• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2005년도 생물공학의 동향(XVII)
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• pp.266-269
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• 2005

This study targeted methane production and decrease of organic materials concentration by high temperature anaerobic digestion of food waste. A anaerobic reactor with circulation was employed and the operation condition as follows: high temperature of $45{\pm}2,$ 0.6 $kg-VS/m^3/d,$ HRT of 70 days, pH of $6.8{\sim}7.2$. The CODcr removal rate of $75%{\sim}85%$ with effluent of $14,000{\sim}19,000$ mg/L in case of influent of $75,000{\sim}95,000$ mg/L showed. In influent TS(Total Solid) and VS(Volatile Solid) concentration of $2.94%{\sim}5.09%,$ and $2.98{\sim}5.01%,$ the effluent concentration was $0.65{\sim}1.1%$ and $0.6%{\sim}0.8%,$ respectively. 0.28 $m^3-CH_4$ / kg-VS was averagely obtained in the system.

• Journal of Fisheries and Marine Sciences Education
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• 제28권3호
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• pp.746-759
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• 2016

In this study, we monitored the status of marine environment of olive flounder, Paralichythys olivaceus, culture ground in Jeju-do, Republic of Korea. It reported the consumption of raw olive flounder meat containing of Kudoa, Kudoa septempunctata, could induce vomitting and diarrhea in Japan. The Kudoa is a new mycosporean species, researchers found Kudoa from the muscles of olive flounder cultured at western Japan and imported from Jeju-do. We choose two Kudoa positive farms and two negative farms in the mid of concern about the relation between Kudoa and habitat. We found two marine invasive species at the water-pumping seabed at one of the Kudoa positive farm. The concentration of pH and DO at on-growing flounder farms showed the decreasing pattern along side the raceway (influent sea waters > on growing sea waters > outfluent sea waters). The TN and TP values increased gradually following to the raceway (influent sea waters < on growing sea waters < outfluent sea waters). The concentration of COD and SS were in the range of $0.100-2.581mg{\cdot}L^{-1}$, $1.00-12.70mg{\cdot}L^{-1}$, respectively. The calculated residence time was 4hr 32minutes at F1, 11hr 21minutes at F2, and 9hr 50minutes at F3, respectively. It was calculated same distance of 4 km away from effluent pipes. Although direct relation between Kudoa and marine environment could not define well based on this study result, the more studies on marine environmental stressors for olive flounder are required to conduct as a reliable method including socio-economic group and environmental group.

• Journal of Korean Society on Water Environment
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• 제33권4호
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• pp.481-486
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• 2017

This paper aims to evaluate the characteristics of direct and indirect effluents'toxicity level and difference between two test durations (24 h and 48 h) of test method. The proportion of the indirect effluent samples which exceeded the ecotoxicity permit limitations (TU 1 or TU 2) showed more than 2 times higher than that of direct effluent samples. However, effluent toxicity of Wastewater Treatment Plants (WTPs) indicated less than TU 1 regardless of influent toxicity. From this results, treatment process was thought to have a good efficiency. WTP Salinity was very similar between influent and effluent. This trend could be reconfirmed by the component ratio of ion concentration between them and $Na^+$, $SO_4^{2-}$, $C^-$ lions which have a greater percentage than other ions. In addition, in case of high salinity, toxicity value also showed high level. To judge from above results, indirect effluents which were exempted from application of ecotoxicity standards, may need a new effluent limitations regardless of the treatment efficiency of WTP. According to circumstances, effective countermeasure may need to restrain the discharge of salinity-contained effluents which came from indirect-effluent factories. Test duration comparative study indicated that 48 h results were higher toxicity (exceeding rate of ecotoxicity criteria) than 24 h by the 5 to 5.4 percentage. 24 h test duration seemed to be useful in case of rapid detection, whereas 48 h test method could be applied for reinforcement of ecotoxicity regulatory system.

• Journal of Environmental Health Sciences
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• 제35권4호
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• pp.334-342
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• 2009

Perfluorinated compounds (PFCs) have a wide range of domestic and industrial applications, but they are persistent in the environment. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) are among the metabolites of PFCs and occur at high concentration in the environment. Korea is the largest importer of PFC compounds in the world, therefore, the accumulation of these compounds is possible. In this study, the concentrations of PFOS and PFOA were determined in water samples taken from sewage treatment plants (STPs) and the Han River in Seoul, Korea. After extraction with a HLB cartridge, PFCs in the samples were analyzed by HPLC with an ion trap mass spectrometry in electrospray negative mode. Limits of detection was between 1 and 1.6 ng/l. The result showed that the concentrations of PFOS and PFOA in effluent and influent of the four STPs in Seoul were 60~570 ng/l, and not detected (nd)~254 ng/l, respectively. The levels of PFOS and PFOA were higher in the effluents which passed through the treatment process than in influent water samples which was against expectation. The concentration of PFOA and PFOS in the Han River was 60~570 ng/l and nd~254 ng/l, respectively. PFOA was detected in every sample, but PFOS was only detected in the downstreams of the Han River. This result indicates that there is comprehensive contamination of PFCs in the aquatic environment in Korea.

• Journal of Environmental Health Sciences
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• 제34권6호
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• pp.423-432
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• 2008

In this study, we investigated the possibility of auto control and the proper operating factors in the BNR(Biological Nutrient Removal) process using an NADH(Reduced Nicotinamide Adenine Dinucleotide) fluorometer, which characterized the emitted fluorescence when activated by flashes of UV light at 460 nm. In terms of finding adequate operating parameters, results indicted that nitrification efficiency decreased in the controlled DO while denitrification efficiency decreased in the controlled pH. The above results indicated that controlled operating condition after combination with NADH, DO and pH was resonable. Result obtained from the correlation between NADH and pH showed that variation trend of influent loading was similar to those of NADH and pH, and also the variation cycle was repeated on a daily basis. Consequently, this result showed the increase of BOD loading caused the nitrification efficiency to decrease because air-flow, required for nitrification, was reduced, and so the NADH value was increased. From these results, it is possible to use NADH flourimetry to assess the variation of organic load and nitrification efficiency in the case of small change in influent pH such as in sewage and also to handle and operate the load variation in the auto control system using the NADH fluorometer.

• Membrane and Water Treatment
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• 제9권3호
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• pp.181-188
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• 2018

A sidestream contains the filtrate or concentrate from the belt filter press, filter backwash and supernatant from sludge digesters. The sidestream flow, which heads back into the sewage treatment train, is about 1-3% less than the influent flow. However, the sidestream can increase the nutrient load since it contains high concentrations of phosphorus and nitrogen. In this study, the removal of PO4-P with organic matter characteristics and bacteriological changes during the sidestream treatment via ladle furnace (LF) slag was investigated. The sidestream used in this study consisted of 11-14% PO4-P and 3.2-3.6% soluble chemical oxygen demand in influent loading rates. LF slag, which had a relatively high $Ca^{2+}$ release compared to other slags, was used to remove $PO_4-P$ from the sidestream. The phosphate removal rates increased as the slag particle size decreased 19.1% (2.0-4.0 mm, 25.2% (1.0-2.0 mm) and 79.9% (0.5-1.0 mm). The removal rates of dissolved organic carbon, soluble chemical oxygen demand, color and aromatic organic matter ($UV_{254}$) were 17.6, 41.7, 90.2 and 77.3%, respectively. Fluorescence excitation-emission matrices and liquid chromatography-organic carbon detection demonstrated that the sidestream treatment via LF slag was effective in the removal of biopolymers. However, the removal of dissolved organic matter was not significant during the treatment. The intact bacterial biomass decreased from $1.64{\times}10^8cells/mL$ to $1.05{\times}10^8cells/mL$. The use of LF slag was effective for the removal of phosphate and the removal efficiency of phosphate was greater than 80% for up to 100 bed volumes.

• Journal of Korean Society on Water Environment
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• 제22권2호
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• pp.215-221
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• 2006

This research presents results from laboratory and pilot-scale experiments to remove high-nitrate in pickling wastewater using the sequencing batch reactor (SBR) as a biological method. During the experimental periods, the influent concentrations of NOx-N and $Ca^{+2}$ were analyzed to be 350-1,600 and 700-800 mg/L, respectively. In order to provide carbon source for denitrification, methanol has been added in proportion to the influent nitrate loading. The mean concentrations of MLSS and MLVSS, the fraction of volatile solids in sludge and the sludge volume index were measured to be 27 g/L, 5 g/L, 18.5% and 7.5, respectively. The solid retention time was kept in the range of 18 to 22 days, specific denitrification rate ($U_{dn}$) was $0.301g{NO_3}^--N/gVSS/day$. The oxidized nitrogen concentration of effluent ranged 2-34 mg/L with an average of 5.2 mg/L, the overall reduction in total nitrogen was more than 99.2%. In order to treat the pickling wastewater including the high concentration of nitrate and $Ca^{+2}$, the continuous flow process is not suitable because the specific gravity of the sludge is considerably increased by $Ca^{+2}$, thus the SBR process is shown to be very effective to treat the pickling wastewater.

• Journal of Korean Society on Water Environment
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• 제22권2호
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• pp.358-363
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• 2006

KSMBR process is dynamic state advanced wastewater treatment applied with Trisectional Aeration (TSA) mode combined with membrane. TSA was remodeled conventional intermittent aeration which was operated nonaeration-aeration. TSA operates nonaeration ($N_1$) - aeration (A) - nonaeration ($N_2$) in Trisectional Aeration Reactor (TAR). Organics of influent could be nearly consumed to denitrification without influence by remained DO in TAR and it could be operated about sludge return ratio of 1Q (influent base). The purpose of this study was to apply KSMBR to the full-scale plant and to evaluate efficiency of nitrogen and phosphorus removal and TSA operation. The result of this study, average CODcr/T-N and CODcr/T-P ratio were 7.8 and 59.6, respectively. BOD, TCODcr, SS, T-N, T-P, E-coli removal efficiency were 98.4, 95.2, 73.0, 69.6, 99.95 %, respectively. KSMBR obtained high removal efficiencies of C, N and P when it applied full-scale plant.

• Journal of Korean Society on Water Environment
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• 제20권6호
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• pp.563-570
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• 2004

Phased isolation intrachannel clarifier ditch process developed in this study is an enhanced biological nutrient removal process employing two ditches with intrachannel clarifiers. Bench-scale phased isolation ditch process was used to evaluate the system performance on municipal wastewater and detailed assessment of internal behavior in a ditch and each reactions. When the system was operated at the HRTs of 6~12hours, SRTs of 9~31 days, and cycle times of 4hours, the system showed removals of BOD, TN, and TP as high as 88~97%, 73~78%, and 65~90%, respectively. The internal behavior were well matched on each reactions such as nitrification, denitrification, and phosphorus release and uptake. As the SRT became longer, TN removal increased gradually, whereas TP removal decreased contrarily. However, the system was capable of producing an effluent TP concentration 1mg/L or less even at longer SRTs except the case of solids discharge by malfunction of intra-clarifier occurred by its geometrical limit. The system performance slightly decreased by hydraulic shock loading(increasing of influent flowrate and decreasing of system HRT). However, the higher system performance could be achieved again after four cycles. Thus, the system reliability could be successfully achieved short-term hydraulic shock loading that occurred in medium- and small-sized wastewater treatment plants suffering fluctuation of influent quality and flowrate during wet season.

• Journal of Korean Society on Water Environment
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• 제23권6호
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• pp.961-965
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• 2007

In this study, degradation of carbohydrates and composition of fermentative products were investigated in semi-continuous acid fermenter varying hydraulic retention time (HRT). Rice soup was used as a sole substrate for the acid fermentation. Solubilization efficiency of the substrate was higher than 70% for all HRT, however the gas conversion was ignorable implying that most of organic contents in the influent remained in the form of volatile fatty acids (VFAs) and ethanol after acid fermentation. The VFAs were the predominant product and the VFAs conversion increased as the HRT decreased. The VFAs conversion reached the maximum value at 12 hr HRT accounting for 70% of the influent COD. Similar to VFAs, ethanol conversion was increased with the decrease of HRT and the maximum ethanol conversion efficiency was 8% at the HRT of 12 hr. Composition of VFAs was markedly dependent on HRT. As HRT increased, the composition of acetic acid was increased as a product of acetogenesis from butyrate, valerate and ethanol. This study demonstrated that HRT affected acid fermentation of a carbohydrate containing organic wastes producing VFAs and ethanol which could be effectively used to compensate the lack of carbon in wastewater for biological nutrient removal.