• Journal of Korean Society of Water and Wastewater
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• v.27 no.1
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• pp.21-29
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• 2013

Present study was conducted to evaluate the performance of Anaerobic Hybrid Reactor (AHR) combined with two types of anaerobic attached growth reactors at mesophilic temperature ($37^{\circ}C$). The reactor was operated at the influent substrate condition of 19,400 mg/L soluble chemical oxygen demand (sCOD). The organic loading rate (OLR) and flow rate were varied in the range of $9.5{\sim}22.5kg/m^3$. day and 10.6 ~ 26.0 L/day respectively since start-up was done. The COD removal efficiency of 93 % was measured at the OLR of $14kg/m^3$. day in AHR. However a reduction in removal efficiency to as low as 85 % could have been related to a combined effect of high concentration suspended solids (SS) concentration over 3,800 mg/L. On the other hand the total COD removal efficiencies were measured to be 96.3 % and 96.2 % for AHR+APF and AHR+ADF respectively. The pH of the POME was adjusted to neutral range by using sodium bicarbonate at the initial stages of the reactor feed, later stages pH adjustment was not required as the pH was maintained in the desired neutral range due to self-buffering capacity of the reactor. The reactor proved to be economically acceptable and operationally stable. The biogas was measured to have $CH_4$ and $CO_2$ with a ratio of 35:65, and methane gas production rate was estimated to be $0.17{\sim}10.269L\;CH_4/g\;COD_{removed}$.

• Korean Journal of Environmental Agriculture
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• v.22 no.4
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• pp.251-254
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• 2003

Phosphorous removal rate and emergent plant growth were examined of a surface-flow constructed treatment wetland system, whose dimensions were 31 meter in length and 12 meter in width. The system was established on floodplain in the down reach of the Kwangju Stream in Korea in one and half months from May to June 2001. Cattails(Typha angustiflora) were transplanted in the system. They were dug out of natural wetlands and stems were cut at about 40 cm height from their bottom ends. Water of the Kwangju Stream were funneled into it via a pipe by gravity flow and its effluent were discharged back into it. The stems of cattails grew from 45.2 cm in July 2001 up to 186 cm in September 2001 and the number of cattail stems per square meter increased from 22 in July 2001 to 53 in September 2001. The early establishment of cattails was good. Volume and water quality of inflow and outflow were analyzed from July 2001 through December 2001. Inflow averaged $40\;m^3/day$ and hydraulic retention time was about 1.5 days. The concentration of total phosphorous in influent and effluent was 0.85 mg/L, 0.41 mg/L, respectively. The average removal rate of total phosphorous in the system was about 52%. The retention efficiency was slightly lower, compared with that in surface-flow wetlands operating in North America, whose retention efficiency was reported to be about 57%. The lower abatement rate could result from the initial stage of the system and inclusion of two cold months into the six-month monitoring period. Root rhizosphere in wetland soils and litter-soil layers on bottoms were not properly developed. Increase of standing density of cattails within a few years will establish both root zones and substrates beneficial to the removal of phosphorous, which may lead to increase of the phosphorous retention rate. The system was submerged one time by heavy storm during the monitoring period. The inundation, however, scarcely disturb its environment.

• Environmental Engineering Research
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• v.15 no.2
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• pp.79-84
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• 2010

Three biological aerated filters (BAFs) composed of a PVC pipe with a diameter of 75 mm were constructed and operated at a waste-water temperature at $13^{\circ}C$. The media used for each BAF were: 5-mm gravel; 5-mm lava rock; 12.5-mm diameter by 15-mm long plastic rings, all with a media depth of 1.7 m. The feedwater, which simulated the effluent of aerated lagoons, had influent soluble chemical oxygen demand (sCOD) and ammonia concentrations of approximately 50 and 25 mg/L, respectively. For a hydraulic retention time (HRT) of two hours without recirculation, ammonia percent removals were 98.5, 98.9, and 97.8%, for the gravel, lava rock, and plastic rings, respectively. By increasing the effluent recirculation from 100 to 200% for an HRT of one hour, respective ammonia removals improved from 90.1 to 96, 76.5 to 90, and 65.3 to 79.5% for gravel, lava rock, and plastic rings. Based on the ammonia and sCOD loadings for different HRTs, the estimated maximum ammonia loading was approximately 0.6 kg $NH_3-N/m^3$-day for the three BAFs of different media types. The zero-order biotransformation rates for the BAF with gravel were found to be higher than the lava rock and plastic ring media. The results ultimately showed that BAF can be used as an add-on system to aerated lagoons or as a secondary treatment unit to meet ammonia discharge limits.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.37-44
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• 2000

Laboratory experiments were conducted to investigate the performances of anaerobic filters packed with ceramic tube and pall-ring media treating a dairy waste. The media packing volume was 65% of effective volume of anaerobic filter. Organics removals of anaerobic filters were maintained above 80% even at an organics loading rate of $10kgCOD/m^3/d$, and this was comparable to aerobic treatment of organic wastes. Organics removals of the ceramic tube anaerobic filters were always lower than those of the pall-ring anaerobic filters due to intrinsic physical property of ceramic tube, especially lower void space which caused to clogging and entrapment of biogas, substrate transfer limitation, and irregular evolution of biogas leading to loss of solids and biomass. This was clearly observed in higher concentration of TSS in the effluent from the ceramic tube anaerobic filter despite of higher retention capacity of TSS compared with pall-ring media. Vertical distribution of organics and solids in the filters showed above 90% of organics and solids in influent were removed below 20% of reactor height, and 50% of remaining organics and solids were removed though media packing zone. Effluent quality from the anaerobic filter was heavily depended on media itself as well as suspended biomass formed below media. It is therefore concluded that the type of media played an important role in biomass accumulation arid gas-liquid-solid separation efficiency. Type of media did not affect the start-up behaviors of the anaerobic filter, and supernatant from anaerobic digested sludge showed a good performance as a seeding materials.

• Journal of Environmental Health Sciences
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• v.38 no.6
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• pp.568-574
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• 2012

Objectives: The purpose of this experiment is to understand the phosphorus removal ratio effects of iron plates per unit of surface area through the iron electrolysis system, which consists of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis, which uses an iron precipitation reactor in anoxic and oxic basins, consisted of iron plates with total areas of 400 $cm^2$, 300 $cm^2$ and 200 $cm^2$ respectively. The FNR process was operated with a hydraulic retention time and a sludge retention time of 12 hours and three days, respectively. Wastewater used in the experiments was prepared by dissolving $KH_2PO_4$ in influent water. Results: The iron plates 400 $cm^2$ (16.6 $mA/cm^2$), 300 $cm^2$ (13.3 $mA/cm^2$) and 200 $cm^2$ (7.3 $mA/cm^2$) in surface area in the phosphorus reactor had respective phosphorus of 2.4 mg/l, 2.7 mg/l and 3.2 mg/l in the effluent and phosphorus removal respective efficiencies of 90.3%, 89.1% and 87.1%. The effluent in the reactor, where the iron plate was not used, had relatively very low phosphorus removal efficiency showing phosphorus concentration of 15.3 mg/l and a phosphorus removal efficiency about 38.3%. Phosphorus removal per ferrous was 0.472 mgP/mgFe in the iron electrolysis system where the surface area of iron was low. Phosphorus pollution load per active surface area and the phosphorus removal efficiency had an interrelation of RE = -0.27LS + 89.0 (r = 0.85). Conclusion: With larger iron plate surface area, the elution of iron concentration and phosphorus removal efficiency was higher. The removal efficiency of phosphorus has decreased by increasing the initial phosphate concentration in the iron electrodes. This shows a tendency of decreasing phosphorus removal efficiency because of decreasing of iron deposition as the phosphorus pollution load per active surface area increases.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.5 no.6
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• pp.24-29
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• 2002

Nitrate removal rate in three cattail wetland cells was investigated. They were a part of a pond-wetland system for stream water treatment demonstration. The system was composed of two ponds and six wetland cells. The acreage of each cell was approximately $150m^2$. The earth works for the system were finished from April 2000 to May 2000 and cattails were planted in the three cells in June 2000. Waters of Sinyang Stream flowing into Kohung Estuarine Lake were pumped into a primary pond, whose effluent was discharged into a secondary pond. The reservoir was formed by a tidal marsh reclamation project and located in southern coastal area of Korean Peninsula. Effluents from the secondary pond were funneled into the three cells. Volumes and water quality of inflow and outflow were analyzed from July 2000 through January 2001. Inflow and outflow averaged $20.2m^3/day$ and $19.8m^3/day$, respectively. Hydraulic retention time was about 1.6 days. Average influent and effluent nitrate concentration was $1.98mg/{\ell}$, $1.38mg/{\ell}$, respectively. Nitrate removal rate averaged $82.6mg\;m^{-2}\;day^{-1}$. Seasonal changes of nitrate retention rates were closely related to those of wetland cell temperatures. The average nitrate removal rate in the cells was a little lower, compared with that of $125.0mg\;m^{-2}\;day^{-1}$ for the wetlands operating in North America. This could be attributed to the initial stage of the cells and inclusion of three cold months into the seven-month study period. Root rhizosphere in wetland soils and litter-soil layers on cell bottoms could not developed. Increase of standing density of cattails within a few years will establish both root zones suitable for the nitrification of ammonia to nitrates and substrates beneficial to the denitrification of nitrates into nitrogen gases, which may lead to increase of the nitrate retention rate.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.6 no.6
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• pp.49-55
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• 2003

Total phosphorous removal rate was examined of a subsurface-flow treatment wetland system which was constructed on floodplain in the down reach of the Kwangju Stream in Korea from May to June 2001. Its dimensions were 29 meter in length, 9 meter in width and 0.65 meter in depth. A bottom layer of 45 cm in depth was filled with crushed granite with about 15~30 mm in diameter and a middle layer of 10 cm in depth had pea pebbles with about 10 mm in diameter. An upper layer of 5 cm in depth contained course sand. Reeds(Phragmites australis) were transplanted on the surface of the system. They were dug out of natural wetlands and stems were cut at about 40 cm height from their bottom ends. Water of the Kwangju Stream flowed from a submerged dam into it via a pipe by gravity flow and treated effluent was funneled back into the Stream. The number of reed stems increased from 80 stems/$m^2$ in July 2001 to 136 stems/$m^2$ in September 2001. The hight of stems was 44.2 cm in July 2001 and 75.3 cm in September 2001. The establishment of reeds at early operating stage of the system was good. Volume and water quality of inflow and outflow were investigated from July 2001 through December 2001. The average inflow was 40 $m^3$/day and hydraulic detention time was about 1.5 days. The concentration of total phosphorous n influent and effluent was 0.83 and 0.33 mg/L, respectively. The removal rate of total phosphorous averaged about 60%. The removal efficiency was slightly higher, compared with that of subsurface-flow wetlands operating in North America, whose retention rate of total phosphorous was reported to be about 56%. The good abatement rate could be attributed to sedimentation of particle phosphorous in pores of the media and adsorption of phosphorous to the biofilm developed on the surface of them. Increase of standing density of reeds within a few years will develop root zones which may lead to increment in the phosphorous retention rate.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.71-74
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• 2001

AMB(Acid Mine Drainage), characterized as high concentration of metal & sulfate ions and low pH(2.0~4.0), is the world-wide problem wherever there is or has been mining activities. Though limestone has been generally used to neutralize AMD, There are metal hydroxide precipitation on the surface of limestone and excessive alkalinity formation which exceeds the regulation. In this research, concrete-recycled fine aggregate is selected for alternative neutralizing agent. Because fine recycled aggregate had more ANP than others in the preliminary research, the purpose of this research is to apply fine aggregate for AMD neutralization. Three columns packed with fine aggregates(2.5mm$O_3$) of it is calculated as 0.09(C-1), approximated 10% purity of limestone. Comparing with values of other columns(C-2: 0.01 and C-3: 0.01), there is variation of porosity and residence time induced from the precipitation of metal hydroxide. Consequently, 8 hours of HRT is enough to create adequate alkalinity and the function which could expect the variation of porosity(n) and residence time( $t_{R}$) should be applied to develop design function.lied to develop design function.

• Journal of Korean Society on Water Environment
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• v.33 no.5
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• pp.580-586
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• 2017

The fractionation characteristics of organic matter were investigated in inflow and effluent of each other pollution sources and river. While the DOC/TOC ratio in the influent of public sewage treatment plant and livestock disposal facilities was above 0.58, the POC/TOC ratio of human livestock Night soil treatment plant and stormwater runoff was more than 0.7. The TOC removal efficiency of public sewage treatment plant and human livestock Night soil treatment plant were 88.5 % and 99.6 %, respectively. Although the concentration distribution of organic matter pollution most of total organic carbon (TOC) in effluent of pollution sources accounted for dissolved organic carbon (DOC) type (DOC/TOC ratio >0.89) and Refractory-DOC (RDOC)/TOC ratio was higher (>0.65). The fractionation characteristics of organic matter in river were similar with that of sewage treatment plant and TOC concentration showed the positive correlation with DOC ($r^2=0.93$) and RDOC ($r^2=0.89$) concentration. The decay rate of Labile DOC (LDOC) (avg. $0.128day^{-1}$) was higher than labile particulate organic carbon (LPOC) ($0.082day^{-1}$), while that of DOC ($0.008day^{-1}$) was lower than POC ($0.039day^{-1}$) (paired t-test, p < 0.001, n = 5). These study results suggested that it should consider important both TOC and DOC as the target indicator to control refractory organic matter in pollution sources.

• Journal of Environmental Science International
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• v.14 no.2
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• pp.157-165
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• 2005

This study was conducted to determine optimum design parameters in nitrification and denitrfication of chemical fertilizer wastewater using pilot plant, Jet Loop Reactor. The chemical fertilizer wastewater which contains low amounts of organic carbon and has a high nitrogen concentration requires a post-denitrfication system. Organic nitrogen is hydrolyzed above $86\%$, and the concentration of organic nitrogen was influent wastewater 126mg/L and of effluent wastewater 16.4mg/L, respectively. The nitrification above $90\%$ was acquired to TKN volumetric loading below $0.5\;kgTKN/m^3{\cdot}d$, TKN sludge loading below $0.1\;kgTKN/kgVSS{\cdot}d$ and SRT over 8days. The nitrification efficiency was $90\%$ or more and the maximum specific nitrification rate was $184.8\;mgTKN/L{\cdot}hr$. The denitrification rate was above $95\%$ and the concentration of $NO_3-N$ was below 20mg/L. This case was required to $3\;kgCH_3OH/kgNO_3-N$, and the effluent concentration of $NO_3^--N$ was below 20mg/L at $NO_3^--N$ volumetric loading below $0.7\;kgNO_3^--N/m^3{\cdot}d$ and v sludge loading below $0.12\;kgNO_3^-N/kgVSS{\cdot}d$. At this case, the maximum sludge production was $0.83\;kgTS/kgT-N_{re}$ and the specific denitrfication rate was $5.5\;mgNO_3-N/gVSS{\cdot}h$.