• 한국진공학회지
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• 제18권6호
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• pp.426-434
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• 2009

평판형 유도결합 플라즈마 장치의 $SiH_4/H_2$ 방전에 대한 공간 평균 전산모사가 이루어졌다. $SiH_4/H_2$ 플라즈마 방전에서 발생되는 전자, 양이온, 음이온, 중성종, 그리고 라디칼들에 대한 공간 평균된 유체 방정식을 기반으로 하고 있으며, 비정상 표피효과(Anomalous skin effect)를 고려한 비충돌 전자가열 모델을 적용하여 흡수되는 파워량을 결정하였다. $SiH_4$와 $H_2$의 가스 주입비율, 파워, 그리고 압력을 변화시키며 각각에 대한 하전입자, 중성종 및 라디칼들의 밀도 변화와 전자온도 의존성을 조사하였다.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.2015-2018
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• 2010

Second-order rate constants $(k_{OH^-})$ have been measured spectrophotometrically for alkaline hydrolysis of Y-substituted phenyl phenyl carbonates (2a-j) and compared with the $k_{OH^-}$ values reported previously for the corresponding reactions of Y-substituted phenyl benzoates (1a-j). Carbonates 2a-j are 8~16 times more reactive than benzoates 1a-j. The Hammett plots correlated with $\sigma^-$ and $\sigma^o$ constants exhibit many scattered points, while the Yukawa-Tsuno plot results in excellent linear correlation with $\rho$ = 1.21 and $\gamma$ = 0.33. Thus, the reaction has been concluded to proceed through a concerted mechanism in which expulsion of the leaving group is advanced only a little. However, one cannot exclude a possibility that the current reaction proceeds through a forced concerted mechanism with a highly unstable intermediate.

• Journal of Electrical Engineering and Technology
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• 제13권6호
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• pp.2335-2343
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• 2018

This paper proposes an optimal damping control algorithm of the DTI (Direct Two-level Inverter) to miniaturize and reduce the weight of auxiliary power supply for railway vehicles. The conventional auxiliary power supply for railway vehicles uses a DC-DC converter to maintain the inverter input power from the line voltage smoothly. The proposed topology does not use a DC-DC converter for reducing of manufacturing and maintenance costs. It also proposes a DTI topology removed damping resistors that generate ground signal noise in a certain period. At this time, a resonance phenomenon of DC-link voltage occurs due to variation of the inductive load, and a method of controlling the resonance phenomenon of DC-link voltage is required. In order to suppress the resonance phenomenon of the DC-link voltage, at a point before resonance occurs, this paper introduces an algorithm to suppress the resonance phenomenon of DC-link voltage by compensating the resonance component of the q axis voltage of the synchronous reference frame. The proposed algorithm verifies the effect through simulation and experiment.

• Environmental Analysis Health and Toxicology
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• 제24권3호
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• pp.213-218
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• 2009

1-bromopropane (1-BP) has been used in numerous purposes such as an intermediate in the synthesis of pharmaceuticals, a solvent for fats, waxes, or resins and a substitute for chlorofluorocarbons that destroy the ozone layer. However, the studies related to the modulation of activities of hepatic cytochrome P450s (CYPs) are not reported yet. This study was the first study to investigate the potential effect for the activities of hepatic CYPs by the treatment of 1-BP in vivo. When 1-BP was treated to male ICR mice by dose-dependently at the dose levels of 200, 500 and 1,000 mg/kg of body weight once, the activity of CYP2E1 was selectively increased for 24 h. The inductive potency for the activity of CYP2E1 by 1-BP was equal to induction by acetone a well-known selective CYP2E1 inducer. The present results indicated that 1-BP would affect the metabolism of 1-BP itself and/or other xenobiotics.

• 대한교통학회지
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• 제12권4호
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• pp.35-52
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• 1994

In order to operate the computerized traffic signal system, it requires the detectors which ensure the exact detections of actual traffic data (e.g., traffic volume, occupancy and velocity of vehicles). The octagonal detectors are used currently in Korea. However, the maintenance of the detectors has many problems with the road repairs and the constructions on the pavement, and failure due to the disconnection of the wires. Serious delay due to the long installation time of loops also causes the traffic disturbances. The low sensitivities and splash-over effect can sometimes create error data after installation of the octagonal loops. The mai purpose of this study is to evaluate the feasibility of domestic use of the round (circular) inductive loops which developed recently in U.S.A. It was found that the round loops are comparable to the existing octagonal loops. In addition, the use of the high quality of materials in the round loop system can reduce the current problems and weakpoints of the octagonal loops. The installation cost of the round loop was found out as economic as the octagonal loop. The installation time of the round loop system can be reduced with the specially equipped loop truck, and wide/deep slots without sharp corners can extend the durability without serious stress of loop head wires. In conclusion, the round loop is superior to the octagonal type in overall points. It is recommended that the localization of the materials and equipments of round loop system is required to carry out the extensive local installations. Also, several contractors to meet the nationwide demand should be arranged to gurantee the proper maintenance and operation of the systems.

• 전기학회논문지
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• 제61권3호
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• pp.437-441
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• 2012

In this paper, we have designed and manufactured 10MHz power source for the application of short distance wireless power transmission. The designed power source consists of a DDS(direct digital synthesizer) signal generator, a buffer driver and a balanced power amplifier. Short range wireless power transmission is usually carried out by near-field inductive coupling between source and load. The distance variation between source and load gives rise to the change of load impedance of power amplifier, which has effect on the operation of power amplifier. To overcome this problem due to load variation of power amplifier, we have adopted the balanced power amplifier using the quadrature hybrid implemented by lumped capacitors and a mutually coupled coil. The experiment results show the above 40dBm output power, frequency range of 9 to 11MHz, and total DC power consumption of 36W.

• 한국자동차공학회논문집
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• 제22권3호
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• pp.143-147
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• 2014

The ECU which is operating inductive actuator like motor or solenoid should be designed with considering the heat removal performance and the EMC performance. In most cases, these two performances are trade-off. Especially, the metal cover with plastic housing for improving heat removal performance can affect EMC performance by coupling the noise source to harness cable and connector. Therefore, after analyzing the EMC effectiveness of the metal cover, countermeasures for EMC noise reduction should be established. In this paper, by simulating and testing of AHB Gen3 ECU, the influence of the metal cover to EMC performance is analyzed. And based on this result, we propose solutions for EMC noise reduction.

• 대한화학회지
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• 제38권3호
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• pp.179-185
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• 1994

니트릴기의 라만 신축진동 파수는 용매 변화에 의해 영향을 받고 또한, 동일한 용매에서 농도변화에 의해 영향을 받았다. 아세토니트릴의 경우에는 니트릴기 신축진동 파수들이 다양한 용매들에서 2247.3~2254.9 $ cm^{-1}영역에 나타났다. 반면에 벤조니트릴에서는 2226.1∼2230.3 cm-1영역에서 나타났다.아세토니트릴에서는 물의 첨가로, νC≡N은 메틸프로톤들과 물 사이에서의 더 많은 수소결합으로 순수한 아세토니트릴의 2250.1cm^{-1}로부터 90% 물의 2257.7 cm^{-1}까지 높은 파수쪽으로 이동하였다. 니트릴기에 대한 νC≡N파수는 혼합용매 (CHCl_3/CCl_4)의$ 몰비가 증가함에 따라 용매 유발효과에 의해 높은 파수쪽으로 이동하였다.

• 대한화학회지
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• 제36권1호
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• pp.38-43
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• 1992

치환 스틸벤 계열에 대해 HMO법으로 Hammett치환기 상수를 해석하였다. 이 계열에서 치환기 상수에 대한 유도효과와 공명효과의 기여를 양자화학적 지수로 취하여 계산한 이론값이 Hammett 치환기 상수 ${\sigma}_p$와 병행성이 있음을 알았으며 이 이론값으로 치환 스틸벤의 쌍극자능륙에 미치는 치환기 효과를 설명할 수 있었다. 아울러 이 화합물의 전자전이에 대한 최대 흡수파장$({\lambda}_{max})$은 HOMO와 LUMO 에너지의 창에 의존됨이 확인되었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.433-433
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• 2013

Graphene, $sp^2$-hybridized 2-Dimension carbon material, has drawn enormous attention due to its desirable performance of excellent properties. Graphene can be applied for many electronic devices such as field-effect transistors (FETs), touch screen, solar cells. Furthermore, indium tin oxide (ITO) is commercially used and sets the standard for transparent electrode. However, ITO has certain limitations, such as increasing cost due to indium scarcity, instability in acid and basic environments, high surface roughness and brittle. Due to those reasons, graphene will be a perfect substitute as a transparent electrode. We report the graphene synthesized by inductive coupled plasma enhanced chemical vapor deposition (ICP-PECVD) process on Cu substrate. The growth was carried out using low temperature at $400^{\circ}C$ rather than typical chemical vapor deposition (CVD) process at $1,000^{\circ}C$ The low-temperature process has advantage of low cost and also low melting point materials will be available to synthesize graphene as substrate, but the drawback is low quality. To improve the quality, the factor affect the quality of graphene was be investigated by changing the plasma power, the flow rate of precursors, the scenario of precursors. Then, graphene film's quality was investigated with Raman spectroscopy and sheet resistance and optical emission spectroscopy.