• Applied Chemistry for Engineering
• /
• v.25 no.1
• /
• pp.72-77
• /
• 2014

Microstructure and thermal stability of mechanically ball milled $FeS_2$ were investigated. The average particle size and distribution of $FeS_2$ powder were changed in two steps with the increased ball milling time. The average particle size drastically decreased from $98.4{\mu}m$ to 1.01 and $0.89{\mu}m$ after ball milling of 10 h and 30 h, respectively. However, the distribution was broad and a shoulder appeared at $2{\mu}m$ because the pulverization was still in process at 10 h ball milling. After 60 h ball milling, the distribution became narrower. After ball milling of 120 h, the average particle size increased because of $FeS_2$ particle agglomeration. Therefore, the particle size distribution became broaden again. Finally, after ball milling of 170 h, $FeS_2$ with the narrowest size distribution can be obtained. Thermal stability of $FeS_2$ was unstable as the $FeS_2$ particle was pulverized. Therefore, the activation energy of the fine size particles is 27% lower than that of the as-received $FeS_2$.

• Applied Chemistry for Engineering
• /
• v.34 no.6
• /
• pp.670-673
• /
• 2023

The biocompatibility of hydroxyapatite (HAP) has led to its application in various fields. To accomplish practical biological applications, such as drug/gene delivery, the colloidal stability of HAP in phosphate-buffered saline (PBS) is particularly important. In this study, we prepared a glycerol incorporated-HAP (Gly-HAP) by heating HAP in a glycerol environment at 200 ℃. To compare morphology and colloidal stability, HAP prepared at room temperature (RT-HAP) was thermally treated in water at 200 ℃ (H₂O-HAP). The heat treatment of HAP in both water and glycerol solutions results in an increase in the crystallinity of HAPs. Due to the low solubility of HAP in glycerol and the adsorption of glycerol on the HAP surface, crystal growth is limited. However, the heat-treated HAP under water increased in size by approximately four times compared to the initial crystallites. Compared to RT-HAP and H₂O-HAP, Gly-HAP shows improved colloidal stability in PBS, which originates from the adsorption of glycerol on the HAP surface that inhibits the agglomeration of individual HAP precipitates.

• Journal of the Korean Regional Science Association
• /
• v.40 no.3
• /
• pp.95-108
• /
• 2024

This study analyzes the location determinants of newly established and relocated manufacturing firms in South Korea using the National Business Survey data from 2016 to 2019. Both new establishments and relocations are concentrated in the Seoul metropolitan area, Chungcheong, Yeongnam, and Daegyeong regions, with relocated firms showing a higher degree of spatial concentration. Employing a negative binomial regression model, we find that manufacturing concentration, population density, industrial diversity, and lower wage levels positively influence both new establishments and relocations. The proportion of highly educated workers, accessibility to producer services, and average land prices only positively affect the frequency of new establishments, suggesting that firms in the early stages of their life cycle, which are more dependent on human capital and producer services, demonstrate a higher willingness to pay for land use. Conversely, increased travel time to Seoul and improved transportation accessibility enhance the probability of attracting relocated firms. This implies that cost reduction incentives associated with distance from Seoul may outweigh the benefits of proximity to the capital in relocation decisions. Our findings suggest that strengthening agglomeration economies and improving transportation infrastructure efficiency could increase the likelihood of attracting relocated manufacturing firms to non-capital regions.