

  • C.I. Yen
    • 국제학술발표논문집
    • /
    • The 2th International Conference on Construction Engineering and Project Management
    • /
    • pp.530-539
    • /
    • 2007
  • Many construction projects such as highways, pipelines, tunnels, and high-rise buildings typically contain repetitive activities. Research has shown that the Critical Path Method (CPM) is not efficient in scheduling linear construction projects that involve repetitive tasks. Linear Scheduling Method (LSM) is one of the techniques that have been developed since 1960s to handle projects with repetitive characteristics. Although LSM has been regarded as a technique that provides significant advantages over CPM in linear construction projects, it has been mainly viewed as a graphical complement to the CPM. Studies of scheduling linear construction projects with resource consideration are rare, especially with multiple resource constraints. The objective of this proposed research is to explore a resource assignment mechanism, which assigns multiple critical resources to all activities to minimize the project duration while satisfying the activities precedence relationship and resource limitations. Resources assigned to an activity are allowed to vary within a range at different stations, which is a combinatorial optimization problem in nature. A heuristic multiple resource allocation algorithm is explored to obtain a feasible initial solution. The Simulated Annealing search algorithm is then utilized to improve the initial solution for obtaining near-optimum solutions. A housing example is studied to demonstrate the resource assignment mechanism.

  • PDF