• Title/Summary/Keyword: Induced angle

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A Study on the Role of -SO3- Ions in the Dehydration Limit of Poly(styrene-co-styrenesulfonic acid) Membrane

  • Ko, Kwang-Hwan;Kim, Joon-Seop;Lee, Chang Hoon
    • Elastomers and Composites
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    • v.52 no.3
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    • pp.180-186
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    • 2017
  • In this work, the effect of low-temperature dehydration of a poly(styrene-co-styrenesulfonic acid) (PSSA) membrane was investigated by differential scanning calorimetry, fourier transform infrared spectroscopy (FT-IR), electron magnetic resonancespectroscopy (EMR), and $^1H$- and $^{13}C$ solid-state nuclear magnetic resonance spectroscopy. These analyses were performed at room temperature for powdered PSSA specimens with and without dehydration and the following key observations were made. First, FT-IR analysis showed that low-temperature dehydration not only transformed the [${SO_3}^-{\cdots}H^+$] ionic pair in the non-hydrated PSSA to an $SO_3H$ group, but also induced the formation of -C=C- double bonds in the dehydrated PSSA. Second, the ${-SO_3}^{\bullet}$ radical was unambiguously identified by EMR spectroscopy. Third, H-abstraction was detected by $^1H$ magic-angle spinning spectroscopy. Finally, an unexpected color shift from white for the non-hydrated PSSA to a yellowish brown for the dehydrated sample was observed. In order to explain these experimental results, it was proposed that the formation of the intermediate hydrogen ($H^{\bullet}$) or hydroxyl radical ($HO^{\bullet}$) species was initiated by the dehydration process. The sespecies attacked the $SO_3H$ group and the tertiary proton at the ${\alpha}-carbon$, resulting in the formation of $-SO^{\bullet}$ radicals and -C=C- double bonds, which correlated with the color shift in the dehydrated PSSA sample. The semechanisms are useful for understanding the simultaneous loss of an aromatic ring and -SO- groups in the PSSA fuel cell membrane.

Jacking Penetration Resistance of Bucket Foundations in Silty Sand Using Centrifuge Modelling (실트질모래 지반에서 버켓기초의 압입저항력에 대한 원심모형실험 연구)

  • Kim, Dong-Joon;Youn, Jun-Ung;Lee, Kyu-Yeol;Jee, Sung-Hyun;Choo, Yun Wook
    • Journal of the Korean Geotechnical Society
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    • v.31 no.1
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    • pp.25-35
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    • 2015
  • Penetration resistance of bucket foundations with skirt wall in the silty sand of the western coast of Korea was analyzed by centrifuge modelling. The penetration resistance is induced when the bucket foundations are jacked into the soil without suction, and is directly related to the self-weight penetration depth. The procedure by Houlsby and Byrne (2005), which takes into account the effect of stress increase by frictional resistance of skirt wall, was utilized to generate the penetration resistance similar to the experimental results. This paper describes the methods by which major parameters such as lateral earth pressure coefficient and friction angle between the skirt wall and the soil are evaluated. The effect of changes in these parameters on the predictions is analyzed. Also, observed soil behaviour during jacking penetration is investigated.

Analysis of Shaping Parameters Influencing on Dimensional Accuracy in Single Point Incremental Sheet Metal Forming (음각 점진성형에서 치수정밀도에 영향을 미치는 형상 파라미터 분석)

  • Kang, Jae Gwan;Kang, Han Soo;Jung, Jong-Yun
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.39 no.4
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    • pp.90-96
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    • 2016
  • Incremental sheet forming (ISF) is a highly versatile and flexible process for rapid manufacturing of complex sheet metal parts. Compared to conventional sheet forming processes, ISF is of a clear advantage in manufacturing small batch or customized parts. ISF needs die-less machine alone, while conventional sheet forming requires highly expensive facilities like dies, molds, and presses. This equipment takes long time to get preparation for manufacturing. However, ISF does not need the full facilities nor much cost and time. Because of the facts, ISF is continuously being used for small batch or prototyping manufacturing in current industries. However, spring-back induced in the process of incremental forming becomes a critical drawback on precision manufacturing. Since sheet metal, being a raw material for ISF, has property to resilience, spring-back would come in the case. It is the research objective to investigate how geometrical shaping parameters make effect on shape dimensional errors. In order to analyze the spring-back occurred in the process, this study experimented on Al 1015 material in the ISF. The statistical tool employed experimental design with factors. The table of orthogonal arrays of $L_8(2^7)$ are used to design the experiments and ANOVA method are employed to statistically analyze the collected data. The results of the analysis from this study shows that the type of shape and the slope of bottom are the significant, whereas the shape size, the shape height, and the side angle are not significant factors on dimensional errors. More error incurred on the pyramid than on the circular type in the experiments. The sloped bottom showed higher errors than the flat one.

Evaluation and Adjustment of Lateral Displacement of Complex-shaped RC Tall Buildings Considering the Displacement by Tilt Angle of Each Floor (층경사각에 의한 횡변위를 고려한 비정형 고층건물의 횡변위 평가/보정)

  • Kim, Yungon
    • Journal of the Korea Concrete Institute
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    • v.27 no.5
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    • pp.551-558
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    • 2015
  • Lateral displacement in the most complex-shaped tall buildings is caused by eccentric gravity loads which are induced by the difference in location between a center of mass and a center of stiffness. The lateral displacements obtained from analysis, using conventional procedures, are prone to overestimate the actual values because much of realignment efforts made during construction phase are ignored. In construction sequence analysis, the self-leveling of slab and the verticality of columns/walls could be considered at each construction stage. Moreover, the displacement compensation can be achieved by manual process such as re-centering - locating to global coordinates through surveying. Because the lateral displacement increases with the building height, it is necessary to set up adjustment plan through construction stage analysis in advance in order to result in displacements less than the allowable limits. Because analytical solution includes lots of assumptions, the pre-adjusting displacement should be reasonably controlled with considerations for the uncertainty due to these assumptions.

Analysis of Magnetic Fields Induced by Line Currents using Coupling of FEM and Analytical Solution (선전류에 의해 발생되는 자장의 해석을 위한 유한요소법과 해석해의 결합 기법)

  • Kim, Young-Sun;Cho, Dae-Hoon;Lee, Ki-Sik
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.55 no.3
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    • pp.141-145
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    • 2006
  • The line current problem(2-dimensional space : point source) is not easy to analyze the magnetic field using the standard finite element method(FEM), such as overhead trolley line or transmission line. To supplement such a defect this paper is proposed the coupling scheme of analytical solution and FEM. In analysis of the magnetic field using the standard FEM. If the current region is a relatively small compared to the whole region. Therefore the current region must be finely divided using a large number of elements. And the large number of elements increase the number of unknown variables and the use of computer memories. In this paper, an analytical solution is suggested to supplement this weak points. When source is line current and the part of interest is far from line current, the analytical solution can be coupling with FEM at the boundary. Analytical solution can be described by the multiplication of two functions. One is power function of radius, the other is a trigonometric function of angle in the cylindrical coordinate system. There are integral constants of two types which can be established by fourier series expansion. Also fourier series is represented as the factor to apply the continuity of the magnetic vector potential and magnetic field intensity with tangential component at the boundary. To verify the proposed algorithm, we chose simplified model existing magnetic material in FE region. The results are compared with standard FE solution. And it is good agreed by increasing harmonic order.

Revealing the complexity of ionized gas outflows in powerful Type 2 AGN in the local Universe

  • Karouzos, Marios;Woo, Jong-Hak;Bae, Hyun-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.32.3-33
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    • 2015
  • There exist scaling relations that link the mass of supermassive black holes with both the velocity dispersion and the mass of the central stellar cusp of their host galaxies. This implies that these two components grow in tandem. Feedback from actively accreting supermassive black holes (AGN), in the form of multi-phase gas outflows, has been argued to be the agent of this co-evolution. Here we employ the powerful GMOS integral field spectroscopy unit on the 8.2m Gemini-North telescope to investigate ionized gas outflows of luminous Type 2 AGN in the local Universe (z<0.1). Our sample of 6 galaxies is drawn from the Sloan Digital Sky Survey (SDSS) and was selected based on their [OIII] dust-corrected luminosity (>1042 erg/s) and signatures of outflows in the [OIII] line profile of their spatially integrated SDSS spectra. These are arguably the best candidates to explore AGN feedback in action since they are < 1% of a large local type 2 AGN SDSS sample selected based on their [OIII] kinematics. We combine a careful spectral decomposition of the [OIII] and $H{\alpha}$ line profiles with spatial information on ~0.5kpc scales to understand the outflow kinematics and energetics in these objects. We find clear evidence for strong outflows in [OIII] and occasionally $H{\alpha}$ that are clearly driven by the ionizing radiation of the AGN. We kinematically and spatially decompose outflowing and rotating ionized gas components. We find [OIII] to be a better tracer of AGN outflows, while $H{\alpha}$ appears to be strongly affected by both stellar rotation and outflows induced by ongoing star formation. The observed kinematics and spatial distribution of the ionized gas imply a large opening angle for the outflow. Finally, we find the projected outflow velocity to decrease as a function of distance, while its dispersion shows a more complex structure with a potentially initially increasing trend (out to 0.5-1kpc distances).

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A Study on SAR Attenuation by Using Loop-type Ground for Mobile Handsets (루프 형태의 접지판을 이용한 휴대폰의 SAR 감쇄에 관한 연구)

  • Lee Won-Kew;Son Ji-Myoung;Han Jun-Hee;Yang Woon-Geun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.9 s.112
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    • pp.821-828
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    • 2006
  • In this paper, we investigated SAR(Specific Absorption Rate) value variation by the position and size of the loop-type ground located in a test mobile handset. We carried out simulations on SAR value with loop-type grounds in rear case of a mobile handset, and obtained results showed that different positions and sizes of loop-type grounds had different SAR values. Among investigated positions and sizes of loop-type grounds, the small size case-C showed the best performance; i.e., it showed a decrease efficiency of 8.70 %. And in this case, it showed the highest induced electric-field distribution in the loop-type ground. In the simulation, the folding angle was set to $160^{\circ}$.

Oscillatory Motion of Natural Convective Flow in Partially Divided Square Enclosure (수평격판을 갖는 4각형 밀폐공간내에서 자연대류의 진동유동)

  • 김점수;정인기;송동주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1963-1970
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    • 1992
  • An oscillatory motion of the natural convection in a two dimensional, partially divided square enclosure heated from below, and fitted with a partition is investigated numerically. The enclosure was composed of the lower hot and the upper cold horizontal walls and the adiabatic vertical walls, and a partition was situated perpendicularly at the mid-height of the one vertical insulated wall. The governing equations are solved by using the finite element method with Galerkin method. The computations were performed with the variation of the length and the thermal conductivity of the partition, and Rayleigh number based on the temperature difference between horizontal walls and the enclosure height with water(Pr=4.95). also, the effect of the inclination angles was studied for the transition to the oscillating flow. As the results, it was found that the intensity and frequency of oscillatory motion were affected significantly by the Rayleigh number and the length of partition. The effect of oscillatory motion was weaken with the increase of the thermal conductivity of partition. The inclination angle for the transition was raised with the increase of Rayleigh number and the length of partition.

Effects of High-Intensity Interval Training on Motor Skills Recovery in Sciatic Nerve Crush-Induced Rats

  • Kim, Ki-Hyun;Shin, Hyung-Soo;Jung, Nam-Jin;Hwangbo, Gak
    • Journal of the Korean Society of Physical Medicine
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    • v.15 no.1
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    • pp.43-54
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    • 2020
  • PURPOSE: This study examined the effects of mild-intensity exercise (MIE) and high-intensity interval exercise (HIIE) on the recovery of the motor function over time in sciatic nerve crush injury rats. METHODS: The MIE group ran on a treadmill at a speed of 8.3 m/min to perform low-intensity training with maximum oxygen uptakes ranging from 40 to 50%. The HIIE group ran on the treadmill at a speed of 25 m/min to perform high-intensity training with a maximum oxygen uptake of 80%. The interval training was performed based on a 1:1 work-to-rest ratio. The effects of each form of exercise on the rats' walking abilities following their recovery from the peripheral nerve injuries were evaluated based on the results of behavior tests performed at one and 14 days. RESULTS: According to the test results, the MIE group showed significant improvements in the rats' ankle angle in the initial stance phase, and in the ankle and knee angles in the toe-off phase (p<.05). The HIIE group exhibited significant improvements in the ankle and knee angles in the initial stance phase, SFI(p<.05). CONCLUSION: The state of such patients can be improved by applying the results of this study in that MIE and HIIE on a treadmill can contribute to the recovery of the peripheral nerve and motor skill. In particular, MIE is used as a walking functional training in the toe-off stance phase, while HIIE is suitable in the initial stance stage.

Effect of Anodized Carbon Fiber Surfaces on Interfacial Adhesion of Carbon Fiber-reinforced Composites (양극산화된 탄소섬유가 복합재료의 계면결합력에 미치는 영향)

  • 박수진;김문한;최선웅;이재락
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.499-504
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    • 2000
  • The effect of anodic oxidation on high strength PAN-based carbon fibers has been studied in terms of surface functionality and surface energetics of the fiber surfaces, resulting in improving the mechanical properties of composites. According to FT-IR and XPS measurements, it reveals that the oxygen functional groups on fiber surfaces induced by an anodic oxidation largely influence the surface energetics of fibers or the mechanical interfacial properties of composites, such as the interlaminar shear strength (ILSS) of composites. According to the contact angle measurements based on the wicking rate of a test liquid, it is observed that anodic oxidation does lead to an increase in surface free energy of the carbon fibers, mainly due to the increase of its specific (or polar) component. From the surface energetic point of view, it is found that good wetting plays an important role in improving the degree of adhesion at interfaces between fiber and epoxy resin matrix of the resulting composites. Also, a direct linear relationship is shown between 01s/01s ratio and ILSS or between specific component and ILSS of the composites for this system.

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