• 한국응용과학기술학회지
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• 제11권1호
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• pp.33-37
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• 1994

In this research, (3-alkyl benzimidazalium)-TCNQ complexes were synthesized to obtain the necessary components for Langmuir-Blodgett Technique. (3- Alkyl benzimidazolium)-TCNQ complexes were prepared by the reaction of LiTCNQ with 3-alkyl benzimidazolium bromides and the products were confirmed by elemental analysis. FT-IR, UV-Visible spectroscopies. FT-IR spectra of (3-alkyl benzimidazolium) TCNQ(1:2) complexes were characterized by a broad band with a maximum at about $2900cm^{-1}$ appears and were ascribed to electronic rather than vibrational absorption.

• Bulletin of the Korean Chemical Society
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• 제10권3호
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• pp.279-282
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• 1989

Two rhodium(I) complexes of the types [Rh(BPPF)(NBD)]$ClO_4$ (10) and [Rh(BPPF)$Cl]_2$ (11) (BPPF = 1,1'-bis(diphenylphosphino)-ferrocene) have been prepared and investigated as catalysts for the regioselective hydrogenation of polynuclear heteroaromatic nitrogen and sulfur compounds such as quinoline (1), acridine (2), phenanthridine (3), 7,8-benzoquinoline (4), benzothiophene (5), isoquinoline (6), indole (7), pyridine (8), and thiophene (9). Both complexes 10 and 11, except for the cases of indole (7) and mononuclear heteroaromatics 8-9, are very efficient in the selective reduction under quite mild hydrogenation conditions to give the corresponding saturated nitrogen and sulfur heterocyclic analogues of 1-6 in fast conversion rates and in excellent yields. Relative rate studies revealed that the reduction depends significantly on the steric and electronic effects of the substrates. Of the two complexes 10-11, the dimeric species 11 gives faster reaction rates in all cases studied.

• 한국경제지리학회지
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• 제24권2호
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• pp.181-200
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• 2021

청년들의 산업단지 기피 현상은 사회·경제적인 차원에서 매우 중요한 이슈이다. 이로 인해 국가적, 지역적인 차원에서 산업단지에 청년을 유입하기 위한 관심이 고조되고 있다. 본 논문은 산업단지 청년유인력 종합지수를 구성하고, 이를 토대로 산업단지 청년유인력 유형을 4개로 구분하여 유형별 특성을 분석하는 것을 목적으로 한다. 먼저 산업단지별 청년 분포와 산업단지 청년유인력 지수 간 상관분석을 실시한 결과, 양호한 설명력을 보였으며, 근무환경, 혁신환경, 어메니티, 일자리 부문과도 양의 상관관계가 나타났다. 또한 산업단지 청년유인력 유형별 특성을 분석한 결과, 국가산업단지와 일반산업단지 모두 유형별로 상이한 특성을 보였으며, 전반적으로 근무환경, 혁신환경, 배후지역 어메니티가 우수한 산업단지가 청년유인력이 양호한 유형 1에 포함되었다. 이를 토대로 유형별 정책 우선순위를 도출하였고, 유형1은 교통 접근성, 일자리 부문이 우선과제로 분석되었다. 본 논문은 산업단지에 청년을 유입하기 위해서는 산업단지 청년유인력 유형별로 맞춤형 패키지 프로그램이 수립될 필요가 있다는 정책적 시사점을 제공하였다.

• 대한화학회지
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• 제37권7호
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• pp.662-671
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• 1993

isonitrosomethylacetoacetate(H-IMAA)의 이민유도체를 리간드로하는 새로운 Ni(II) 및 Pd(II)착물, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR),$ Pd(IMAA-NH)_2$, 및 $Pd(IMAA-NR)_2(R=CH_3,\;n-C_3H_7,\;n-C_4H_9$, 또는 $CH_2C_6H_5)$을 합성하고, 이들 착물의 구조를 원소분석, 전자흡수분광법, 적외선흡수분광법, $^1H$ 및 $^{13}C$ 핵자기공명분광법으로 조사하였다. 여기서 H-IMAA-MH 및 H-IMAA-NR은 각각 isonitrosomethylacetoacetate imine 및 N-alkylisonitrosomethylacetoacetate imine 유도체를 나타낸다.

• 대한산업공학회지
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• 제27권2호
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• pp.150-157
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• 2001

Since the transportation cost takes two thirds of the logistics cost of Korean firms, significant reduction of business logistics cost can hardly be achieved without effective reduction of the transportation cost. Although consolidated transportation has been regarded as the most promising strategy for reducing the transportation cost, it has not been successful in practice. In this paper, we propose a consolidated transportation model for firms located in industrial complexes, present a heuristic algorithm to operate the system, and analyze the expected cost reduction.

• 한국대기환경학회지
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• 제23권1호
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• pp.1-13
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• 2007

This study was carried out to evaluate the applicability of the odor source tracking using wind field and fingerprint as a solution tool. First of all, CALMET and HYSPLIT modeling system, and database of odor discharge companies were utilized to track odor from industrial complexes. Secondly, industrial odor fingerprint was made by listing on the 19 domestic industries, and compared with foreign data to assess the representative, and thus the similarity was 86.7%. On the modeling experiment, Sihwa industrial complex did not show any difference because the matching rates of day and night were 49.5% and 50.0%, respectively. However, the Banwol and Sihwa industrial complexes did show some differences due to odor facility density. Separately, in this study, odor samples were obtained from 10 odor discharging companies, located in the Sihwa and Banwol industrial complexes, They were compared with the results of odor tracking modeling. The matched companies were 4 of 10 by three cases of tracking, while the fingerprint and industry of odor monitoring networks and companies matched each other. Therefore, this study confirmed the approach applicability of source tracking system using the fingerprint.

• Bulletin of the Korean Chemical Society
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• 제1권2호
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• pp.49-54
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• 1980

Solutions of $Ni^{2+}$ and $Cd^{2+}$ were mixed with the solutions of various dibasic organic acids in the presence of cation exchange resin at room temperature. The distribution ratios of the metal ions between resin and solution were measured, using radioactive metal ions as tracer. From the observed variation of the distribution ratios with acid anion concentrations, it was concluded that $Ni^{2+}$ and $Cd^{2+}$ formed one-to-one complexes with succinate, malonate, o-phthalate and tartarate ions in aqueous, 20 % ethanol-water and 20 % acetone-water solutions. The results of the present study indicated that the relative stabilities of the complexes in solution increased generally in the order : $Ni^{2+}$ < $Cd^{2+}$ complexes. Succinate < malonate < o-phthalate < tartarate complexes. Aqueous < mixed solvent systems.

• 한국환경복원기술학회지
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• 제19권2호
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• pp.109-119
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• 2016

In South Korea the need of sustainably managing development on forest lands has required to develop a new approach to estimating environmental impacts on forest surrounding development sites in a scientific manner. As for forest-related development, two types of development were selected: golf courses and industrial complexes. Using Fragstats 4.2, the fragmentation effects and patterns of each type by forest area within project sites and buffer zones ranging from the outside of project sites up to 2,000 meters were analyzed. As a result, golf courses were strongly related to a group of fragmentation indexes: CA, NP, PD, TE, LSI, TCA, NDCA and CONNECT, whereas industrial complexes were associated with CA, NP, PD, TE, LSI and CONNECT. Among them, NP, LSI, TCA and NDCA of golf courses were considered as representative indexes reflecting the average impact ranges of each sub-group by forest area, and focussing on the size of core areas. In the case of industrial complexes, PD, TE and LSI were the representatives, vulnerable to the composition of given landscape. For two case studies, one for golf courses and the other for industrial complexes, they showed there existed a difference between the average of a group and the individual results. Therefore, to minimize the variations in impact range within a group, it is needed to analyze more individual cases. This study proved there was a distinction between project types in terms of the range of environmental impact. To effectively and comprehensively manage forest development, further research on analyzing other development types related to forests with more cases is needed.

• 지역연구
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• 제31권3호
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• pp.99-112
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• 2015

기상관측망은 충분히 고밀도로 구축되어 있기 않기 때문에 산업지역의 전체 지표온도를 얻기는 쉽지 않다. 넓은 지역에 걸쳐 취득하고 짧은 시간에 처리할 수 있는 다기능 원격탐사 정보를 통하여 특정지역에서 현재의 변화하는 지표온도를 정확하고 연속적으로 관측할 수 있다. 전라남도는 광양제철소, 여수산업단지, 율촌산업단지, 대불산업단지와 같은 많은 산업단지와 함께 빠르게 산업화되고 있다. 산업단지 내 지표온도 특성을 살펴보기 위하여 본 연구는 Landsat 7 ETM+의 열적외 파장영상을 이용하여 4개의 산업단지의 지표온도를 비교하였다. 이로부터 환경적 자연적 자원관리를 위한 산업단지의 기초자료를 얻을 수 있었다. 연구 결과는 산업단지계획가에서 환경적 문제와 관련된 개발방식에 도움을 줄 수 있다.

• 한국자기공명학회논문지
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• 제1권1호
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• pp.1-6
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• 1997

Several dioxovanadate (V) complexes are synthesized and studied by solution and solid-state 51V NMR spectroscopy. In the results, large 51V chemical shift anisotropy ({{{{ DELTA delta }}a = -800 ∼720 ppm) and quadrupole coupling (e2q /h = 7.50 ∼ 9.16 MHz) were observed in the solid-state complexes. The isotropic chemical shifts of the solid samples are very close to the values obtained from solution measurements.